Carbon steels, 288 table

AX] = shell thickness, ft Ki = shell thermal conductivity Btu/hr-ft-°F s 30 for carbon steel (Table 2-3)... 

Machinability of Carbon Steel, Table 1 Mechanical properties of metallographic constituents, according to... 

Alloying additions of less than 5% have little effect on seawater corrosion. The susceptibility to pitting is least for 3% Cr-steel than plain carbon steel. Table 9.19 shows the corrosion rates of several low alloy steels containing small quantities of alloying elements (Cu, Ni, Cr) in various combinations. 

Effect of Alcohols and Related Compounds on PAA Solutions Containing Carbon Steel. Five types of alcohols and one type of ether were evaluated for their ability to stabilize PAA solutions containing carbon steel (Table 16). The results showed that all of the additives reduced polymer degradation in solutions containing a carbon steel coupon, while control solutions with no metal were not always aided by the additives. The relative effectiveness of the alcohols tested followed the general trend of primary > secondary > tertiary. A good correlation was not observed between alcohol effectiveness and water solubility. 

Shipment. The DOT/IMO shipping information is shown in Table 6. Approved materials of constmction for shipping, storage, and associated transportation equipment are lined carbon steel (DOT spec. 105 S 500W) and type 316 stainless steel. Water spray, carbon dioxide, chemical-foam, or dry-chemical fire extinguishers may be used. 

Fluorine can be handled using a variety of materials (100—103). Table 4 shows the corrosion rates of some of these as a function of temperature. System cleanliness and passivation ate critical to success. Materials such as nickel, Monel, aluminum, magnesium, copper, brass, stainless steel, and carbon steel ate commonly used. Mote information is available in the Hterature (20,104). 

In aqueous solution, malic acid can be mildly corrosive toward aluminum and corrosive to carbon steel. Under normal conditions, it is not corrosive to stainless steels, which usually are the constmetion materials for processes involving malic acid. Malic acid is also virtually noncorrosive to tinplate and other materials used to package acidulated foods and beverages (Table 3) (27). 

In common with other hydroxy organic acids, tartaric acid complexes many metal ions. Formation constants for tartaric acid chelates with various metal ions are as follows Ca, 2.9 Cu, 3.2 Mg, 1.4 and Zn, 2.7 (68). In aqueous solution, tartaric acid can be mildly corrosive toward carbon steels, but under normal conditions it is noncorrosive to stainless steels (Table 9) (27). 

Soft magnetic materials are characterized by high permeabiUty and low coercivity. There are sis principal groups of commercially important soft magnetic materials iron and low carbon steels, iron—siUcon alloys, iron—aluminum and iron—aluminum—silicon alloys, nickel—iron alloys, iron-cobalt alloys, and ferrites. In addition, iron-boron-based amorphous soft magnetic alloys are commercially available. Some have properties similar to the best grades of the permalloys whereas others exhibit core losses substantially below those of the oriented siUcon steels. Table 1 summarizes the properties of some of these materials. 

Larger volume cycloaUphatic amines and diamines, their worldwide major manufacturers and approximate January 1990 prices are shown in Table 4. Shipment of these Hquid products is by nitrogen-blanketed tank tmck or tank car. Dmm shipments are usually in carbon steel, DOT-17E. 

The original hot carbonate process developed by the U.S. Bureau of Mines was found to be corrosive to carbon steel (55). Various additives have been used in order to improve the mass transfer rate as well as to inhibit corrosion. Vetrocoke, Carsol, Catacarb, Benfteld, and Lurgi processes are all activated carbonate processes. Improvements in additives and optimization of operation have made activated carbonate processes competitive with activated MDEA and nonaqueous solvent based systems. Typical energy requirements are given in Table 9. 

Chloroformates are shipped in nonretumable 208-L (55-gal) polyethylene dmms with carbon steel overpacks or high density polyethylene dmms. Eor bulk shipments, insulated stainless-steel tank containers and tmcks provide secure protection. Tank tmck and rail car quantities are shipped using equipment dedicated for these types of products. Materials such as isopropyl chloroformate, benzyl chloroformate, and j -butyl chloroformate that require refrigeration are precooled when shipped in bulk containers. Bulk shipments that are precooled must proceed to the destination without layover. Dmm shipments of IPCE, BCE, and SBCE must be shipped in refrigerated containers. Many of the chloroformates are only shipped in tmck load shipments. The U.S. Department of Transportation (DOT) Hazardous Materials Regulations control the shipments of chloroformates, as described in Table 3. 

The reaction vessel (nitrator) is constructed of cast iron, mild carbon steel, stainless steel, or glass-lined steel depending on the reaction environment. It is designed to maintain the required operating temperature with heat-removal capabiUty to cope with this strongly exothermic and potentially ha2ardous reaction. Secondary problems are the containment of nitric oxide fumes and disposal or reuse of the dilute spent acid. Examples of important intermediates resulting from nitration are summarized in Table 3. 

Table 1. Processing Cycle for Engineering Nickel on Low Carbon Steel ...

Table 9-50 gives typical values of the exponent n for many types of equipment. Prices are North American with a Marshall and Swift index of 1000, mainly for carbon steel equipment. 

Table 9-51 fflves typical values of such factors for carbon steel installations taken from the data of D. R. Woods Financial Decision Making in the Process Industiy, Prentice Hall, Englewood Cliffs, NJ, 1975, p. 184). Auxiliaries and site preparation are given as factors of the delivered-equipment cost in Table 9-51, whereas C. A. Miller [Chem. 

TABLE 9-58 Typical Factors for Converting Carbon Steel Cost to Equivalent-Alloy Costs... 

TABLE 10-39 Cement-Lined Carbon-steel Pipe ... 

Carbon steel and alloy combinations appear in Table 11-12 Alloys in chemical- and petrochemical-plant sei vice in approximate order of use are stainless-steel series 300, nickel. Monel, copper alloy, aluminum, Inconel, stainless-steel series 400, and other alloys. In petroleum-refinery sei vice the frequency order shifts, with copper alloy (for water-cooled units) in first place and low-alloy steel in second place. In some segments of the petroleum industiy copper alloy, stainless series 400, low-alloy steel, and aluminum are becoming the most commonly used alloys. 

The frame plates are typically epoxy-painted carbon-steel material and can be designed per most pressure vessel codes. Design limitations are in the Table 11-18. The channel plates are always an alloy material with 304SS as a minimum (see Table 11-18 for other materi s). 

Performance Data for Vacttum-Shelf Dryers The purchase price of a vacuum-shelf dryer depends upon the cabinet size and number of shelves per cabinet. For estimating purposes, typical prices (1985) and auxiliai y-emiipment requirements are given in Table 12-12. Installed cost of the equipment will be roughly 100 percent of the carbon steel purchase cost. 

Performance and Cost Data for Indirect-Heat Rotary Steam-Tube Dryers Table 12-22 contains data for a number of standard sizes of steam-tube diyers. Prices tabulated are for ordinaiy carbon steel construction. Installed costs will run from 150 to 300 percent of purchase cost. 

Based upon 1200 F air-inlet temperature. With an inlet temperature of 700 F the evaporative capacity would he half that given in the table. Prices are based upon carbon steel construction with cyclone collector (January, 1995). Motors and secondary dust collectors excluded... 

A typical microbiological analysis in a troubled carbon-steel service water system is given in Table 6.2. Table 6.3 shows a similar analysis for a cupronickel utility main condenser that showed no significant corrosion associated with sulfate reducers. When biological counts of sulfate reducers in solid materials scraped from corroded surfaces are more than about 10, significant attack is possible. Counts above 10 are common only in severely attacked systems. 

As you can see from the tables in Chapter 1, few metals are used in their pure state -they nearly always have other elements added to them which turn them into alloys and give them better mechanical properties. The alloying elements will always dissolve in the basic metal to form solid solutions, although the solubility can vary between <0.01% and 100% depending on the combinations of elements we choose. As examples, the iron in a carbon steel can only dissolve 0.007% carbon at room temperature the copper in brass can dissolve more than 30% zinc and the copper-nickel system - the basis of the monels and the cupronickels - has complete solid solubility. 

The most important displacive transformation is the one that happens in carbon steels. If you take a piece of 0.8% carbon steel "off the shelf" and measure its mechanical properties you will find, roughly, the values of hardness, tensile strength and ductility given in Table 8.1. But if you test a piece that has been heated to red heat and then quenched into cold water, you will find a dramatic increase in hardness (4 times or more), and a big decrease in ductility (it is practically zero) (Table 8.1). 

Carbon is the cheapest and most effective alloying element for hardening iron. We have already seen in Chapter 1 (Table 1.1) that carbon is added to iron in quantities ranging from 0.04 to 4 wt% to make low, medium and high carbon steels, and cast iron. The mechanical properties are strongly dependent on both the carbon content and on the type of heat treatment. Steels and cast iron can therefore be used in a very wide range of applications (see Table 1.1). 

Carbon steels as received "off the shelf" have been worked at high temperature (usually by rolling) and have then been cooled slowly to room temperature ("normalised"). The room-temperature microstructure should then be close to equilibrium and can be inferred from the Fe-C phase diagram (Fig. 11.1) which we have already come across in the Phase Diagrams course (p. 342). Table 11.1 lists the phases in the Fe-FejC system and Table 11.2 gives details of the composite eutectoid and eutectic structures that occur during slow cooling. 

In some service stations, stainless steel or aluminum materials are used for all the filters, pipes and fittings to maintain the purity of the fuel. The rest potentials of these materials are different from that of plain carbon steel (see Table 2-4). 

Table 4.9 Selected inorganic salts highly corrosive to carbon steel (Corrosion rate >50 mpy)...

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