Poly 2-hydroxyethyl methacrylate-co-methyl

Poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) Theophylline, triamterene, oxprenolol, buflomedil, vitamin B12, inulin, myoglobin [105]... 

Poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) Poly (lactic acid) the d- and L-isomers are often referred to as PDLA, PLLA, respectively... 

Poly(2-hydroxyethyl methacrylate) (polyHEMA) is used for soft contact lenses and is a representative medical use hydrogel. Encapsulation of cells into polyHEMA or poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) (polyHEMA-co-MMA)) will be introduced in the following. 

Poly(2-hydroxyethyl methacrylate) (pHEMA) is a nonbiodegradable material. One of pHEMA s physical characteristics is that it is easily tailorable, and been used extensively in medical applications. Tsai et al. implanted poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) (pHEMA-MMA) hydrogel guidance channels into a T8 transected spinal cord in adult Sprague-Dawley rats the hydrogel guidance channel improved specific supraspinal and local axonal regeneration after complete spinal cord transection (Tsai et al. 2004). In another study, modifications of pHEMA with cholesterol and laminin have... 

Biodegradation of poly(2-hydroxyethyl methacrylate) (PHEMA) and poly (2-hydroxyethyl methacrylate)-co-[poly(ethylene glycol) methyl ether methacrylate] hydrogels containing peptide-based cross-linking agents. Biomacromolecules, 11, 2949. 

Two approaches are discussed for the preparation of enzymatically controlled drug delivery systems a calcium-responsive biodegradable drug delivery system based on a mixture of starch with HPMC (hydroxypropyl methyl cellulose ether) (biodegradable) and the starch hydrolytic enzyme, alpha-amylase, in its non-active form and a glucose responsive insulin delivery system based on the hydrogel poly(2-hydroxyethyl methacrylate-co-N,N-dimethylaminoethyl methacrylate), with entrapped glucose oxidase, catalase and insulin. In both systems, the sensitivity... 

Magnetic Resonance Imaging (MRI) becomes one of the useful microscopy and is used not only for the medical purposes but also for chemical applications. For polyurethane foams, the analysis of the distributions of many microstructural features, including strut length and window and cell shape distributions, were carried out. The diffusion behaviours of water in membrane is investigated by MRI in order to develop the polymer electrolyte fuel cells.The solvent diffusions and the swollen behaviors were investigated by MRI for hydroxy methyl cellulose,high amylose starch tablets, poly(ethylene methacrylate)/poly(2-hydroxyethyl methacrylate)-co-tetrahydro-... 

Figure 5. Amount of absorbed fibrinogen on copolymer surface including hydrophilic domain at 37 C. GEMA glucosyloxyethyl methacrylate, HEMA 2-hydroxyethyl methacrylate, MMA methyl methacrylate, GEMA-MMA poly(GEMA-co-MMA), and HEMA-MMA poly(HEMA-co-MMA).

APTMOS 3-amino-propyl-trimethoxysilane, AuHFA fluoroalcohol-coated gold nanospheres, BBCB bisbenzocy-clobutene, BCB benzocyclobutene, CA cellulose acetate, CAB cellulose acetate-butyrate, CEE chloroethyl ether, DIMP diisopropyl methylphosphonate, DMMP dimethyl methylphosphonate, EPR epoxidized novolac, IPA isopropanol, OV-225 cyanopropyl methyl phenylmethyl silicone, OV-275 dicyanoallyl sihcone, PAAM polyallylamine hydrochloride, PAPPS propylaminopropyl polysiloxane, PDMS poly(dimethylsiloxane), PECH polyepichlorohydrin, PEG polyethylene glycol, PEI polyethyleneimine, PEO polyethylene oxide, PEVA polyethylene-co-vinyl acetate, PEUT poly(ether urethane), PHEMA poly(2-hydroxyethyl methacrylate), PIB polyisobutylene, PMMA poly(methyl methacrylate), PTMOS propyltrimethoxysilane, PVA polyvinyl alcohol, PVP polyvinylpyrrolidone, SXFA siloxanefluoroalcohol... 

Until 2003, Chen s [28], Qu s [29-31], and Hu s [32] groups independently reported nanocomposites with polymeric matrices for the first time the. In Hsueh and Chen s work, exfoUated polyimide/LDH was prepared by in situ polymerization of a mixture of aminobenzoate-modified Mg-Al LDH and polyamic acid (polyimide precursor) in N,N-dimethylactamide [28]. In other work, Chen and Qu successfully synthesized exfoliated polyethylene-g-maleic anhydride (PE-g-MA)/LDH nanocomposites by refluxing in a nonpolar xylene solution of PE-g-MA [29,30]. Then, Li et al. prepared polyfmethyl methacrylate) (PMMA)/MgAl LDH by exfoliation/adsorption with acetone as cosolvent [32]. Since then, polymer/LDH nanocomposites have attracted extensive interest. The wide variety of polymers used for nanocomposite preparation include polyethylene (PE) [29, 30, 33 9], polystyrene (PS) [48, 50-58], poly(propylene carbonate) [59], poly(3-hydroxybutyrate) [60-62], poly(vinyl chloride) [63], syndiotactic polystyrene [64], polyurethane [65], poly[(3-hydroxybutyrate)-co-(3-hydroxyvalerate)] [66], polypropylene (PP) [48, 67-70], nylon 6 [9,71,72], ethylene vinyl acetate copolymer (EVA) [73-77], poly(L-lactide) [78], poly(ethylene terephthalate) [79, 80], poly(caprolactone) [81], poly(p-dioxanone) [82], poly(vinyl alcohol) [83], PMMA [32,47, 48, 57, 84-93], poly(2-hydroxyethyl methacrylate) [94], poly(styrene-co-methyl methacrylate) [95], polyimide [28], and epoxy [96-98]. These nanocomposites often exhibit enhanced mechanical, thermal, optical, and electrical properties and flame retardancy. Among them, the thermal properties and flame retardancy are the most interesting and will be discussed in the following sections. 

Poly[2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl methacrylate-co-acrylonitrile] see poly(acrylonitrile-co-[2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl methacrylate]) 374... 

Up to now, poly(methyl methacrylate) and methyl methacrylate copolymers e.g. with styrene, butyl acrylate and dodecyl methacrylate) have been the most widely used acrylic polymers for nanocomposite preparation by emulsion and suspension polymerization. Less research has been based on other acrylic polymers, such as polyacrylonitrile, poly(butyl acrylate), " poly(butyl methacrylate), poly(2-ethylhexyl acrylate), poly(2-hydroxyethyl methacrylate), polyacrylamide, poly(lauryl acrylate)," poly(butyl acrylate-co-styrene)," " poly(acrylonitrile-co-styrene), poly(acrylonitrile-co-meth-acrylate)," poly(ethyl acrylate-co-2-ethylhexyl acrylate)" and poly(2-ethylhexyl acrylate-co-acrylic acid)," and sometimes small amounts of hydophilic acrylic monomers, such as hydroxyethyl methacrylate, methacrylic acid and acrylic acid, have been used as comonomers. " Therefore, it may be stated that, so far, the preparation of acrylic-clay nanocomposites has been based mainly on high glass transition temperature polymers, although nanocomposite materials with lower glass transition temperatures with improved or novel properties, which exhibit a balance of previous antagonistic properties, can also be achieved and are very desirable. Regarding nanocomposites of low glass transition temperature polymers, such as poly(butyl acrylate), poly(ethyl acrylate) and poly(2-ethylhexyl acrylate), which have been utilized as the main components of acrylic pressure-sensitive adhesives, little information is available. 

Preparation of Poly(Methyl Methacrylate-co-2-Hydroxyethyl Methacrylate)... 

Most research into the study of dispersion polymerization involves common vinyl monomers such as styrene, (meth)acrylates, and their copolymers with stabilizers like polyvinylpyrrolidone (PVP) [33-40], poly(acrylic acid) (PAA) [18,41],poly(methacrylicacid) [42],or hydroxypropylcellulose (HPC) [43,44] in polar media (usually alcohols). However, dispersion polymerization is also used widely to prepare functional microspheres in different media [45, 46]. Some recent examples of these preparations include the (co-)polymerization of 2-hydroxyethyl methacrylate (HEMA) [47,48],4-vinylpyridine (4VP) [49], glycidyl methacrylate (GMA) [50-53], acrylamide (AAm) [54, 55], chloro-methylstyrene (CMS) [56, 57], vinylpyrrolidone (VPy) [58], Boc-p-amino-styrene (Boc-AMST) [59],andAT-vinylcarbazole (NVC) [60] (Table 1). Dispersion polymerization is usually carried out in organic liquids such as alcohols and cyclohexane, or mixed solvent-nonsolvents such as 2-butanol-toluene, alcohol-toluene, DMF-toluene, DMF-methanol, and ethanol-DMSO. In addition to conventional PVP, PAA, and PHC as dispersant, poly(vinyl methyl ether) (PVME) [54], partially hydrolyzed poly(vinyl alcohol) (hydrolysis=35%) [61], and poly(2-(dimethylamino)ethyl methacrylate-fo-butyl methacrylate)... 

Poly(aciyloiiitrile-co-[2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl methacrylate] 374... 

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