Mixing pasted plates

Flame plating (D-gun) employs oxygen and fuel gas. In this method, developed by the Union Carbide Corporation, the gas mixture is detonated by an electric spark at four detonations per second. The powders, mixed with the gas, are fed under control into a chamber from which they are ejected when detonation occurs. The molten, 14—16-pm particles are sprayed at a velocity of 732 m/s at distances of 5.1—10.2 cm from the surface. The substrate is moved past the stationary gun. 

To reduce labor and other expenses, most sintered nickel plaques are produced by a wet-slurry method. A nickel slurry is prepared by mixing a low density nickel powder with a viscous aqueous solution such as carboxymethylceUulose [9004-42-6] (CMC). Pure nickel gau2e, a nickel-plated gau2e, or a nickel-plated perforated steel strip is continuously carried through a container filled with the nickel paste and sintering is done in a hori2ontal furnace. The time of the sinter in the furnace is ca 10—20 min. 

Paste Mixing. The active materials for both positive and negative plates are made from the identical base materials. Lead oxide, fibers, water, and a dilute solution of sulfuric acid are combined in an agitated batch mixer or reactor to form a pastelike mixture of lead sulfates, the normal, tribasic, and tetrabasic sulfates, plus PbO, water, and free lead. The positive and negative pastes differ only in additives to the base mixture. Organic expanders, barium sulfate [7727-43-7] BaSO carbon, and occasionally mineral oil are added to the negative paste. Red lead [1314-41 -6] or minium, Pb O, is sometimes added to the positive mix. The paste for both electrodes is characterized by cube weight or density, penetration, and raw plate density. 

The plate heat exchanger consists of a frame in which closely spaced metal plates are clamped between a head and follower. The plates have corner ports and are sealed by gaskets around the ports and along the plate edges. A double seal forms pockets open to atmosphere to prevent mixing of product and service liquids in the rare event of leakage past a gasket. 

Figure 6. Vacuum mixer for lead paste 1, mixing compartment 2, fast-rotating mixing tools 3, material-deflecting plate 4, discharge opening 5, static, vacuum-sealed enclosure [21J.

All AB, alloys are very brittle and are pulverized to fine particles in the hydrid-ing-dehydriding process (see Sec. 7.2.1). Thus electrodes must be designed to accommodate fine powders as the active material. There are several methods of electrode fabrication Sakai et al [35] pulverize the alloy by subjecting it to several hydrogen absorption-desorption cycles, before coating the resulting particles with Ni by chemical plating. The powder is mixed with a Teflon dispersion to obtain a paste which is finally roller-pressed to a sheet and then hot-pressed to an expanded nickel mesh. The fabrication of a simple paste electrode suitable for laboratory studies is reported by Petrov et al. [37],... 

Separate meats from shells, grind twice at least 250 g in a food chopper equipped with 3 mm plate openings or other suitable devices that give a smooth homogeneous paste without loss of oil. Mix well and store in an airtight container. For butters and pastes, mix, warming semi-solid products. 

Halse and Pratt (H57) reported SEM observations on pastes hydrated at various temperatures. In those hydrated at 8°C or 23 C, the main feature was fibrous material that was considered to be hydrous alumina, but which could also have been partly dehydrated CAH,q. The hydrating grains of cement were surrounded by shells of hydration products, from w hich they tended to become separated in a manner similar to that observed with Portland cement pastes (Section 7.4.2) though the authors recognized that this could have been partly due to dehydration. Two-day-old pastes hydrated at 40"C showed spheroidal particles of CjAH and thin, flaky plates of gibbsite. In pastes mixed with sea water, hydration took place more slowly, but no other effects on microstructural development were observed. 

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