Cycling, thermal

Fig. 5. (a) Temperature isotherms in the region of a moving welding arc. (b) Heat-affected-zone thermal cycles at various locations in the base plate (see... 

The enhanced strength and corrosion properties of duplex stainless steels depend on maintaining equal amounts of the austenite and ferrite phases. The welding thermal cycle can dismpt this balance therefore, proper weld-parameter and filler metal selection is essential. Precipitation-hardened stainless steels derive their additional strength from alloy precipitates in an austenitic or martensitic stainless steel matrix. To obtain weld properties neat those of the base metal, these steels are heat treated after welding. 

It has been reported that Parylene N is deposited in a state of compressive stress (37). The inherent stress is 18 MPa (2300 psi) and is invariant with thickness. This congenital compressive stress can be removed and rendered tensile by a thermal cycle. 

A recently developed drying appHcation for zeoHtes is the prevention of corrosion in mufflers (52,55). Internal corrosion in mufflers is caused primarily by the condensation of water and acid as the system cools. A unique UOP zeoHte adsorption system takes advantage of the natural thermal cycling of an automotive exhaust system to desorb the water and acid precursors. 

In all appHcations involving zirconia, the thermal instabiHty of the tetragonal phase presents limitations especially for prolonged use at temperatures greater than - 1000° C or uses involving thermal cycling. Additionally, the sensitivity of Y—TZP ceramics to aqueous environments at low temperatures has to be taken into account. High raw material costs have precluded some appHcations particularly in the automotive industry. 

Mobiltherm 603. Mobiltberm 603, manufactured by Mobil Oil Corp., is a high paraffinic oil suitable for systems in which combined beating and cooling cycles are used. It functions efficiently at both low and high temperatures and withstands repeated thermal cycling. 

Cases can be classified as either hermetic or nonhermetic, based on their permeabiUty to moisture. Ceramics and metals are usually used for hermetic cases, whereas plastic materials are used for nonhermetic appHcations. Cases should have good electrical insulation properties. The coefficient of thermal expansion of a particular case should closely match those of the substrate, die, and sealing materials to avoid excessive residual stresses and fatigue damage under thermal cycling loads. Moreover, since cases must provide a path for heat dissipation, high thermal conductivity is also desirable. 

Aluminide and sUicide cementation coatings such as TaAl on tantalum and MoSi2 on molybdenum oxidize at slow rates and possess some inherent self-repair characteristics. Fine cracks that appear and are common to these coatings can be tolerated because stable, protective oxides form within the cracks and seal them. Thermal cycling, however, accelerates faUure because of thermal expansion mismatch that ultimately dismpts the protective oxide coating. 

Central receiver systems not only require components that can withstand severe and frequent thermal cycling, but in addition they entail long warmup times and exhibit slow transient responses. As a result, energy production from the best systems have been about half of that expected. As development complexities became apparent, government support was curtailed and industrial commitment waned. 

Antimony may be added to copper-base alloys such as naval brass. Admiralty Metal, and leaded Muntz metal in amounts of 0.02—0.10% to prevent dezincification. Additions of antimony to ductile iron in an amount of 50 ppm, preferably with some cerium, can make the graphite fliUy nodular to the center of thick castings and when added to gray cast iron in the amount of 0.05%, antimony acts as a powerflil carbide stabilizer with an improvement in both the wear resistance and thermal cycling properties (26) (see Carbides). 

Specifications and Test Methods. The American Society of Electroplated Plastics pubHshes a comprehensive book covering most technical aspects of testing and control (24). A number of ASTM standards have been issued that cover thickness, adhesion, and thermal-cycling resistance of the total plated film. Some specifically for plated plastics include ... 

Values of thermal-expansion coefficients to be used in determining total displacement strains for computing the stress range are determined from Table 10-52 as the algebraic difference between the value at design maximum temperature and that at the design minimum temperature for the thermal cycle under analysis. 

In thermoplastics and some thermosetting resins, displacement strains are not likely to produce immediate failure of the piping but may result in detrimental distortion. Especially in thermoplastics, progressive deformation may occur upon repeated thermal cycling or on prolonged exposure to elevated temperature. 

Many metal sulfides produce poorly adherent corrosion product layers. This leads to rapid spalling during thermal cycling or turbulent flow. In particular, nonadherent and easily spalled sulfides form on steel and cast irons. 

Cyclic nature of Implement mechanical integrity program batch process (e.g.,, Design equipment for easy replacement start/stop, thermal cycling). Possibil- Consider demand of cycling while designing ity of mechanical equipment and controls wear and tear. Possible loss of containment. ... 

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