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Poly-t-Caprolactone

Figure 4. Single crystal of poly(t-caprolactone) and its electron diffractogram... Figure 4. Single crystal of poly(t-caprolactone) and its electron diffractogram...
Diglycidyl Ether of Bisphenol-A Poly(t-Caprolactone) (DGEBA/PCL) Blends... [Pg.96]

Ouhadi, T., Stevens, C., and Teyssie, P., Study of poly-e-caprolactone bulk degradation, J. Appl. Polym. Sci., 20, 2963-2970, 1976. [Pg.115]

Marchal-Heussler, L. Fessi, H. Devissaguet, J.P. Hoffman, M. Maincent, P. Colloidal drug delivery systems for the eye. A comparison of the efficacy of three different polymers polyisobutylcyanoacrylate, poly (lactic-co-glycolic Acid, poly-epsilon caprolactone. S.T.P. Pharma 1992, 2, 98-104. [Pg.1199]

Fig. 24. Experimental and simulated ( H)- C cross-polarization spectra of poly-5-caprolactone nanospheres in aqueous suspension after 12 h freezing. The calculated spectrum reproduces the carbon spectmm of four different methylene groups based on the chemical shift anisotropy listed in Table 1. It represents a superposition of two fractions of different isotropic mobility (80% T=0.1 ms 20% r=0.007 ms). Fig. 24. Experimental and simulated ( H)- C cross-polarization spectra of poly-5-caprolactone nanospheres in aqueous suspension after 12 h freezing. The calculated spectrum reproduces the carbon spectmm of four different methylene groups based on the chemical shift anisotropy listed in Table 1. It represents a superposition of two fractions of different isotropic mobility (80% T=0.1 ms 20% r=0.007 ms).
Figure 5. Effect of Terminating Agent on GPC of Poly-e-caprolactone (t-C HgLi in benzene)... Figure 5. Effect of Terminating Agent on GPC of Poly-e-caprolactone (t-C HgLi in benzene)...
Cordova, A., Iversen, T., and Hult, K. (1999) Lipase-catalyzed formation of end-functionalized poly(e-caprolactone) by initiation and termination reactions. Polymer, 40 (24), 6709-6721. [Pg.127]

Blends of enzymatically synthesized poly(bisphenol-A) and poly(p-t-butylphenol) with poly(e-caprolactone) (poly(e-CL)) were examined [84]. FT-IR analysis showed the expected strong intermolecular hydrogen bonding interaction between the phenolic polymer with poly(e-CL). A single Tg was observed for the blend, and the value increased as a function of the polymer content, indicating their good miscibility in the amorphous state. In the blend of enzymatically synthesized poly(4,4 -oxybisphenol) with poly(e-CL), both polymers were also miscible in the amorphous phase [85], The crystallinity of poly(e-CL) decreased by poly(4,4 -oxybisphenol). [Pg.176]

The unique signals at 4.23 (t, 0CH2) and 2.64 (t, C(0)CH2) were assigned to the protons of e-caprolactone. Signals at 4.06 (t, OCHl), (t, ROCH2), and 2.30 (t, C(O)Cffi) appeared after tiie onset of polymerization reactions mid were assigned to poly(e-caprolactone). The relative intensity of signals at 4.06 to 4.23 and 4.06 to 3.64 were used to calculate monomer conversion and Mi, respectively. [Pg.273]

Kim, T.G. Lee, D.S. Park, T.G. Controlled protein release from electrospun biodegradable fiber mesh composed of poly(epsilon-caprolactone) and poly (ethylene oxide). Int. J. Pharm. 2007, 338 (1-2), 276-283. [Pg.1328]

Yu, T., Ren, J., Gu, S., and Yang, M. (2010). Preparation and characterization of biodegradable polyQactic acid)-block-poly(c-caprolactone) multiblock copolymer. Polym Adv. TechnoL, 21,183-188. [Pg.893]

D. Cohn, T. Stern, M. Gonzalez, J. Epstein, Biodegradable poly(ethylene oxide)/poly(epsilon-caprolactone) multiblock copolymers, J. Biomed. Mater. Res. 59 (2) (2002) 273-281. [Pg.142]

Mariani, P.D.S.C., Allganer, K., Oliveira, F.B., Cardoso, E.J.B.N., Irmocentini-Mei, L.H. Effect of soy protein isolate on the thermal, mechanical and morphological properties of poly (epsilon-caprolactone) and com starch blends. Polym. Testing 28(8), 824—829 (2009) Fornes, T.D., Yoon, P.J., Keskkula, H., Paul, D.R. Nylon 6 nanocomposites the effect of matrix molecular weight Polymer 42(25), 09929-09940 (2001)... [Pg.168]

Matsuda, T. Mizutani, M. (2002) Liquid acrylate-endcapped biodegradable poly(epsilon-caprolactone-co-trimethylene carbonate). II. Computer-aided stereolithographic microarchitectural surface photoconstructs. Journal of Biomedical Materials Research, 62, 395—403. [Pg.88]

Aho, A. J., Tiiri, T., Kukkonen, J., Strandberg, N., Rich, J., Seppala, J. Yb-Urpo, A. (2004) Injectable bioactive glass/biodegtadable polymer composite for bone and cartilage reconstruction concept and experimental outcome with thermoplastic composites of poly(e-caprolactone-co-D,L-lactide) and bioactive glass S53P4. Journal of Materials Science Materials in Medicine, 15, 1165—73. [Pg.171]

Chang, Y.-W, Eom, J.-R, Kim, J.-G., Kim, H.-T., and Kim, D.-K. 2010. Rreparation and characterization of shape memory polymer networks based on carboxyl-ated telechelic poly(e-caprolactone)/epoxidized natural rubber blends. Journal of Industrial and Engineering Chemistry 16 256-260. [Pg.25]

Two-step fabrication of Sylgard/poly(e-caprolactone) (PCL) shape memory elastomeric composites. (Adapted from Luo, X., and Mather, P. T. 2009. Preparation and characterization of shape memory elastomeric composites. Macromolecules 42 7251-7253. Copyright ACS. Reproduced with permission.)... [Pg.137]

Senda, T., He, Y. and Inoue, Y. (2002) Biodegradable blends of poly(E-caprolactone) with o-chitin and chitosan specific interactions, thermal properties and crystallisation behaviour. Polymer International, 51,33-39. [Pg.80]

Honma, T., Zhao, L., Asakawa, N. and Inoue, Y. (2006) Poly(e-caprolactone)/chitin and poly(e-caprolactone)/chitosan blend films with compositional gradients fabrication and their biodegradability. [Pg.83]

Honma, T., Senda, T. and Inoue, Y. (2003) Thermal properties and crystallization behaviour of blends of poly(s-caprolactone) with chitin and chitosan. Polymer International, 52(12), 1839-1846. [Pg.83]

Tsuji, H., Yamada, T, Suzuki, M. and Itsuno, S. (2003) Blends of aliphatic polyesters VII. Effects of poly(L-lactide-co-e-caprolactone) on morphology, structure, crystallization, and physical properties of blends of poly(L-lactide) and poly(s-caprolactone). Polymer International, 52, 269-275. [Pg.225]

Tsuji, H. and Ishizaka, T. (2001) Porous biodegradable polyesters. 2. Physical properties, morphology, and enzymatic and alkaline hydrolysis of porous poly(E-caprolactone) Films. Journal of Applied Polymer Science, 80, 2281-2291. [Pg.233]

Tsuji, H., Suzuyoshi, K., Tezuka, Y. and Ishida, T. (2003) Environmental degradation of biodegradable polyesters 3. Effects of alkaM-treatment on biodegradation of poly(E-caprolactone) and poly[(R)-3-hydroxybutyrate] films in controlled soil. Journal of Polymers and the Environment, 11, 57-65. [Pg.233]

Ostas E, Schroter K, Beiner M, Yan TZ, Thum-Albrecht T, Binder WH (2011) Poly(epsilon-caprolactone)-poly(isobutylene) a crystallizing, hydrogen-bonded pseudo-block copolymer. J Polym Sci Polym Chem 49(15) 3404—3416... [Pg.95]


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