Pasted Plates

Curing is the process of exposing plates pasted positive and negative to a regime of (a) controlled time (minimum 32h), (b) temperature (30-35°C), and (c) relative humidity (>90%). This process converts the free lead into lead oxide, using oxygen from the surrounding air. The plates are allowed to cure for a minimum of 32 h. Care is also taken to ensure that the maximum temperature of the plate does not exceed 60°C. The cured plates are then parted. 

This chapter reviews the effects of additives in the positive active-material of the lead acid battery. Common materials found in the oxide and the positive-plate paste, such as lead oxides, basie lead sulfates, and lead earbonate, are not included. Additives and impurities that derive from grid eorrosion or from the reaction of the plate with the electrolyte are also beyond the seope of this chapter. 

The depth to which lead sulfate penetrates is dependent on the rate of discharge, as well as on the density and surface area of the plate. Paste density is the key factor in providing the macropores which are necessary for the transport of solution and ionic species to and from the reaction sites within the interior of the plate, while surface area provides sites for the current-generating electrochemical reaction. For the same paste density and surface area, the extent to which lead sulfate can penetrate is determined by the discharge rate. 

Let us first discuss the applicability of 4BS pastes in the battery industry. Batteries produced with positive plates pasted with 4BS pastes have the longest cycle life, but their initial capacity is lower than the rated value and they need several preliminary cycles to reach the rated capacity. 

In the first one, the measuring stand consists of the horizontal cylinder divided in two chambers by separation with plate paste specimen, in which the diffusion is to be determined. One chamber is filled with NaCl or CaCl2, the second one with deionized water or Ca(OH)2 saturated solution. For these solution the following requirements are recommended by Marchand et al. [197] ... 

Because liquid crystals are fluids, they also show anisotropy in their flow behaviom. This can easily be imderstood by imagining measuring the viscosity of a liquid crystal by placing it between two flat plates and measuring the force necessary to move one plate past the other at a certain velocity. In Figure 2.1, the plates lie in the xy plane and are separated by a distance d. The bottom plate is fixed and the force acting on the top plate is in the x-direction, F. The velocity of the top plate is also in the x-direction, v. ... 

The following are some important design criteria for water injection systems. Arrangement of the nozzles. The nozzles should be located on the roof or on the outlet end wall of the cooler. There should be several nozzles, whose jets should not overlap. Wetting the clinker must not begin earlier than at least five rows of plates past the recuperative zone and must be completed at least five rows ahead of the discharge end of the grate, so as to ensure that recuperation will not be impaired and that all the water will have evaporated before the clinker leaves the cooler. 

When only small traction performance is required, cells with fiat plates (pasted plates) are used because of the lower price compared with the tubular cells. Cycles of 800 to 1000 can be performed. These types are on the market with a voltage of 24 V and capacities between 200 and 250 Ah. 

HIGH DENSITY PLATE PASTE FOR HIGHER ELECTRICAL OUTPUT AND MORE CYCLING LIFE... 

Phthalide. In a 1 litre bolt-head flask stir 90 g. of a high quality zinc powder to a thick paste with a solution of 0 5 g. of crystallised copper sulphate in 20 ml. of water (this serves to activate the zinc), and then add 165 ml. of 20 per cent, sodium hydroxide solution. Cool the flask in an ice bath to 5°, stir the contents mechanically, and add 73-5 g. of phthalimide in small portions at such a rate that the temperature does not rise above 8° (about 30 minutes are required for the addition). Continue the stirring for half an hour, dilute with 200 ml. of water, warm on a water bath imtil the evolution of ammonia ceases (about 3 hours), and concentrate to a volume of about 200 ml. by distillation vmder reduced pressure (tig. 11,37, 1). Filter, and render the flltrate acid to Congo red paper with concentrated hydrochloric acid (about 75 ml. are required). Much of the phthalide separates as an oil, but, in order to complete the lactonisation of the hydroxymethylbenzoic acid, boil for an hour transfer while hot to a beaker. The oil solidifles on cooling to a hard red-brown cake. Leave overnight in an ice chest or refrigerator, and than filter at the pump. The crude phthalide contains much sodium chloride. RecrystaUise it in 10 g. portions from 750 ml. of water use the mother liquor from the first crop for the recrystaUisation of the subsequent portion. Filter each portion while hot, cool in ice below 5°, filter and wash with small quantities of ice-cold water. Dry in the air upon filter paper. The yield of phthalide (transparent plates), m.p. 72-73°, is 47 g. 

The American version of the dynamic filter, known as the Artisan continuous filter (Fig. 30), uses such nonfiltering rotors in the form of turbine-type elements. The cylindrical vessel is divided into a series of disk-type compartments, each housing one rotor, and the stationary surfaces are covered with filter cloth. The feed is pumped in at one end of the vessel, forced to pass through the compartments in series, and discharged as a thick paste at the other end. At low rotor speeds the cake thickness is controlled by the clearance between the scraper and the filter medium on the stationary plate, while at higher speeds part of the cake is swept away and only a thin layer remains and acts as the actual medium. 

The diluent portion also determines the form, or physical appearance, of the flavor, ie, Hquid, powder, or paste. Liquid flavor forms include water-soluble, oil-soluble, and emulsion forms powder flavor forms include plated (including dry solubles), extended, occluded, inclusion complexes, and other encapsulated forms and paste flavor forms include fat, protein, and carbohydrate-based paste. 

Compounded Flavors. Liquid or dry blends of natural or synthetic flavor compounds are called compounded flavors. Most commercial preparations are available as water- and oil-soluble Hquids, spray-dried and plated powders, emulsions, and carbohydrate-, protein-, and fat-based pastes. Compounded flavors are used throughout the food industry in confections, baked goods, snack foods, carbonated beverages, and processed foods (53). 

Three-Piece Cans. Most steel cans, whether or not tin-plated, are three-piece, ie, a body and two ends. In the past, solder was used to bond the longitudinal seam, but solder has been replaced by welded side seams. 

The principal types of scrap are battery plates and paste, drosses, skimmings, and industrial scrap such as solders, babbitts, cable sheathing, etc. 

In paste drying the leather is spread on glass or porcelain plates and held in place with a low strength water-soluble paste. The plates are on a conveyor and the drying is done in a drying tunnel. The dryer usually has several temperature- and humidity-controUed zones to control the rate of drying and to prevent overdrying. 

Selective Carburi ng. In most components, it is desirable to carburize only parts of the surface. To prevent other regions from carburizing, they must be protected. For holes, simple plugs of copper may be used. In some cases, copper plating can be appHed, but diffusion into the steel must be considered, and the copper may have to be machined off later. Coatings (qv), which can be appHed as a paste and then removed after heat treatment, are also available and include copper plating, ceramic coatings, and copper and tin pastes. 

Electronic Applications. The PGMs have a number of important and diverse appHcations in the electronics industry (30). The most widely used are palladium and mthenium. Palladium or palladium—silver thick-film pastes are used in multilayer ceramic capacitors and conductor inks for hybrid integrated circuits (qv). In multilayer ceramic capacitors, the termination electrodes are silver or a silver-rich Pd—Ag alloy. The internal electrodes use a palladium-rich Pd—Ag alloy. Palladium salts are increasingly used to plate edge connectors and lead frames of semiconductors (qv), as a cost-effective alternative to gold. In 1994, 45% of total mthenium demand was for use in mthenium oxide resistor pastes (see Electrical connectors). 

Flame plating (D-gun) employs oxygen and fuel gas. In this method, developed by the Union Carbide Corporation, the gas mixture is detonated by an electric spark at four detonations per second. The powders, mixed with the gas, are fed under control into a chamber from which they are ejected when detonation occurs. The molten, 14—16-pm particles are sprayed at a velocity of 732 m/s at distances of 5.1—10.2 cm from the surface. The substrate is moved past the stationary gun. 

To reduce labor and other expenses, most sintered nickel plaques are produced by a wet-slurry method. A nickel slurry is prepared by mixing a low density nickel powder with a viscous aqueous solution such as carboxymethylceUulose [9004-42-6] (CMC). Pure nickel gau2e, a nickel-plated gau2e, or a nickel-plated perforated steel strip is continuously carried through a container filled with the nickel paste and sintering is done in a hori2ontal furnace. The time of the sinter in the furnace is ca 10—20 min. 

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