Equivalent alloys

TABLE 9-58 Typical Factors for Converting Carbon Steel Cost to Equivalent-Alloy Costs... 

Fig. 7.24. The thermoelectric power of equivalence alloys as a function of composition Ag-Au o Mg-Cd a In-Tl Bi-Sb Pb-Sn. (The first named element is on the left of the diagram.) The predicted composition dependence of S ...

No systematic investigation of the Hall effect amongst alloys of type I has been carried out although there is evidence (Busch and Guntherodt, (1967)) that equivalent alloys are among those for which R = at all compositions. 

We now turn to a mean-field description of these models, which in the language of the binary alloy is the Bragg-Williams approximation and is equivalent to the Ciirie-Weiss approxunation for the Ising model. Botli these approximations are closely related to the van der Waals description of a one-component fluid, and lead to the same classical critical exponents a = 0, (3 = 1/2, 8 = 3 and y = 1. 

This class of smart materials is the mechanical equivalent of electrostrictive and magnetostrictive materials. Elastorestrictive materials exhibit high hysteresis between strain and stress (14,15). This hysteresis can be caused by motion of ferroelastic domain walls. This behavior is more compHcated and complex near a martensitic phase transformation. At this transformation, both crystal stmctural changes iaduced by mechanical stress and by domain wall motion occur. Martensitic shape memory alloys have broad, diffuse phase transformations and coexisting high and low temperature phases. The domain wall movements disappear with fully transformation to the high temperature austentic (paraelastic) phase. 

Analytical Procedures. Standard methods for analysis of food-grade adipic acid are described ia the Food Chemicals Codex (see Refs, ia Table 8). Classical methods are used for assay (titration), trace metals (As, heavy metals as Pb), and total ash. Water is determined by Kad-Fisher titration of a methanol solution of the acid. Determination of color ia methanol solution (APHA, Hazen equivalent, max. 10), as well as iron and other metals, are also described elsewhere (175). Other analyses frequendy are required for resia-grade acid. For example, hydrolyzable nitrogen (NH, amides, nitriles, etc) is determined by distillation of ammonia from an alkaline solution. Reducible nitrogen (nitrates and nitroorganics) may then be determined by adding DeVarda s alloy and continuing the distillation. Hydrocarbon oil contaminants may be determined by ir analysis of halocarbon extracts of alkaline solutions of the acid. 

Alloy development in the former Soviet Union has produced alloys having strengths equivalent to IN-100 and Mar-M-200. Alloys developed in the United States and United Kingdom are also widely used in French aircraft engines. 

Various expressions have been derived from which corresponding rates for alloys can be calculated. AH these procedures are based on calculating an effective value for the chemical equivalent of the alloy. Thus for Nimonic 75, a typical nickel alloy used in the aircraft industry, a chemical equivalent of 25.1 may be derived (4). The Nimonic alloy is given to have, on a basis of wt %, 72.5 Ni, 19.5 Cr, 5.0 Ee, 0.4 Ti, 1.0 Si, 1.0 Mn, and 0.5 Cu (see Nickel and... 

Chromium—Cobalt—Iron Alloys. In 1971, a family of ductile Cr—Co—Fe permanent-magnet alloys was developed (79). The Cr—Co—Fe alloys are analogous to the Alnicos in metallurgical stmcture and in permanent magnetic properties, but are cold formable at room temperature. Equivalent magnetic properties also can be attained with substantially less Co, thereby offering savings in materials cost. 

The important (3-stabilizing alloying elements are the bcc elements vanadium, molybdenum, tantalum, and niobium of the P-isomorphous type and manganese, iron, chromium, cobalt, nickel, copper, and siUcon of the P-eutectoid type. The P eutectoid elements, arranged in order of increasing tendency to form compounds, are shown in Table 7. The elements copper, siUcon, nickel, and cobalt are termed active eutectoid formers because of a rapid decomposition of P to a and a compound. The other elements in Table 7 are sluggish in their eutectoid reactions and thus it is possible to avoid compound formation by careful control of heat treatment and composition. The relative P-stabilizing effects of these elements can be expressed in the form of a molybdenum equivalency. Mo (29) ... 

Titanium alloyed with kon is a candidate for soHd-hydride energy storage material for automotive fuel. The hydride, FeTiH2, absorbs and releases hydrogen at low temperatures. This hydride stores 0.9 kWh /kg. To provide the energy equivalent to a tank of gasoline would thus requke about 800-kg... 

This computation is also referred to as calculating the zinc equivalent of the alloy. The increase in strength in this alloy series is caused by increased amounts of beta phase in the stmcture. The silicon brasses show similar hardening effects accompanying a second phase. Typical mechanical properties and electrical conductivity for various cast alloys are shown in Table 2. 

Corrosion Rate by CBD Somewhat similarly to the Tafel extrapolation method, the corrosion rate is found by intersecting the extrapolation of the linear poi tion of the second cathodic curve with the equihbrium stable corrosion potential. The intersection corrosion current is converted to a corrosion rate (mils penetration per year [mpy], 0.001 in/y) by use of a conversion factor (based upon Faraday s law, the electrochemical equivalent of the metal, its valence and gram atomic weight). For 13 alloys, this conversion factor ranges from 0.42 for nickel to 0.67 for Hastelloy B or C. For a qmck determination, 0.5 is used for most Fe, Cr, Ni, Mo, and Co alloy studies. Generally, the accuracy of the corrosion rate calculation is dependent upon the degree of linearity of the second cathodic curve when it is less than... 

The addition of small amounts of alloying materials greatly improves corrosion resistance to atmospheric environments but does not have much effect against liquid corrosives. The alloying elements produce a tight, dense adherent rust film, but in acid or alkaline solutions corrosion is about equivalent to that of carbon steel. However, the greater strength permits thinner walls in process equipment made from low-alloy steel. 

Similarly, graphitically corroded cast iron (see Chap. 17) can assume a potential approximately equivalent to graphite, thus inducing galvanic corrosion of components of steel, uncorroded cast iron, and copper-based alloys. Hence, special precautions must be exercised when dealing with graphitically corroded pump impellers and pump casings (see Cautions in Chap. 17). 

Equivalent grades of Indian Aluntinium (Indal) alloys... 

It was concluded that 1.5Ti-3.0Al should be considered the most suitable alloy for ECC flue gas expander rotors. A 1,400-mm diameter expander rotor disk was manufactured using this alloy. Test specimens removed from the disk rim showed that the disk had equivalent tensile properties at both room and elevated temperatures, and the same creep rupture strength as that of AISI 685. 

Poor Weldability a. Underbead cracking, high hardness in heat-affected zone. b. Sensitization of nonstabilized austenitic stainless steels. a. Any welded structure. b. Same a. Steel with high carbon equivalents (3), sufficiently high alloy contents. b. Nonstabilized austenitic steels are subject to sensitization. a. High carbon equivalents (3), alloy contents, segregations of carbon and alloys. b. Precipitation of chromium carbides in grain boundaries and depletion of Cr in adjacent areas. a. Use steels with acceptable carbon equivalents (3) preheat and postheat when necessary stress relieve the unit b. Use stabilized austenitic or ELC stainless steels. 

Carbon Equivalent (CE) is an approximate measure of weldability expressed in terms of the sum of carbon content and the alloy contents divided by applicable factors to relate equivalence in carbon in effectiveness in hardening—and thereby cracking. Commonly used formulas with commonly accepted but rather arbitrarily set maximums are ... 

Among the measures which have successfully prevented metal dusting are the use of additives (steam, and compounds of S, As, Sb, and P) in the feed, reduction of pressure, reduction of temperature, and material change. The most common additives are sulfur compounds and steam. Susceptibility can be reduced by using a material in which the total percent of Cr plus two times the percent of Si is in excess of 22 percent. In some environments, a. small amount of a sulfur compound will stop the dusting. When sulfur compounds cannot be tolerated in the process stream, a combination of steam and an alloy with a Cr equivalent of over 22 percent may be most desirable. 

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