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Measurement methods ozone

Measurements of ozone concentration in the ozone layer in the stratosphere are made in the less intense Huggins band to avoid complete absorption of the laser radiation. Again, the two or three wavelength DIAL method is used to make allowance for background aerosol scattering. A suitable laser for these measurements is the XeCl pulsed excimer laser (see Section 9.2.8) with a wavelength of 308 nm, close to the peak absorption of the Huggins... [Pg.381]

Ozone can be analyzed by titrimetry, direct and colorimetric spectrometry, amperometry, oxidation—reduction potential (ORP), chemiluminescence, calorimetry, thermal conductivity, and isothermal pressure change on decomposition. The last three methods ate not frequently employed. Proper measurement of ozone in water requites an awareness of its reactivity, instabiUty, volatility, and the potential effect of interfering substances. To eliminate interferences, ozone sometimes is sparged out of solution by using an inert gas for analysis in the gas phase or on reabsorption in a clean solution. Historically, the most common analytical procedure has been the iodometric method in which gaseous ozone is absorbed by aqueous KI. [Pg.503]

Sheeter [17] has discussed an ultraviolet method for the measurement of ozone in seawater. Crecelius [18] has discussed oxidation products obtained (bromine, hypobromous acid, bromate) when bromides in seawater are oxidised by ozone. [Pg.126]

In addition to the specificity of the monitoring method, an important requirement for the measurement of atmospheric pollutants is the accuracy of the calibration technique. The calibration procedure for the measurement of oxidants or ozone utilizes a stable and reproducible sample of dilute ozone in air. The ozone concentration of this sample is established with a reference method that is not necessarily suitable for monitoring ambient air. This reference method must agree with the scientifically accurate measurement of ozone in the calibration sample. [Pg.242]

Many deleterious effects have been associated with photochemically polluted air ozone is deflnitely associated with respiratory problems, plant damage, and material damage PAN has deflnitely been associated with plant damage, and some other members of this class of chemical compounds have been associated with eye irritation the hydroxyl radical is considered to be an important factor in the conversion of gas-phase intermediates to end products, such as sulfur dioxide to particulate sulfate the particulate complex is responsible for haze formation and has also been associated with eye irritation and respiratory effects. The aldehydes have been associated with eye irritation. Ozone and PAN themselves do not cause eye irritation. For purposes of control, much more research is needed, in order to relate the laboratory data about the concentrations of these various materials that have significant effects to their formation in the atmosphere from emission and their atmospheric distribution. The lack of convenient measurement methods has hindered progress in gaining this understanding. [Pg.268]

A number of significant oxygenated organic particulate compounds and gas-phase free radicals are formed by the reactions of gas-phase hydrocarbons (see Table 6-1 and (Chapter 2). The measurement methods for these substances are complicated and in the research stage. Their description is beyond the scope of this chapter. It is of major importance to develop methods for measuring hydroxyl and peroxyhydroxyl radicals, as well as the various oxygen species formed with ozone (see Chapter 12). [Pg.273]

Interferences—substances that exist simultaneously with ozone and alter the response of the measurement method. [Pg.274]

Differences in measurement methods include analyzer systems based both on the same and on different measurement principles. The average standard deviation in the performance of different chemiluminescent ozone instruments that are sampling the same ambient air both with and without an added ozone concentration of 0.(X)2-0.5 ppm is 6-10%. Field studies comparing an ultraviolet monitor with several chemiluminescent monitors showed correlation coefficients for hourly averages of 0.80-0.95 between various pairs of instruments. Hourly averages for about 500 pairs of values at ambient ozone concentrations of 0.005-0.100 ppm showed deviations of 3-23% between the average values for paired instruments. [Pg.275]

Droppo, J. G Jr., Concurrent Measurements of Ozone Dry Deposition Using Eddy Correlation and Profile Flux Methods, J. Geo-phys. Res., 90, 2111-2118 (1985). [Pg.40]

Detection techniques. Detection techniques for surface-based measurements of ozone include (1) UV absorption at 254 nm (2) chemiluminescence on reaction with NO (or ethene) (3) DOAS (4) TDLS and (5) wet chemical methods, mainly those involving the oxidation of I to 12 and measurement of the I2 colori-metrically or coulometrically. The wet chemical method and the principles behind DOAS and TDLS were discussed earlier and are not treated further here. [Pg.583]

Continuous Measurement Methods for Trace Cases and Aerosols. Ozone. Three basic types of ozone instruments have been used in aircraft the ultraviolet photometric method and two chemiluminescent techniques measuring, respectively, light emitted from the reaction of 03 with ethylene and light emitted from the reaction of 03 with NO. Ultraviolet absorption photometry is one of the preferred methods for measuring 03 from aircraft because of the stability and reliability of commercially available instruments. The method is specific for 03 provided there are no immediate... [Pg.130]

The reaction between olefins and ozone produces light that can be measured and related to the concentration of the reactants. One of the preferred methods for measuring ambient ozone concentrations utilizes the chemiluminescence generated in the ozone-ethylene reaction for detection. Recently, Hills and Zimmerman (16) described the use of this detection principle for determining hydrocarbon concentrations. They utilized the chemiluminescence created when ozone reacts with isoprene for development of a continuous, fast-response isoprene analyzer. This real-time isoprene system is reported to be linear over three orders of magnitude and to have a detection limit of about 1 ppbv. Because the system doesn t include a preseparation of hydrocarbons, interferences from other olefins (ethylene, propylene, and so forth) could occur. Thus far the chemiluminescent detector has been used to monitor isoprene emissions under conditions in which the concentrations of olefins that could interfere are negligible compared to those of the biogenic hydrocarbon. [Pg.296]

Parrish D. D. and Fehsenfeld F. C. (2000) Methods for gas-phase measurements of ozone, ozone precursors, and aerosol precursors. Atmoi. Environ. 34, 1921 — 1957. [Pg.4969]

Information on the amount of ozone generated by the lamp under various conditions is of interest to the research scientist, application engineer, and health officer. Many of the divergent views on the bactericidal effect and toxicity of ozone can be attributed to the methods of determination used by the authors as well as the purity of their gas. As an example, oxides of nitrogen were produced as a by-product by some of the early ozone generators. These oxides react with some of the reagents used for the measurement of ozone they have also been shown to be toxic (5, 26). Ultraviolet lamps do not produce oxides of nitrogen. [Pg.63]

Applicability of Method. The potential suitability of the colorimetric technique, for use in measuring atmospheric ozone concentration, was determined by repeating the ozonization procedure with unozonized air flowing at 0.40 cubic meter per hour, lodometric measurements of atmospheric ozone concentration were made simultaneously. [Pg.122]

Chemical measurement of ozone in terms of the release of iodine in a buffered potassium iodide solution. Recent improvements in this method permit the continuous recording of ozone concentration in terms of colorimetry or potentiometer readings 13,27). [Pg.270]

Color measurement of ozone in terms of oxidation of phenolphthalin (C2oHie04) to phenolphthalein (C20H14O4). In this method hydrogen peroxide is used to develop a standard curve 29, 34)-... [Pg.270]

Carter, W. P. L. and I. L. Malkina Development and application of Improved methods for measurement of ozone formation potentials of volatile organic compounds. Final report to California Air Resources Board Contract 97-314, May 22 (2002). Available at http //www.cert.ucr.edu/ carter/absts.htm ftrmethipt. [Pg.240]

Hydrogen peroxide was measured colorimetrlcally by complexation with Ti(IV) ("Tl4" method) ( ) or by the method of Masschelein et al. ( ) (MDL method). As ozone appears to interfere negatively with hydrogen peroxide measurement using the TI4 method, ozone was quickly and vigorously sparged from solution before peroxide measurements were made. The MDL method was not used on ozone-containing solutions. Total oxidants were measured iodi-metrically by the method of Flamm (30), but with the addition of a... [Pg.78]

Section II summarizes the chemical theory most important for the discussion of ozone in the troposphere, and typical tropospheric ozone concentrations are presented in Section III. Section IV contains a short description of the methods which are currently used to measure tropospheric ozone and problems and methods of tropospheric ozone trend determination are discussed in Section V. The present knowledge of trends of surface ozone in different parts of the world is summarized in Sections VI-IX and ozone trends of the free troposphere are summarized in Section X. Section XI includes the smnmaty and some conclusions. [Pg.272]

In the open path absorption method ozone in ambient air is measmed by its absorption in the UV. A UV-source with known intensities at different wavelengths provides the source of the UV-light and a receiver allows one to measure the decrease of the light at the respective wavelengths when the light beam passes through the air. The... [Pg.280]

On the other hand, ozone was S3mthesized in laboratories during this time, and an Irish chemist. Hartley, came up with a method for measuring absorption spectmm. As a result, it was found that ozone absorbs ultraviolet light most strongly at 200-320 nm, and this absorption band was therefore named the Hartley band after the chemist. Today, a standard method to measure ambient ozone concentration is to use an UV absorption instrument, which is based on the Hartley band. Data on the absorption spectrum of ozone took on even greater significance for chemistry of the atmosphere when it led to the discovery of the ozone layer in the stratosphere. Prior to this, scientists had measured the solar spectrum and learned that ultraviolet... [Pg.3]

We saw in Section 9.3.8 that spectroscopy, in the form of LIDAR, is a very important tool for measuring ozone concentration directly in the atmosphere. A useful indirect method involves the measurement of the concentration of oxygen which is formed from ozone by photolysis ... [Pg.384]

Reference methods for criteria (19) and hazardous (20) poUutants estabHshed by the US EPA include sulfur dioxide [7446-09-5] by the West-Gaeke method carbon monoxide [630-08-0] by nondispersive infrared analysis ozone [10028-15-6] and nitrogen dioxide [10102-44-0] by chemiluminescence (qv) and hydrocarbons by gas chromatography coupled with flame-ionization detection. Gas chromatography coupled with a suitable detector can also be used to measure ambient concentrations of vinyl chloride monomer [75-01-4], halogenated hydrocarbons and aromatics, and polyacrylonitrile [25014-41-9] (21-22) (see Chromatography Trace and residue analysis). [Pg.384]

Ozone in the gas phase can be deterrnined by direct uv spectrometry at 254 nm via its strong absorption. The accuracy of this method depends on the molar absorptivity, which is known to 1% interference by CO, hydrocarbons, NO, or H2O vapor is not significant. The method also can be employed to measure ozone in aqueous solution, but is subject to interference from turbidity as well as dissolved inorganics and organics. To eliminate interferences, ozone sometimes is sparged into the gas phase for measurement. [Pg.503]


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See also in sourсe #XX -- [ Pg.547 , Pg.548 , Pg.559 , Pg.736 , Pg.737 , Pg.738 ]




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Ozone measurement

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