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Ethylene ozonation

Peroxides can be obtained from ozonides in various ways. Dioxirane (246), the simplest cyclic peroxide, appears in the microwave spectrum of ethylene-ozone mixtures, in the — 115 to — 110 °C temperature range, probably as a decomposition product of the primary... [Pg.705]

Figure 5. Change in the energy of the ethylene+ozone system by the pathway of non-coordinated addition (1) in the singlet and (2) triplet states and (3) change in the y value in the former case UB3LYP calculations. Figure 5. Change in the energy of the ethylene+ozone system by the pathway of non-coordinated addition (1) in the singlet and (2) triplet states and (3) change in the y value in the former case UB3LYP calculations.
The second patent80 describes the conversion of ethylene into ethylene ozonide followed by the immediate decomposition of the latter into formaldehyde. The primary object in this process is to so regulate the reaction as to produce a large yield of formaldehyde or its polymerization product, paraformaldehyde, while reducing the formation of formic acid to a minimum. The procedure is similar to that which has been described in the case of the preceding patent and differs principally in the fact that no catalyst is employed. For example, ethylene, ozonized air and water vapor are introduced into a drum, tower, or other convenient form of apparatus which will facilitate an intimate mixture of the substances. The following reactions are supposed to occur ... [Pg.215]

This conclusion is analogoits to one in Ref [3], where such verifieation is done for ethylene-ozone reaction. [Pg.103]

For each type of component, its relative reactivity in ozone formation was taken into account which makes it possible to characterize by weighting the behavior of the overall motor fuel under the given experimental conditions. The overall reactivity is in fact governed by a limited number of substances ethylene, isobutene, butadiene, toluene, xylenes, formaldehyde, and acetaldehyde. The fuels of most interest for reducing ozone formation are those which contribute towards minimizing emissions of the above substances. [Pg.262]

Ozone ALkenes, aromatic compounds, bromine, diethyl ether, ethylene, HBr, HI, nitric oxide, nitrogen dioxide, rubber, stibine... [Pg.1210]

O ne. Air pollution (qv) levels are commonly estimated by determining ozone through its chemiluminescent reaction with ethylene. A relatively simple photoelectric device is used for rapid routine measurements. The device is caHbrated with ozone from an ozone generator, which in turn is caHbrated by the reaction of ozone with potassium iodide (308). Detection limits are 6—9 ppb with commercially available instmmentation (309). [Pg.276]

Chemiluminescent analyzers are based on the light (chemiluminescence) emitted in the gas-phase reaction of ozone with ethylene, which is measured with a photomultipHer tube. The resulting current is proportional to the ozone concentration (see Luminescent materials, chemiluminescence). [Pg.503]

There is evidence that dioxirane is an intermediate product in the low temperature ozonization of ethylene and is probably formed from the diradical resonance isomer of the 1,3-zwitterion (164). [Pg.118]

Chemiluminescence. Chemiluminescence (262—265) is the emission of light duting an exothermic chemical reaction, generaUy as fluorescence. It often occurs ia oxidation processes, and enzyme-mediated bioluminescence has important analytical appHcations (241,262). Chemiluminescence analysis is highly specific and can reach ppb detection limits with relatively simple iastmmentation. Nitric oxide has been so analyzed from reaction with ozone (266—268), and ozone can be detected by the emission at 585 nm from reaction with ethylene. [Pg.320]

Ozonc-rcsjstant elastomers which have no unsaturation are an exceUent choice when their physical properties suit the appHcation, for example, polyacrylates, polysulfides, siHcones, polyesters, and chlorosulfonated polyethylene (38). Such polymers are also used where high ozone concentrations are encountered. Elastomers with pendant, but not backbone, unsaturation are likewise ozone-resistant. Elastomers of this type are the ethylene—propylene—diene (EPDM) mbbers, which possess a weathering resistance that is not dependent on environmentally sensitive stabilizers. Other elastomers, such as butyl mbber (HR) with low double-bond content, are fairly resistant to ozone. As unsaturation increases, ozone resistance decreases. Chloroprene mbber (CR) is also quite ozone-resistant. [Pg.238]

Brassylic Acid. This acid is commercially available from Nippon Mining Company (Tokyo, Japan). It is made by a fermentation process (76). Several years ago, Emery Group, Henkel Corp. (Cincinnati, Ohio) produced brassyUc acid via ozonization of emcic acid primarily for captive use in making dimethyl brassylate and ethylene brassylate. A pilot-scale preparation based on ozonization of emcic acid has been described in which brassyUc acid yields of 72—82% were obtained in purities of 92—95%. Recrystallization from toluene gave purities of 99% (77). [Pg.63]

The process yields a random, completely soluble polymer that shows no evidence of crystallinity of the polyethylene type down to —60°C. The polymer backbone is fully saturated, making it highly resistant to ozone attack even in the absence of antiozonant additives. The fluid resistance and low temperature properties of ethylene—acryUc elastomers are largely a function of the methyl acrylate to ethylene ratio. At higher methyl acrylate levels, the increased polarity augments resistance to hydrocarbon oils. However, the decreased chain mobiUty associated with this change results in less fiexibihty at low temperatures. [Pg.498]

Ethylene—propylene elastomers exhibit a high resistance to oxygen, ozone, and heat, and are used in motor parts because of thek excellent low... [Pg.432]

Low-temperature spectroscopy is indispensable for the studies of processes on the ice surface, illustrated by ozone adsorption and ethylene ozonolysis. Such results are important to clarify the mechanism of atmospheric pollutant elimination and air purification in the nature. [Pg.431]

More recently, in 1975, Du Pont introduced a terpolymer (Vamac) based on ethylene, methyl acrylate and a third monomer of undisclosed composition which contained a carboxylic acid group to provide a cure site for use with peroxides or amines. Both types of rubber exhibit good heat, oxygen and ozone resistance. [Pg.301]

This still retains the initial ethylenic linkage and can be hydrogenated to heliotridane (II). The hydrochloride in water is oxidised by ozone to 2-acetylpyrrolidinoacetic acid (XIV) hydrochloride, m.p. 180-1°, — 4-4° (MeOH). In this the presenee of the. CO. CHj group is shown by a positive iodoform reaction and the formation of a 2 4-dinitro-... [Pg.611]

Ozonuies (1,2,4-trioxolanes) are generally obtained by the reaction of fluoroalkenes with ozone Thus, vmyl fluonde is oxidized to monofluoroozomde and formyl fluonde [23] (equation 15) The same ozomde is formed by ozonolysis of a mixture of cis 1,2-difluoroethylene with ethylene [24]... [Pg.326]

Unusually stable ozonides are prepared by treating mono- and bisffluroal-kyl)ethylenes with ozone [26] (equation 17)... [Pg.327]

D 2770 Ozone-Resist Ethylene-Propylene Rubber Integral Insulation Jacket for Wire Cable. [Pg.223]

D 2802 Ozone-Resistant Ethylene-Propylene Rubber Insulation for Wire Cable. [Pg.223]

The principal organic reaction of ozone is its addition to the carbon-carbon double bond of an ethylenic compd. The resulting ozone-olefin addition compd is known as an ozonide. Decompn of the ozonide gives a mixt of oxygenated products containing carbonyl compds and acids. [Pg.469]


See other pages where Ethylene ozonation is mentioned: [Pg.1450]    [Pg.1461]    [Pg.98]    [Pg.775]    [Pg.229]    [Pg.1450]    [Pg.1461]    [Pg.98]    [Pg.775]    [Pg.229]    [Pg.293]    [Pg.728]    [Pg.184]    [Pg.469]    [Pg.481]    [Pg.496]    [Pg.465]    [Pg.151]    [Pg.2178]    [Pg.464]    [Pg.197]    [Pg.110]    [Pg.238]    [Pg.529]    [Pg.468]    [Pg.473]    [Pg.309]    [Pg.395]   
See also in sourсe #XX -- [ Pg.478 , Pg.479 ]




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Ozone/ethylene double bond interaction

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