Polyvinyl acetate-butyl acrylate

The author also investigated the comparative effects of physical and chemical monomer reduction (stripping) on chloromethyl and methyl isothiazolinones in a polyvinyl acetate/butyl acrylate co-polymer dispersion in a large scale plant trial. Results are detailed in Table 16 and show that even under apparently strongly oxidising conditions CIT was degraded by up to 75% when redox monomer reduction was used. In comparison no such effect was seen with the physically stripped samples. [Pg.239]

Vinyl acetate-butyl acrylate copolymers (0-100% butyl acrylate) were prepared by both batch and starved semi-continuous polymerization using sodium lauryl sulfate emulsifier, potassium persulfate initiator, and sodium bicarbonate buffer. This copolymer system was selected, not only because of its industrial importance, but also because of its copolymerization reactivity ratios, which predict a critical dependence of copolymer compositional distribution on the technique of polymerization. The butyl acrylate is so much more reactive than the vinyl acetate that batch polymerization of any monomer ratio would be expected to give a butyl acrylate-rich copolymer until the butyl acrylate is exhausted and polyvinyl acetate thereafter. [Pg.86]

Surfactant Interactions in Polyvinyl Acetate and Poly (vinyl acetate-butyl acrylate) Latexes... [Pg.226]

Recent investigations have shown that the behavior and interactions of surfactants in a polyvinyl acetate latex are quite different and complex compared to that in a polystyrene latex (1, 2). Surfactant adsorption at the fairly polar vinyl acetate latex surface is generally weak (3,4) and at times shows a complex adsorption isotherm (2). Earlier work (5,6) has also shown that anionic surfactants adsorb on polyvinyl acetate, then slowly penetrate into the particle leading to the formation of a poly-electroyte type solubilized polymer-surfactant complex. Such a solubilization process is generally accompanied by an increase in viscosity. The first objective of this work is to better under-stand the effects of type and structure of surfactants on the solubilization phenomena in vinyl acetate and vinyl acetate-butyl acrylate copolymer latexes. [Pg.226]

Emulsion Polymerization A typical recipe is give in Table I. Emulsion polymerization was carried out at 60°C under a nitrogen atmosphere using a batch process. Theoretical solids content in all the formulations was 25%, and generally the conversions were better than 98%. A polyvinyl acetate homopolymer and two poly (vinyl acetate-butyl acrylate) copolymers having VA/BA composition of 85/15 and 70/30 were prepared according to the above procedure. [Pg.227]

Transmission electron microscopy of latex film replicas showed that the polyvinyl acetate latexes did not undergo further gradual coalescence upon ageing at room temperature (37), as had been reported earlier (40). The addition of butyl acrylate, even in the 89 11 vinyl acetate-butyl acrylate molar ratio, however, was sufficient to cause further gradual coalescence of the latex films (37). [Pg.23]

There is a similarly wide range of sealants for the DIY household maihet, varying from oil based putties for glazing polyvinyl acetate and acrylic emulsion sealants, with easy appUcation and clean-up properties and butyl, polyiuethane and silicone sealants for dmable, flexible, long lasting external seals. Again the cost increases progressively from oil based putties to silicone rubber based sealants. [Pg.292]

There are a variety of thickening agents (thixotropes) designed for different applications. In aqueous and latex adhesives and sealants, such as acrylics, polyvinyl acetate, butyl, and natural rubber, frequently used types include ... [Pg.332]

ABA ABS ABS-PC ABS-PVC ACM ACS AES AMMA AN APET APP ASA BR BS CA CAB CAP CN CP CPE CPET CPP CPVC CR CTA DAM DAP DMT ECTFE EEA EMA EMAA EMAC EMPP EnBA EP EPM ESI EVA(C) EVOH FEP HDI HDPE HIPS HMDI IPI LDPE LLDPE MBS Acrylonitrile-butadiene-acrylate Acrylonitrile-butadiene-styrene copolymer Acrylonitrile-butadiene-styrene-polycarbonate alloy Acrylonitrile-butadiene-styrene-poly(vinyl chloride) alloy Acrylic acid ester rubber Acrylonitrile-chlorinated pe-styrene Acrylonitrile-ethylene-propylene-styrene Acrylonitrile-methyl methacrylate Acrylonitrile Amorphous polyethylene terephthalate Atactic polypropylene Acrylic-styrene-acrylonitrile Butadiene rubber Butadiene styrene rubber Cellulose acetate Cellulose acetate-butyrate Cellulose acetate-propionate Cellulose nitrate Cellulose propionate Chlorinated polyethylene Crystalline polyethylene terephthalate Cast polypropylene Chlorinated polyvinyl chloride Chloroprene rubber Cellulose triacetate Diallyl maleate Diallyl phthalate Terephthalic acid, dimethyl ester Ethylene-chlorotrifluoroethylene copolymer Ethylene-ethyl acrylate Ethylene-methyl acrylate Ethylene methacrylic acid Ethylene-methyl acrylate copolymer Elastomer modified polypropylene Ethylene normal butyl acrylate Epoxy resin, also ethylene-propylene Ethylene-propylene rubber Ethylene-styrene copolymers Polyethylene-vinyl acetate Polyethylene-vinyl alcohol copolymers Fluorinated ethylene-propylene copolymers Hexamethylene diisocyanate High-density polyethylene High-impact polystyrene Diisocyanato dicyclohexylmethane Isophorone diisocyanate Low-density polyethylene Linear low-density polyethylene Methacrylate-butadiene-styrene... [Pg.958]

The results showed that all batch polymerizations gave a two-peaked copolymer compositional distribution, a butyl acrylate-rich fraction, which varied according to the monomer ratio, and polyvinyl acetate. All starved semi-continuous polymerizations gave a single-peaked copolymer compositional distribution which corresponded to the monomer ratio. The latex particle sizes and type and concentration of surface groups were correlated with the conditions of polymerization. The stability of the latex to added electrolyte showed that particles were stabilized by both electrostatic and steric stabilization with the steric stabilization groups provided by surface hydrolysis of vinyl acetate units in the polymer chain. The extent of this surface hydrolysis was greater for the starved semi-continuous sample than for the batch sample. [Pg.87]

Butyl benzyl phthalate is a plasticizer added to polymers to give flexibility and softness. It is used extensively in polyvinyl chloride and in cellulose plastics, polyvinyl acetate, polysulfides, and polyurethane. Also used in flexographic inks for food packaging applications and acrylic coatings, profile extrusions, slush moulding, film and sheeting, coated fabrics, floor and wall coverings, vinyl foams and plastisols for car sealants. [Pg.296]

Emulsions of polyvinyl acetate and polyalkyl acrylates have been used as tub caulking compositions, spackling compounds and as building sealants.22 Acrylic sealants which harden in the presence of powdered iron or copper meet Federal Specifications TT-S-00230C. 27 Liquid monomers, such as polyethylene glycol dimethacrylate and butyl alpha—cyanoacrylate have been used as room temperature curing sealants.22 22. [Pg.102]

Vinyl Acetate, Homo- and Copolymer Latexes Vinyl Acetate Comonomer (butyl acrylate, ethylene, vinyl ester of versatic add) Partially Hydrolyzed Polyvinyl Alcohol Sodium Bicarbonate Hydrogen Peroxide (35%) Sodium Formaldehyde Sulfoxylate Water 70.0-100.0 0.0-30.0 6.0 0.3 0.7 0.5 80.0... [Pg.25]

Orchis mascula Orchis mascula extract. See Orchid (Orchis mascula) extract Orcinol monomethyl ether Orclnyl 3. SeeS-Methoxy-m-cresol Oreo Antifoam AF. See Silicone Oreo Binder LF-X. See Aery I i c res i n Oreo Dye Carrier B. See Butyl benzoate Oreo Low Crock T-550. See Acrylic resin Orcoset Resin CN. See Polyvinyl acetate... [Pg.3000]

Vinyl acetate, inhibited. See Vinyl acetate Vinyl acetate/isobutyl maleate/vinyl neodecanoate copolymer. See VA/isobutyl maleate/vinyl neodecanoate copolymer Vinyl acetate monomer. See Vinyl acetate Vinyl acetate polymer. See Polyvinyl acetate Vinyl acetate, polymer with n-butyl acrylate. [Pg.4676]

Thermoplastic polymers (plastics) Ethylene-vinyl acetate (EVA), ethylene-methyl acrylate (EMA), ethylene-butyl acrylate (EBA), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS) (2), (3), [8], [9], [10]... [Pg.141]

A polyanrline-poly(butyl acrylate-vinyl acetate) composite exhibiting electroactivity and having a conductivity of 2.2 S/cm was prepared by emulsion polymerization. The composite was soluble in common organic solvents and a stable water-based dispersion could also be prepared. Films cast from aqueous media had exceptional mechanical properties and had excellent adhesion to steel [144]. From the same group, a polyaniline and polyvinyl alcohol electroactive composite has been synthesized by... [Pg.1623]

In the hot-melt type, two principal polymer types are used polyolefin and ethylene co-polymer based and polyester and polyamide type. In the solvent-based type, the most prominent are neoprene (polychloroprene)-based solvent and latex types, and polyvinyl acetate emulsions. For pressure-sensitive adhesives, the most favored are acrylic adhesives and butyl rubber/polyisobutylene types. [Pg.38]

Sodium poly(acrylate) copolymer with maleic acid Polyvinyl pyrrolidone copolymer with vinyl acetate Butylated poly(vinylpyrrolidone)... [Pg.306]

Types within group Cellulose acetate, cellulose acetate butyrate, cellulose nitrate, polyvinyl acetate, vinyl vinylidene, polyvinyl acetals, polyvinyl alcohol, polyamide, acrylic, phenoxy Cyanoacrylate, polyester, urea formaldehyde, melamine formaldehyde, resorcinol and phenol-resorcinol formaldehyde, epoxy, polyimide, polybenzimidazole, acrylic, acrylate acid diester Natural rubber, reclaimed rubber, butyl, polyisobutylene, nitrile, styrene-butadiene, polyurethane, polysuHide, silic e, ne< nene Epoxy-phenolic, epoxy-polysulfide, epoxy-nylon, nitrilephenolic, neoprene-phenolic, vinyl-phenolic... [Pg.837]

Journal of Polymer Science Polymer Physics Edition 39, No.14, 15th July 2001, p.1659-64 EFFECT OF RESIDUAL WATER AND FREE VOLUME ON THE GLASS-TRANSITION TEMPERATURE AND HEAT CAPACITY IN POLYSTYRENE/POLYVINYL ACETATE-CO-BUTYL ACRYLATE STRUCTURED LATEX FILMS... [Pg.55]

The dispersion of fibers in polymer latex to prepare composite has been reported for poly(6-hydroxyoctanoate) (PHO) [101, 102], polyvinylchloride (PVC) [103], waterborne epoxy [104] and polyvinyl acetate (PVAc) [94]. Most of the works focus on the use of non-polar, non-water-sensitive polymers, while keeping an aqueous media for the processing of the films to preserve the dispersion of the nanoparticles. In their pioneering work, Favier et al [94] adopted the technique of solvent casting using a synthetic latex obtained by the copolymerization between styrene (35 wt%) and butyl-acrylate (65 wt%) (poly(S-co-BuA)). Nanowhiskers were dispersed in the latex and evaporated. The nanocomposite films were obtained by water evaporation and particle coalescence at room temperature, that is at a temperature higher than Tg of poly(S-co-BuA), around 0 C. [Pg.266]

Bentonite thickening agents are used in various water based adhesives, caulks and sealants including those based on proteins and starch, polyvinyl acetate emulsions, natural rubber latexes, acrylic emulsions, neoprene emulsions, butyl emulsions, nitrile emulsions, and SBR emulsions. [Pg.338]