Attached anodes

Attached anodes provide the particular advantage of proportionately low grounding resistance for the protection current because the actual anode body is set into both sloping sides of the plastic body as long narrow strips. The disadvantage is that the body is exposed on the ship s side and can easily be damaged mechanically. 

Aromatic perfluoroaLkylation can be effected by fluorinated aUphatics via different techniques. One category features copper-assisted coupling of aryl hahdes with perfluoroalkyl iodides (eg, CF I) (111,112) or difluoromethane derivatives such as CF2Br2 (Burton s reagent) (113,114), as well as electrochemical trifluoromethylation using CF Br with a sacrificial copper anode (115). Extmsion of spacer groups attached to the fluoroalkyl moiety, eg,... 

Solid Polymer E,kctroljte. The electrolyte in soHd polymer electrolyte (SPE) units is Nafion, a soHd polymer developed by Du Pont, which has sulfonic acid groups attached to the polymer backbone. Electrodes are deposited on each side of the polymer sheet. H" ions produced at the anode move across the polymer to the cathode, and produce hydrogen. The OH ions at the anode produce oxygen. These units have relatively low internal resistances and can operate at higher temperatures than conventional alkaline electrolysis units. SPE units are now offered commercially. 

Functionalized conducting monomers can be deposited on electrode surfaces aiming for covalent attachment or entrapment of sensor components. Electrically conductive polymers (qv), eg, polypyrrole, polyaniline [25233-30-17, and polythiophene/23 2JJ-J4-j5y, can be formed at the anode by electrochemical polymerization. For integration of bioselective compounds or redox polymers into conductive polymers, functionalization of conductive polymer films, whether before or after polymerization, is essential. In Figure 7, a schematic representation of an amperomethc biosensor where the enzyme is covalendy bound to a functionalized conductive polymer, eg, P-amino (polypyrrole) or poly[A/-(4-aminophenyl)-2,2 -dithienyl]pyrrole, is shown. Entrapment of ferrocene-modified GOD within polypyrrole is shown in Figure 7. 

Examples of the sacrificial-anode method include the use of zinc, magnesium, or aluminum as anodes in electrical contact with the metal to be protected. These may be anodes buried in the ground for protection of underground pipe lines or attachments to the surfaces of equipment such as condenser water boxes or on ship hulls. The current required is generated in this method by corrosion of the sacrificial-anode material. In the case of the impressed emf, the direct current is provided by external sources and is passed through the system by use of essentially nonsacrificial anodes such as carbon, noncor-rodible alloys, or platinum buried in the ground or suspended in the electrolyte in the case of aqueous systems. 

Although rod anodes screwed into the side walls of containers are preferred, plate anodes and basket anodes are mostly necessary on the base. They are particularly suitable for large containers without being built in. Plate anodes are supplied with a flat plastic holder to which the cable conductor is attached and... 

In total, three high-silicon iron anodes of 3 kg each were installed at points a, aj and as shown in Fig. 11-3. The anodes were bedded vertically in fine-grained coke in boreholes about 2.3 m deep and J = 0.2 m so that the length of the coke backfill was about 1 m. Each anode was connected by a separate cable to the anode bus bar of the transformer-rectifier to allow the current of individual anodes to be monitored. Three cathode cables 2x4 mm were installed for the return path of the protection current and attached on the tank end to the connecting clamps of the dome support. 

The anodes can either be laid on the bottom, hung between the pillars or attached to the object to be protected. In every case they should be mounted so they can be easily exchanged. Anodes laid on the seabed are installed on concrete sleds or concrete slabs (see Fig. 16-7) so that they do not sink into the mud or become covered with sand. The current output in sand is considerably reduced due... 

Propeller brackets in multipropeller ships must be particularly protected. In small ships the anodes are attached on both sides at the base of the propeller bracket. With large ships the anodes are welded onto the propeller brackets (see Fig. 17-4). 

Special propulsion also requires relevant calculations and distribution of the anodes. For Kort nozzles, the total surface area of the mdder is determined and a basic protection current density of 25 mAm" imposed. The anodes are attached on the external surface at a spacing of 0.1 r to 0.25 r at the region of greatest diameter. Internally the anodes are fixed to the strengthening stmts. With Voith-Schneider propellers, the anodes are arranged around the edge of the base of the propeller. 

Ships with nonmetallic hulls frequently have metallic attachments which can be cathodically protected. Here the anodes are screwed onto the timber or plastic hull and electrically connected with low resistance via the interior of the ship to the objects to be protected. The metallic foundation serves for flotation and copper bands. 

Anodes are not attached to the rudder but are situated between the rudder shaft and the ship s wall and connected via a copper strip. The propeller is protected via a slip ring on the shaft. To achieve a low-resistance contact, the divided copper or bronze ring has a rolled silver-bearing surface on which metal graphite brushes slide. The transmission voltage should be below 40 mV. 

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