Boilers feed water

Feed water to boilers operating at moderate steam pressures should be softened and treated [28.1] to ensure that it  

Lime-soda ash softening, followed by settling or filtration, can be used to remove suspended solids and non-carbonate hardness, and to reduce the carbonate hardness to the required level. 

Commercial hydrated limes are suitable for the treatment of boiler feed water. 

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The Stamicarbon wastewater system consisting of two desorbers, hydrolyzer, hydrolyzer heater, reflux condenser, desorber heat exchanger, and a wastewater cooler is very efficient. Also, in many plants, as the water contains less than 1 ppm of NH and of urea, it can be used as cooling water make-up, or boiler-feed water. 

All process Hcensors also feature wastewater treatment systems. Stamicarbon guarantees the lowest NH —urea content and has plants in operation confirming the low NH —urea (1 ppm NH —1 ppm urea). This water is very satisfactory to use as boiler feed water. See Figures 16 and 17 for this system. 

Fig. 1. Process flow diagram of the commercial propylene ammoxidation process for acrylonitrile. BFW, boiler feed water.

Humidification. For wiater operation, or for special process requirements, humidification maybe required (see Simultaneous HEAT and mass transfer). Humidification can be effected by an air washer which employs direct water sprays (see Evaporation). Regulation is maintained by cycling the water sprays or by temperature control of the air or water. Where a large humidification capacity is required, an ejector which direcdy mixes air and water in a no22le may be employed. Steam may be used to power the no22le. Live low pressure steam can also be released directly into the air stream. Capillary-type humidifiers employ wetted porous media to provide extended air and water contact. Pan-type humidifiers are employed where the required capacity is small. A water filled pan is located on one side of the air duct. The water is heated electrically or by steam. The use of steam, however, necessitates additional boiler feed water treatment and may add odors to the air stream. Direct use of steam for humidification also requires careful attention to indoor air quahty. 

This reaction is first conducted on a chromium-promoted iron oxide catalyst in the high temperature shift (HTS) reactor at about 370°C at the inlet. This catalyst is usually in the form of 6 x 6-mm or 9.5 x 9.5-mm tablets, SV about 4000 h . Converted gases are cooled outside of the HTS by producing steam or heating boiler feed water and are sent to the low temperature shift (LTS) converter at about 200—215°C to complete the water gas shift reaction. The LTS catalyst is a copper—zinc oxide catalyst supported on alumina. CO content of the effluent gas is usually 0.1—0.25% on a dry gas basis and has a 14°C approach to equihbrium, ie, an equihbrium temperature 14°C higher than actual, and SV about 4000 h . Operating at as low a temperature as possible is advantageous because of the more favorable equihbrium constants. The product gas from this section contains about 77% H2, 18% CO2, 0.30% CO, and 4.7% CH. ... 

Fig. 2. Schematic flow diagram of the ALMA fluidized-bed process (121). BFW BFW = boiler feed water.

Eig. 1. Monopressure process using catalytic NO abatement, where BEW = boiler feed water, CH = high level compression, CM = medium level compression, CW = cooling water, and D = makeup driver, EX = expander, and E = filter. 

Phosphonic acid is an intermediate in the production of alkylphosphonates that are used as herbicides and as water treatment chemicals for sequestration, scale inhibition, deflocculation, and ion-control agents in oil weUs, cooling tower waters, and boiler feed waters. For example, aqueous phosphonic acid reacts with formaldehyde and ammonium chloride in the presence of hydrochloric acid to yield aminotri(methylenephosphonic acid) [6419-19-8]. 

Organophosphoms compounds, primarily phosphonic acids, are used as sequestrants, scale inhibitors, deflocculants, or ion-control agents in oil wells, cooling-tower waters, and boiler-feed waters. Organophosphates are also used as plasticizers and flame retardants in plastics and elastomers, which accounted for 22% of PCl consumed. Phosphites, in conjunction with Hquid mixed metals, such as calcium—zinc and barium—cadmium heat stabilizers, function as antioxidants and stabilizer adjutants. In 1992, such phosphoms-based chemicals amounted to slightly more than 6% of all such plastic additives and represented 8500 t of phosphoms. Because PVC production is expected to increase, the use of phosphoms additive should increase 3% aimually through 1999. 

Fig. 11. Ocelot plant flow diagram. MEA, monoethano1 amine BFW, boiler feed water.

Demineralization. Softening alone is insufficient for most high-pressure boiler feed waters and for many process streams, especially those used in the manufacture of electronics equipment. In addition to the removal of hardness, these processes require removal of all dissolved soHds, such as sodium, sihca, alkalinity, and the mineral anions (Cl , and NO ). 

Boiler feed water pretreatment systems have advanced to such an extent that it is now possible to provide boilers with ultrapure water. However, this degree of purification requires the use of elaborate pretreatment systems. The capital expenditures for such pretreatment equipment trains can be considerable and are often not justified when balanced against the capabiUty of internal treatment. 

Boiler feed-water systems that use dernineralized or evaporated makeup or pure condensate may be protected from caustic attack through coordinated phosphate and pH control. Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic or acid concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate. 

Overall comparison between amine and carbonate at elevated pressures shows that the amine usually removes carbon dioxide to a lower concentration at a lower capital cost but requires more maintenance and heat. The impact of the higher heat requirement depends on the individual situation. In many appHcations, heat used for regeneration is from low temperature process gas, suitable only for boiler feed water heating or low pressure steam generation, and it may not be usefiil in the overall plant heat balance. 

Fig. 1. Typical heater configuration. BFW = boiler feed water SSH = super high pressure steam HP = high pressure and ID = induced draft..

Catalyst contamination from sources such as turbine lubricant and boiler feed water additives is usuaUy much more severe than deactivation by sulfur compounds in the turbine exhaust. Catalyst formulation can be adjusted to improve poison tolerance, but no catalyst is immune to a contaminant that coats its surface and prevents access of CO to the active sites. Between 1986 and 1990 over 25 commercial CO oxidation catalyst systems operated on gas turbine cogeneration systems, meeting both CO conversion (40 to 90%) and pressure drop requirements. 

Site development Boiler feed-water treatment... 

Process Water Purification Boiler feed water is a major process apphcation of RO. Sealants and colloids are particularly well rejected by membranes, and TDS is reduced to a level that makes ion exchange or continuous deionization for the residual ions very economic. Even the extremely high quahty water required for nuclear power plants can be made from seawater. The iiltra-high quahty water required for production of electronic microcircuits is usually processed starting with two RO systems operating in series, followeci by many other steps. 

If the d-a tank should be. sealed and artificially pressurized with steam gas (sometimes they are, or should be), then each 10 psi adds 23.1 ft of artificial head to the. sy.stem s NPSHa. If the boiler feed water pump has a NPSHr of 30 ft at the duty point, now you can see why boiler feed water pumps are sometimes considered problematic regarding eavitation. This also demonstrates the need to seal and artifieially pressurize d-a tanks to get the NPSHa above the NPSHr of the pump. 

The fluid being pumped is often not well defined. Terminology like well water, industrial effluent, raw water, boiler feed water, condensate water, etc., is usually the only definition we have of the fluid being pumped. Any of these fluids can contain several concentrations of. solids that cause erosion and wear inside the pump. 

A tank with a fixed cover of plain carbon steel for storing 60°C warm, softened boiler feed water that had a tar-pitch epoxy resin coating showed pits up to 2.5 mm deep after 10 years of service without cathodic protection. Two separate protection systems were built into the tank because the water level varied as a result of service conditions. A ring anode attached to plastic supports was installed near the bottom of the tank and was connected to a potential-controlled protection rectifier. The side walls were protected by three vertical anodes with fixed adjustable protection current equipment. 

Activate steam Introduce steam to Boiler feed water Vent inerts from Check all headers. Check for... 

Petrochemical Recycling of steam condensate for boiler feed water Removal of oil and hydrocarbon contamination... 

Condensate is to be recovered and returned to treating and boiler feed water facilities. 

Demineralized water is water from which all the minerals have been removed by ion-eNchange. It is used where pure water is needed for a process and as boiler feed water. Mixed and multiple-bed ion-exehange units are used for this purpose, one resin converting the cations to hydrogen and the other removing the acid radicals. Water can be produced that has less than I ppm of dissolved solids. 

The usual concentration of O2 in boiler feed water is 0.01 ppm so that, even allowing for a twofold excess, 1 kg N2H4 is sufficient to treat 50000 tonnes of feed water (say 4 days supply at the rate of 5(X) tonnes per hour). 

Kessel-niederscUag, m. deposit in a kettle, boiler or reservoir, -ofen, m. pot furnace crucible furnace. -rohr, n. boiler tube, -spaonung,/. boiler pressure, -speisewasser, n. boiler feed water, -speisimg, /. boiler feeding, boiler feed. 

Assume that a boiler feed water is being pumped at 180 °F. Read the chart in Figure 3-46 and the water vapor pressure curve, and follow over to read NPSH reduction = 0.45 feet. A pump selected for the sertice requires 6 feet cold water service NPSHr ... 

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