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Hydrocarbons Aromatic products

Similar to the attempt to obtain a high octane number from amixture of hydrocarbons aromatics production results from the following reactions ... [Pg.166]

Separation of Aromatic and Aliphatic Hydrocarbons. Aromatics extraction for aromatics production, treatment of jet fuel kerosene, and enrichment of gasoline fractions is one of the most important appHcations of solvent extraction. The various commercial processes are summarized in Table 4. [Pg.78]

ElexibiHty allows the operator to pick and choose the most attractive feedstock available at a given point in time. The steam-cracking process produces not only ethylene, but other products as weU, such as propylene, butadiene, butylenes (a mixture of monounsaturated C-4 hydrocarbons), aromatics, etc. With ethane feedstock, only minimal quantities of other products ate produced. As the feedstocks become heavier (ie, as measured by higher molecular weights and boiling points), increasing quantities of other products are produced. The values of these other coproduced products affect the economic attractiveness and hence the choice of feedstock. [Pg.171]

Paraffin and Aromatic Hydi ocarbon may be separated by the action of fuming sulphuric acid, 4iich forms the sulphonic and with the aromatic hydrocarbon. The product is poured into water. The sulphonic acid dissolves readily in water, whereas the paiaffin is insoluble. [Pg.344]

Liquid solvents are used to extract either desirable or undesirable compounds from a liquid mixture. Solvent extraction processes use a liquid solvent that has a high solvolytic power for certain compounds in the feed mixture. For example, ethylene glycol has a greater affinity for aromatic hydrocarbons and extracts them preferentially from a reformate mixture (a liquid paraffinic and aromatic product from catalytic reforming). The raffinate, which is mainly paraffins, is freed from traces of ethylene glycol by distillation. Other solvents that could be used for this purpose are liquid sulfur dioxide and sulfolane (tetramethylene sulfone). [Pg.53]

Considerable attention has been directed in determining the products from reactions of aliphatic hydrocarbons, aromatic compounds, and unsaturated compounds including biogenic terpenes that exhibit appreciable volatility. These studies have been conducted both in simulation chambers and using natural sunlight in the presence of NO. [Pg.17]

Before the 1960s, products were introduced based on alkyl aryl phosphates that could contain chlorinated aromatic hydrocarbons. Such products have now entirely disappeared from commercial use, and the vast majority of the industrial organophosphate esters are based on triaryl phosphates with no halogenated components (Marino 1992). However, at older waste disposal sites, hydraulic fluid site contaminants could contain chlorinated hydrocarbons. As with the PCBs formerly included as additives in other forms... [Pg.258]

Chapter 7 gives a review of the technology and applications of zeolites in liquid adsorptive separation of petrochemical aromatic hydrocarbons. The application of zeolites to petrochemical aromatic production may be the area where zeolites have had their largest positive economic impact, accounting for the production of tens of millions of tonnes of high-value aromatic petrochemicals annually. The nonaromatic hydrocarbon liquid phase adsorption review in Chapter 8 contains both general process concepts as well as sufficient individual process details for one to understand both commercially practiced and academic non-aromatic separations. [Pg.626]

Oyler, A.R., Llukkonen, R.J., Lukasewycz, M.T., Heikkila, K.E., Cox, D.A., and Carlson, R.M. Chlorine disinfection chemistry of aromatic compounds. Polynuclear aromatic hydrocarbons rates, products, and mechanisms. Environ. Sci. Technol, 17(6) 334-342, 1983. [Pg.1706]

As observed, aromatic hydrocarbons gave products of protonation on dissolution in hydrofluoric acid. Oxidation into aromatic cation-radicals did not take place (Kon and Blois 1958). Trifluoro-acetic acid is able to transform aromatics into cation-radicals. This acid is considered a middle-powered one-electron oxidant (Eberson and Radnor 1991). Its oxidative ability can be enhanced in the presence of lead tetraacetate. This mixture, however, should be used carefully to avoid oxidation deeper than the one-electron removal. Thus, oxidation of 1,2-phenylenediamine by the system Pb(OCOCH3)4 -I- CE3COOH -P CH2CI2 leads to the formation of either primary or secondary cation-radicals. The primary product is the cation radical of initial phenylenediamine, whereas the secondary product is the cation radical of dihydrophenazine (Omelka et al. 2001). Sulfuric acid is also used as an one-electron oxidant, especially for aromatic hydrocarbons. In this case, generation of cation radicals proceeds simultaneously with the hydrocarbon protonation and sulfonation (Weissmann et al. 1957). [Pg.90]

Fig. 3. Scheme for the alteration of sterols to saturated and aromatic hydrocarbons (natural product example is boxed.)... [Pg.84]

Depending on the reaction conditions, alkenes may undergo either of two types of catalytic polymerization. The products of the first type, which may be termed true polymerization, consist of alkenes having molecular weights which are integral multiples of the monomer alkene. The second type, conjunct polymerization, yields a complex mixture of alkanes, alkenes, alkadienes, cycloalkanes, cycloalkenes, cycloalkadienes, and, in some cases, aromatic hydrocarbons the products do not necessarily have a number of carbon atoms corresponding to an integral multiple of the monomer. [Pg.22]

The specific gravity of a fuel or oil is a function of the weight per standard volume of the product. Since aromatic compounds have a greater weight per unit volume than do paraffinic hydrocarbons, the specific gravity of a highly aromatic product would be greater than a paraffinic fuel or oil. [Pg.123]

From the practical point of view, this is probably the most important reaction related to the metallic component of the reforming catalysts (despite the fact that a part of aromatization is acid catalyzed). There are certainly several pathways which can, at least in principle, lead to the aromatic products. Let us mention here the most relevant facts on aromatization of hexanes and higher hydrocarbons. [Pg.176]

Some Inorganic Substances, Chlorinated Hydrocarbons, Aromatic Amines, N-Nitroso Compounds, and Natural Products... [Pg.565]

The historical development of aromatics production from petroleum is outlined, and the methods employed during World War II for the production of nitration grade toluene are described. Included is a discussion of methods of synthesizing and purifying benzene, xylenes, and aromatics of higher molecular weight both as mixtures and as pure compounds. Data are presented on the composition of the aromatic hydrocarbons available from typical hydroformates. Aromatics and mixtures thereof currently available from petroleum are listed. Some of the problems facing the industry in the field of aromatics production are discussed and the probable trend of future research is indicated. [Pg.301]

Naphtenic hydrocarbons yield products similar to paraffins upon oxidation. Aromatic hydrocarbons are che most readily oxidized constituents of lubricating oils. The end products are very complex condensation and polymerization products and tend to be Insoluble in oil. These products constitute the sludges, resins and varnishes which allegedly cause piston ring sticking in the engine. [Pg.324]

Much of the aromatic product obtained by catalytic re-forming is blended with other fractions from petroleum refining to give high-octane gasoline. The rest is separated into its component hydrocarbons, which then are utilized by the chemical industry for the production of chemicals derived from benzene, methylbenzene, and the dimethylbenzenes, as summarized in Figures 22-9 and 22-10,... [Pg.1083]

C5- and C6- cyclizations are parallel reactions. Csicsery has shown that isomerization of tetralin to methylindan over platinum-alumina at 371°C is extremely slow (22). Davis and Venuto provided further evidence by showing that methylindan is also not converted to tetralin or naphthalene over platinum on silica-alumina (23). This behavior is similar to that observed in the cyclization of aliphatic hydrocarbons. Davis and Venuto also reported that the major aromatic products obtained from ten C8-C9 paraffins and olefins at 482°C are only formed by direct six-membered ring... [Pg.304]

A short review in Chinese covers Friedel-Crafts reactions of alkenyl halides with aromatic hydrocarbons.49 High yields of the allylated aromatic products have been... [Pg.264]

Aromatic hydrocarbons gave products of protonation on dissolving in hydrofluoric acid. Oxidation in aromatic cation radicals did not take place (Kon Blois 1958). Triflu-oroacetic acid is an effective one-electron oxidant (Eberson Radner 1991). Meanwhile, sulfuric acid caused not only dissolution and protonation, but also one-electron oxidation of aromatic hydrocarbons. Sulfonation, naturally, proceeded too (Weissmann et al. 1957). [Pg.94]

Nature of the Diluents. Diluents can inhibit or sensitize TBP radiolysis. The effect of various diluents (aliphatic hydrocarbons, aromatic and halo-carbons) on TBP degradation products was examined over a wide range of nitric acid concentrations (26). [Pg.445]


See other pages where Hydrocarbons Aromatic products is mentioned: [Pg.171]    [Pg.364]    [Pg.307]    [Pg.490]    [Pg.212]    [Pg.292]    [Pg.63]    [Pg.20]    [Pg.117]    [Pg.114]    [Pg.138]    [Pg.27]    [Pg.276]    [Pg.266]    [Pg.310]    [Pg.41]    [Pg.42]    [Pg.51]    [Pg.307]    [Pg.213]    [Pg.144]    [Pg.163]    [Pg.358]    [Pg.37]   


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