Concrete Surface

Moving the transducer along the concrete surface one is able to directly compare the data from different positions simultaneously reeieving information on intensity and phases of the signal and their relative changes. A Pentium-PC, included in tlie testing-system,... 

Radiographic image of 800 mm thick reinforced concrete wall with vertical and horizontal bars clearly visible, in this case some 150 mm from the concrete surface (film side). 

Rendering plants Feedstock storage and housekeeping Cookers and percolators Grinding Odors SO2, mercaptans, ammonia, odors Particulates (dust) Quick processing, washdown of all concrete surfaces, paving of dirt roads, proper sewer maintenance, enclosure, packed towers Exhaust system, condenser, scrubber, or incinerator Exhaust system and scrubber... 

Structures or pits for water lines are mostly of steel-reinforced concrete. At the wall entrance, contact can easily arise between the pipeline and the reinforcement. In the immediate vicinity of the pit, insufficient lowering of the potential occurs despite the cathodic protection of the pipeline. Figure 12-7 shows that voltage cones caused by equalizing currents are present up to a few meters from the shaft. With protection current densities of 5 mA mr for the concrete surfaces, even for a small pit of 150 m surface area, 0.75 A is necessary. A larger distribution pit of 500 m requires 2.5 A. Such large protection currents can only be obtained with additional impressed current anodes which are installed in the immediate vicinity of the pipe entry into the concrete. The local cathodic protection is a necessary completion of the conventional protection of the pipeline, which would otherwise be lacking in the pit. 

Steel constructions and pipelines must either be electrically connected to the reinforcement of reinforced concrete structures or electrically separated. If they are connected, a current density of about 5 mA m should be applied to the external reinforcement and calculated on the total area of the concrete surface. 

Very often steel sheet pilings exist in conjunction with steel-reinforced concrete structures in harbors or locks. If cathodic protection is not necessary for the reinforced concrete structure, there is no hindrance to the ingress of the protection current due to the connection with the steel surfaces to be protected. The concrete surface has to be partly considered at the design stage. An example is the base of the ferry harbor at Puttgarden, which consists of reinforced concrete and is electrically connected to the uncoated steel sheet piling. 

Two-dimensional potential measurements on the concrete surface serve to determine the corrosion state of the reinforcing steel. This method has been proved for one-dimensional systems (pipelines), according to the explanation for Fig. 3-24 in Section 3.6.2.1 on the detection of anodic areas. 

In the first reconstruction [27] of road slabs contaminated with CL, silicon iron anodes were embedded in a layer of coke breeze as shown in Fig. 19-4a or the current connection was achieved with noble metal wires in a conducting mineral bedding material. Slots were ground into the concrete surface for this purpose at spacings of about 0.3 m (see Fig. 19-4b). This system is not suitable for vertical structures. 

Membranes are applied directly to the metal or concrete surface to protect from corrosion by any liquor that penetrates the brick lining through pores and cracks. Membranes consist of sheet material bonded to the metal or concrete, e.g., flexible PVC sheet, or it may be formed in situ (e.g., polyester resin reinforced with glass fiber, or synthetic rubber sheet, lead, polyisobutylene, polyethylene and asphalt). 

Sodium silicate and silico fluoride solutions as concrete surface hardeners 9/104... 

Both sodium silicate and silico fluoride solutions are applied to clean, dry, sound concrete floors as dilute aqueous solutions (10-15 per cent solids) in two to three applications, taking care to ensure that all material penetrates and is absorbed into the concrete surface. The silicate or silico fluoride reacts with the small amount of free lime in the cement to form glassy inert materials in the surface, and the successful application of both materials depends upon filling the micropores in the surface of good-quality concrete, leaving its surface appearance and non-skid characteristics virtually unchanged. 

It is important to stress that neither sodium silicate nor silico fluoride will improve the performance of a poor, low-strength, dusty concrete floor and if the surface is too porous, there is no way that all the material applied can react with the relatively small quantity of free lime in the concrete surface. All that will happen is that the pores will be filled with non-reacted powder, producing a most unpleasant alkaline dust, which can be very irritating to the skin and eyes when the floor is put into service. 

Resin solution penetrating sealers are now available which, for very large warehouse floors, are comparable in applied costs with the concrete surface hardeners and are now being increasingly specified. Experience indicates that certain acrylic resin solutions are proving more durable and offer better protection to chemical and oil spillage than concrete surface hardeners. Acrylic resin solution sealers can markedly improve the abrasion resistance of concrete floors and have rescued a number of poor-quality floors. 

Concrete surface hardeners, two to three coats In-surface seals 1-1.8... 

Berger, D. M., Preparing concrete surfaces. Concrete Construction, 481-494, September (1978). 

These materials are now widely used for coating both steel and concrete surfaces that are subject to a particularly aggressive environment (e.g. North Sea oil platforms). There is less validity for their use under normal atmospheric conditions since they are relatively expensive and tend to chalk on exposure to sunlight. However, their use as zinc phosphate, pretreatment or blast primers for blast-cleaned steel which is subsequently overcoated by any other paint system is an extremely valuable contribution to the painting of new steel work. 

Chlorinated rubber See Section 12.3.2. This is used for decoration but also provides a relatively impermeable coating. Its best use is for concrete surfaces that have to be kept clean by regular washing. 

Two-pack epoxy Section 12.3.3. These are widely used to give the maximum protection to concrete surfaces, floors and walls. They can be applied as relatively thin coatings by spray or as thick epoxy surfaces applied by trowel. In all cases, the application must be preceded by adequate surface preparation (see Section 12.6.1). To allow maximum penetration into the concrete the first coat must have a low viscosity. Coal tar epoxies are used where protection is the main requirement. 

A number of anode connections will be made to the d.c. power source using proprietary splice kits (approximately one for every 60-80 m of concrete to be protected). This will provide redundancy for anode failure and reduce ohmic losses along the anode cable. Care must also be taken not to expose the copper conductor during installation or anode failure could take place. Once fitted to the concrete surface a 15 mm thick cementitious overlay is applied above the anode mesh, as recommended by the anode manufacturer, although thickness of up to 35-40 mm have been applied in some instances. 

These consist of a number of parallel slots cut into the concrete surface. Each slot is then filled with a secondary anode of carbon/graphite fibres embedded in a conductive polymer grout. The current to each of these secondary anode systems is provided by a primary anode of platinised niobium wire placed in slots filled with conductive polymer which acts as the primary anode, these slots intersecting each slot of graphite fibre/conductive polymer at right angles. 

Brown and Fessler have conducted a laboratory evaluation of conductive mastics that can be brushed or sprayed onto the concrete surface to achieve the necessary thickness. However, the most extensive study on conductive paints for cathodic protection purposes has been undertaken by the Federal Highway AuthorityA total of nine commercially available resins were evaluated in this work. It was shown that neither thermal cycling, freeze thawing nor the application of cathodic protection currents... 

In recent years, there has been interest in using zinc as a power-impressed anode for the cathodic protection of steel in concrete. The zinc is flame sprayed onto a grit blasted concrete surface to a final film thickness of approximately 250 m. A primary anode is necessary. Early systems used brass plates as the primary anode, but more recent systems used platinised titanium or niobium wire anodes as the primary current conductor. 

All metal surfaces such as mild steel should be grit blasted, normally to SA 2-5 as defined in Swedish Standard SIS 055900. If the surfaces are contaminated with oil, grease or a chemical from previously used items, the contamination is usually removed by sweating in steam prior to grit blasting. Concrete surfaces must be clean and dry and any laitence must be removed as it will affect the bond of the lining. Preferably the surface should be grit blasted. 

The interior surface finish, to comply with EEC and other health standards, must be rustproof, cleanable, and free from any crevices which can hold dirt. Bare timber in any form is not permitted. Most liners are now aluminium or galvanized steel sheet, finished white with a synthetic enamel or plastic coating. GRP liners are also in use. Floors are of hard concrete or tiles. Very heavy working floors may have metal grids let into the concrete surface. Floor concrete is coved up at the base of the walls to form a protective curb. 

Davis and McLean (Ref 2) studied the expl reaction between metallic K. or Na and chlf more closely. They stated that if a test tube contg some chlf, and an ampule with K or Na, were dropped onto a concrete surface from a height of about 6 ft, a loud report is produced accompanied by a bright flash Refs 1) H. Staudinger, ZElectrochem 31,... 

Davis JE, Staiff DC, Butler LC, et al. 1977. Persistence of methyl and ethyl parathion following spillage on concrete surfaces. Bull Environ Contam Toxicol 18 18-25. 

A simplification of the polarization resistance technique is the linear polarization technique in which it is assumed that the relationship between E and i is linear in a narrow range around E . Usually only two points ( , 0 are measured and B is assumed to have a constant value of about 20 mV. This approach is used in field tests and forms the basis of commercial corrosion rate monitors. Rp can also be determined as the dc limit of the electrochemical impedance. Mansfeld et al. used the linear polarization technique to determine Rp for mild steel sensors embedded in concrete exposed to a sewer environment for about 9 months. One sensor was periodically flushed with sewage in an attempt to remove the sulfuric acid produced by sulfur-oxidizing bacteria within a biofilm another sensor was used as a control. A data logging system collected Rp at 10-min intervals simultaneously for the two corrosion sensors and two pH electrodes placed at the concrete surface. Figure 2 shows the cumulative corrosion loss (Z INT) obtained by integration of the MRp time curves as ... 

As a final application of the profiling technique, the sensor for large depth measurements described in Section 2.4.2.5 was used to resolve multi-layer polymer coatings on concrete samples. Such coatings are used to protect concrete from degradation and corrosion. They are applied to the concrete surface to reduce the porosity in the upper first millimeters to prevent the penetration of water and... 

Fig. 2.4.14 Profile of a multi-layer polymer coating used to protect concrete surfaces from environmental corrosion. The profile is the signal amplitude resulting from the addition of the first 32 echoes acquired with a CPMG sequence with tE = 50 ps. It has an FOV of 8 mm and was measured with a spatial resolution of 100 pm. Using 256 scans per point and a repetition time of 100 ms, the total acquisition time per point was 25 s.

The surface of concrete may be subjected to cycles of wetting and drying during normal service life. This process is a durability concern as harmful ions such as chlorides or sulfates can easily penetrate with the adsorbed water and there is the potential for saturation prior to freezing. Measuring the rate of water penetration into a dry concrete surface is thus important to the quality control of concrete mixes - hopefully yielding a durable product. 

Air content of freshly mixed concrete by the pressure method Air content of freshly mixed concrete by the volumetric method Unit weight, yield, and air content of concrete Specific gravity, absorption, and voids in hardened concrete Resistance of concrete to rapid freezing and thawing Scaling resistance of concrete surfaces exposed to deicing chemicals... 

ASTM, Standard Specification C672 Scaling Resistance of Concrete Surfaces Exposed to Deicing Chemicals, in Annual Book of ASTM Standards, Vol. 04.02, American Society for Testing and Materials, West Conshohocken, PA, 1993. 

As long as sulfide remains in the water phase, no harmful effect will occur. The concrete corrosion problem is caused by hydrogen sulfide that from the gas phase is absorbed in the liquid film that exists on moist concrete surfaces in the... 

Insulation of the floor of broiler houses prevents moisture condensing on the concrete surface and thus has an effect on the dry matter content of the litter. This effect can be expected wherever the ground water level is about one metre below the surface. The theoretical principles are given Other benefits of the insulation are a reduction in ammonia and odour emission, as well as an improvement in the quality of the broilers as measured by the presence of blistered briskets and wrong legs. The economic implications, however, remain unclear. 

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