Oil in soybeans

Table A1.3.2 Typical Percent Oil in Soybean by Benchtop NMR and Comparison to Reference Method Values ...

As many will appreciate, the detection of small amounts of rapeseed oil in soybean oil can be easily accomplished by determination of sterol composition. Table 8.4 shows sterol compositions of nine oils, including rapeseed and soybean oil rapeseed oil contains quite significant quantities of brassicas-terol, whereas the level in soybean oil is almost zero. Table 8.4 also shows that rapeseed oil contains a small amount of cholesterol. In some countries it may be claimed that vegetable oils are free from cholesterol. Although this may be permitted under the local law, it is not, of course, scientifically correct. 

Because of the zwitterion formation, mutual buffering action, and the presence of strongly acid components, soybean phosphoHpids have an overall pH of about 6.6 and react as slightly acidic in dispersions-in-water or in solutions-in-solvents. Further acidification brings soybean phosphoHpids to an overall isoelectric point of about pH 3.5. The alcohol-soluble fraction tends to favor oil-in-water emulsions and the alcohol-insoluble phosphoHpids tend to promote water-in-oil emulsions. 

The total commercial lecithin potential if all vegetable oils were degummed worldwide would be 552,000 t (Table 7). Although soybean, sunflower, and rape lecithins are available in the market, the principal commercial interest is only in soybean lecithin. The aimual worldwide production is 130,000 t (Table 8). 

Other Sources. The four oils named above are the most commonly used fats and oils in the soap-making industry in the United States, but other sources are also utilized throughout the world, including lard or hog fat. Babassu oil, rice brand oil, and soybean oil. 

Soybeans are the most important oilseed in international trade. The United States, Bra2il, and Argentina are the main suppHers to the export markets. In 1994—1995, United States exports of 22.0 x 10 metric tons represented 32% of the domestic production, 16% of the world crop, and 69% of the international trade in soybeans. The European Union, Japan, Mexico, and Taiwan were the largest importers of soybeans (51). Japan, which produces <5% of its soybean needs, is the largest single soybean customer of the United States. Japan imported 3.4 x 10 t in 1994 (51). The United States also exports processed soybean products, eg, oil and meal. For 1990—1993, an average of 47% of the crop was exported as whole beans and processed products. 

Edible Oil. For edible uses, oilseed oils are processed into salad and cooking oils, shortenings, margarines, and confectionery fats such as for candy, toppings, icings, and coatings (73). These products are prepared by a series of steps, as outlined for soybean oil in Figure 6. 

Polyunsaturated fatty acids in vegetable oils, particularly finolenic esters in soybean oil, are especially sensitive to oxidation. Even a slight degree of oxidation, commonly referred to as flavor reversion, results in undesirable flavors, eg, beany, grassy, painty, or fishy. Oxidation is controlled by the exclusion of metal contaminants, eg, iron and copper addition of metal inactivators such as citric acid minimum exposure to air, protection from light, and selective hydrogenation to decrease the finolenate content to ca 3% (74). Careful quality control is essential for the production of acceptable edible soybean oil products (75). 

Cobalt in Driers for Paints, Inks, and Varnishes. The cobalt soaps, eg, the oleate, naphthenate, resinate, Hnoleate, ethyUiexanoate, synthetic tertiary neodecanoate, and tall oils, are used to accelerate the natural drying process of unsaturated oils such as linseed oil and soybean oil. These oils are esters of unsaturated fatty acids and contain acids such as oleic, linoleic, and eleostearic. On exposure to air for several days a film of the acids convert from Hquid to soHd form by oxidative polymeri2ation. The incorporation of oil-soluble cobalt salts effects this drying process in hours instead of days. Soaps of manganese, lead, cerium, and vanadium are also used as driers, but none are as effective as cobalt (see Drying). 

Figure 10.14 Schematic representation of the SFSPE/SFC set-up developed by Murugaverl and Vooi hees (67). Reprinted from Journal of Microcolumn Separation, 3, B. Mumgaverl and K. J. Vooi hees, On-line supercritical fluid exti aaion/chromatography system for ti ace analysis of pesticides in soybean oil and rendered fats , pp. 11-16, 1991, with permission from John Wiley and Sons, Inc.

Sterile air was supplied at 1,200 liters per minute. Antifoam was added in 25 ml amounts as required. (10% Piuronic LSI in soybean oil.) The fermentation was controlled at 26°C until a maximum yield of clevulanic acid wes obtained between 3-5 days when 200-300 /.Ig/ml of clavulanic acid were produced. 

Biodiesel is diesel fuel produced from vegetable oils and other renewable resources. Many different types of oils can he used, including animal fats, used cooking oils, and soybean oil. Biodiesel is miscible with petroleum diesels and can he used in biodiesel-diesel blends. Most often blends are 20 percent biodiesel and 80 percent traditional diesel. Soy diesel can be used neat (100%), hut many other types of biodiesel are too viscous, especially in winter, and must be used in blends to remain fluid. The properties of the fuel will vaiy depending on the raw material used. Typical values for biodiesel are shown in Table 1. 

Flaky piecrusts used to contain lard, or at least butter. Solid fats are important in baking, as they separate sheets of dough into thin, independent flakes. Traditional solid fats are animal-derived saturated fats, such as lard and butter. Some vegetable fats, such as coconut and palm kernel oils, are solid, but they are more expensive than some liquid vegetable oils like corn oil, cottonseed oil, or soybean oil. These oils come from plants that are used for more than just the oil they provide. Using several different parts of the plant makes growing them more economical. 

The raw materials for the manufacture of soap, the alkali salts of saturated and unsaturated C10-C20 carboxylic acids, are natural fats and fatty oils, especially tallow oil and other animal fats (lard), coconut oil, palm kernel oil, peanut oil, and even olive oil. In addition, the tall oil fatty acids, which are obtained in the kraft pulping process, are used for soap production. A typical formulation of fats for the manufacture of soap contains 80-90% tallow oil and 10-20% coconut oil [2]. For the manufacture of soft soaps, the potassium salts of fatty acids are used, as are linseed oil, soybean oil, and cottonseed oil acids. High-quality soap can only be produced by high-quality fats, independent of the soap being produced by saponification of the natural fat with caustic soda solution or by neutralization of distilled fatty acids, obtained by hydrolysis of fats, with soda or caustic soda solutions. Fatty acids produced by paraffin wax oxidation are of inferior quality due to a high content of unwanted byproducts. Therefore in industrially developed countries these fatty acids are not used for the manufacture of soap. This now seems to be true as well for the developing countries. 

Plant uptake is one of several routes by which an organic contaminant can enter man s food chain. The amount of uptake depends on plant species, concentration, depth of placement, soil type, temperature, moisture, and many other parameters. Translocation of the absorbed material into various plant parts will determine the degree of man s exposure—i.e., whether the material moves to an edible portion of the plant. Past experience with nonpolar chlorinated pesticides suggested optimal uptake conditions are achieved when the chemical is placed in a soil with low adsorptive capacity e.g., a sand), evenly distributed throughout the soil profile, and with oil producing plants. Plant experiments were conducted with one set of parameters that would be optimal for uptake and translocation. The uptake of two dioxins and one phenol (2,4-dichlorophenol (DCP)) from one soil was measured in soybean and oats (7). The application rates were DCP = 0.07 ppm, DCDD 0.10 ppm, and TCDD = 0.06 ppm. The specific activity of the com-... 

Preparation of lipid microspheres. The lipid microspheres (lipo-PGEj) with a diameter of 0.2 to 0.3 p m arc prepared from the drug, soybean oil and lecithin (Figure 1). The drug to be enclosed in the microspheres is first dissolved in soybean oil, and then emulsified with lecithin by a Manton-Gaulin homogenizer (7,2). 

Pd(acac)2 has been reported to be an active catalyst in soybean oil hydrogenation [47]. The reactions were conducted in bulk with low catalyst loadings (1-60 ppm) and without any co-catalyst. Under 10 atm H2 pressure and at 80-120 °C, optimum linolenate selectivity and high trans-isomers content were obtained. Decomposition of the catalyst occurred at temperatures above 120 °C. 

The first NIR instruments were, in reality, developed for the UV and Vis regions of the spectrum. They were made by seven companies Beckman, Cary (now owned by Varian), Coleman, Perkin-Elmer, Shimadzu, Unicam, and Zeiss. Based on the work of Karl Norris and coworkers in the USDA, the Illinois Department of Agriculture solicited bids from companies to produce a pure NIR instrument, capable of measuring protein, oil, and moisture in soybeans. 

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