Ethylene-vinyl ketone copolymers

Ethylene-carbon monoxide copolymers E-CO, Ethylene-vinyl ketone copolymers Ecolyte (J.E.Guillet) [3,15,16]... 

Magnetic tapes are usually coated with coatings from solvents, such as methyl ethyl ketone, methyl isobutyl ketone, and toluene. Aqueous replacements can eliminate all or nearly all of the solvents.352 One system used iron oxide in a blend of a polyurethane and ethylene-vinyl chloride copolymer emulsions thickened with hydroxyethyl cellulose, which was cross-linked with a melamine-formaldehyde resin. Coating was done at line speeds of 100 m/min. The whole system proved to be 15% cheaper than coating from solvent. In another system, traces of methanol are evolved on drying and would have to be captured. This replaces a line where 600 kg/h of solvent would have to be recovered and recycled. 

Binder resins for the injection molding method are poly(amide)s and ethylene vinyl acetate copolymers, and more recently poly(ether ether ketone) (PEEK) and PPS, because of their superior properties. Crystalline resins such as PPS or PEEK require a high temperature for fusion molding of 350°C or higher, so that there is a disadvantage in that the magnetic powder of the rare earth is likely to be oxidized by the molding process. 

EVK. See Ethyl vinyl ketone EVM. See Ethylene/VA copolymer EVOH EVOH copolymer. See Ethylene/vinyl alcohol copolymer Evoprene G 940. See Styrene-ethylene/butylene-styrene block copolymer EW-POL 7902 NaC 12. See Sodium laurate EW-POL 9110. See Ammonium oleate EX 1035, EX 1044, EX 1057. See Polyethylene, low-density... 

Binder resins for the injection molding method are poly(amide)s and ethylene vinyl acetate copolymers, and more recently poly(ether ether ketone) (PEEK) and PPS, because of their superior properties. Crys-... 

Poly (methyl vinyl ketone), poly (isopropyl vinyl ketone), ethylene-carbon monoxide copolymers Poly(vinyl acetate), poly (methyl acrylate), poly (ethyl acrylate), poly (methyl methacrylate), poly (butyl acrylate), ethylene-vinyl acetate copolymers Poly (acrylic acid),... 

The foUowing activity coefficients and interaction parameters determined by GLC for solute-statistical copolymers may be found in the literature (a) forty three non-polar and polar solutes on ethylene-vinyl acetate copolymer with 29% weight of vinyl acetate at 150.6 and 160.5°C [105] chloroform, carbon tetrachloride, butyl alcohol, butyl chloride, cyclohexanol, cyclohexane, phenol, chlorobenzene and pentanone-2 on the same copolymer with 18% weight vinyl acetate at 135°0 [102], normal xdkanes (C5, Oj, Og, Ojo), oct-l-ene, chlorinated derivatives, n-butanol, toluene, benzene, methyl-propyl-ketone and n-butyl-cyclohexane on the copolymer mentioned with 40% weight vinyl acetate at 65, 75 and 85°0 [68, 106] (b) n-nonane, benzene, chloroform, methyl-ethyl-ketone and ethanol in methyl methacrylate-butyl methacrylate copolymer with 10% butyl methacrylate [32] (c) hydrocarbons in styrene-alkyl methacrylates copolymers at 140°C [101] (d) the solutes in (b) on butadiene-acrylonitrile copolymer with 34% weight acrylonitrile [68]. 

The heat distortion temperature at 1.80 Mpa is the temperature that causes a beam loaded to 1.80 to deflect by 0.3 mm. If the heat distortion temperature is lower than the ambient temperature, -20 C is given. Polymers such as low-density polyethylene, styrene ethylene-butene terpolymer, ethylene-vinyl acetate copolymer, polyurethane, and plasticized polyvinyl chloride distort at temperatures below <50°C, whereas others, such as epoxies, polyether ether ketone, polydiallylphthalate, polydiallyl isophthalate, polycarbonate, alkyd resins, phenol formaldehyde, polymide 6,10 polyimide, poly-etherimides, polyphenylene sulfide, polyethersulfone, polysulfonates, and silicones, have remaikably high distortion temperatures in the range of 150°C to >300 C. Thermomechanical analysis has been used to determine the deflection temperature of polymers and sample loading forces (i.e., plots of temperature vs. flexure). 

For ethylene-carbon monoxide copolymers, the formation of the free radical type I prcxlucts is suppressed to only about 10% of the total reactkms because both radicals are polymeric and hardly ever escape from the iimnediate environment On the other hand, for ethylene-methyl vinyl ketone copolymers, photolysis yields one polymeric and one small acetyl radical, with the effknency of type I reaction eight times as... 

The disc-shaped plastic micoreactors, termed microcapillary films (MCFs), contain 19 parallel microchannels, each with a mean internal diameter of 142 10 pm. The material was prepared using a melt extrusion process from an ethylene-vinyl alcohol copolymer (EVOH) [28]. Immobilization of palladium(0) on the wall surface inside the MCFs was performed by simple chemical deposition techniques (Scheme 7.3). The palladium-coated capillaries were used for transfer hydrt enation of ketones, imines, nitro compounds, alkenes, and alkynes with triethylsilane under flow conditions [29]. Microcapillaries whose inside surfaces were coated with copper or gold were also utilized for the continuous-flow reactions [30]. 

Other patents include copolymers of vinyl ketones with acrylates, methacrylates, and styrene (53) an ethylene—carbon monoxide (1—7 wt %) blend... 

A similar variation in the quantum yield of the Norrish type I process is illustrated in Figure 3 for solid copolymers of ethylene containing three different ketone structures. The ketone groups in the backbone of the polymer chain in ethylene- copolymers show much lower quantum yields than those from the secondary or tertiary structures induced by copolymerization of methyl vinyl ketone and methyl isopropenyl ketone with ethylene. (See Table I, structures I, II and III.) In the latter two cases, the Norrish type I cleavage produces a small radical and a polymer radical, and it seems likely that the small radical has a much greater probability of escaping the cage than when the radicals produced are both polymeric, as in the case of structure I. 

Preferred olefins in the polymerisation are one or more of ethylene, propylene, 1-butene, 2-butene, 1-hexene, 1-octene, 1-pentene, 1-tetradecene, norbornene and cyclopentene, with ethylene, propylene and cyclopentene. Other monomers that may be used with these catalysts (when it is a Pd(II) complex) to form copolymers with olefins and selected cycloolefins are carbon monoxide (CO) and vinyl ketones of the general formula H2C=CHC(0)R. Carbon monoxide forms alternating copolymers with the various olefins and cycloolefins. 

Poly(vinyl ketones) such as poly(ethylene-a//-carbon monoxide) CAS 111190-67-1, poly(methyl vinyl ketone) CAS 25038-87-3, and poly(methyl isopropenyl ketone) CAS 25988-32-3, also have practical applications. For example, poly(ethylene-a/f-carbon monoxide) is used in photodegradable plastics and in various copolymers. Several studies were reported regarding the thermal stability of these polymers. It has been shown that poly(ethylene-a/f-carbon monoxide) decomposes upon heating with chain scission generating small molecular weight alkenes and ketones. Some literature reports discussing the thermal decomposition of poly(vinyl ketones) are summarized in Table 6.5.5 [13]. 

Polyarylate resin Polyarylether ketone resin Polyester carbonate resin Polyetherimide resin Polyethylene, chlorinated Polyethylene glycol Polyethylene, medium density Poly (p-methylstyrene) Poly (p-methylstyrene), rubber-modified Poly (oxy-1,2-ethanediyloxycarbonyl-2,6-naphthalenediylcarbonyl) resin Poly (oxy-p-phenylenesulfonyl-p-phenyleneoxy-p-phenyleneisopropylidene-p-phenylene) resin Poly (phenyleneterephthalamide) resin Polysulfone resin Poly (tetramethylene terephthalate) Polyvinylidene chloride Potassium sorbate Potato (Solanum tuberosum) starch Silica, colloidal Silicone Sodium N-alkylbenzenesulfonate Sodium bicarbonate Sodium tetraborate pentahydrate Starch, pregelatinized Styrene/acrylates copolymer Styrene/butadiene polymer Styrene/DVB copolymer , 1,1 -Sulfonylbis (4-chlorobenzene) polymer with 4,4 -(1-methylethylidene) bis (phenol) and 4,4 -sulfonylbis (phenol) Synthetic wax Tapioca starch Tetrafluoroethylene/perfluoro (propyl vinyl ether) copolymer Tocopherol Triglycidyl isocyanurate VA/crotonates copolymer Vinyl chloride/ethylene copolymer Wheat (Triticum vulgare) starch... 

Other recent patents include copolymers of tdnyl ketones with acrylates, methacrylates, and styrene (O Brien, 1993) an ethylene/carbon monoxide (1-7 wt%) blend as a photo initiator in polycaprolactone/polyethylene blends (Hirsoe, 1992) ethylene/ carbon monoxide for degradable golf tees (Akimoto) a vinyl ketone analog of Exxon s carbon monoxide/dioxapane/ethylene (Priddy, 1992) a photodegradable food wrapper based on blends of a polyolefin/starch and photo activators for the... 

Photodegradation of poly(acrylic acid [449, 1952] occurs by mechanisms similar to those described for poly(methacrylic acid) (cf section 3.4.2). There are several papers devoted to the photodegradation of polycarboxylic acid esters such as poly(vinyl acetate) [335-337, 519, 749, 750, 1482, 2147, 2173] (cf section 3.4.4), poly(vinyl propionate [335-337], poly(vinyl butyrate) [1480], and copolymers such as poly(acrylic acid-co-phenyl isopropenyl ketone) [1465], poly(vinyl acetate-co-ethylene [335-337,2003], poly(vinyl acetate-coethylene) blends with poly(vinyl chloride [2005] and poly(vinyl acetate-cophenyl vinyl ketone [1208, 1209]. 

Abbreviations for plastics ABS, acrylonitrile-butadiene-styrene CPVC, chlorinated poly vinyl chloride ECTFE, ethylene-chlorotrifluoroethylene ETFE, ethylene-tetrafluoroethylene PB, polybutylene PE, polyethylene PEEK, poly ether ether ketone PFA, perfluoroalkoxy copolymer POP, poly phenylene oxide PP, polypropylene PVC, polyvinyl chloride PVDC, poly vinylidene chloride PVDF, poly vinylidene fluoride. 

ETHYL BENZENE ETHYL BROMIDE ETHYL CHLORIDE ETHYL ETHER ETHYLENE CHLOROHYDRIN ETHYLENE DIAMINE ETHYLENE DIBROMIDE ETHYLENE DICHLORIDE ETHYLENE GLYCOL ETHYLENEIMINE ETHYLENE OXIDE DIETHYL KETONE DIETHYLENE GLYCOL GLYCOL ETHERS, ESTERS MEA, DEA. TEA VINYL ACETATE POLYMERS. COPOLYMERS... 

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