Boiler feed

The Stamicarbon wastewater system consisting of two desorbers, hydrolyzer, hydrolyzer heater, reflux condenser, desorber heat exchanger, and a wastewater cooler is very efficient. Also, in many plants, as the water contains less than 1 ppm of NH and of urea, it can be used as cooling water make-up, or boiler-feed water. 

All process Hcensors also feature wastewater treatment systems. Stamicarbon guarantees the lowest NH —urea content and has plants in operation confirming the low NH —urea (1 ppm NH —1 ppm urea). This water is very satisfactory to use as boiler feed water. See Figures 16 and 17 for this system. 

Fig. 1. Process flow diagram of the commercial propylene ammoxidation process for acrylonitrile. BFW, boiler feed water.

Humidification. For wiater operation, or for special process requirements, humidification maybe required (see Simultaneous HEAT and mass transfer). Humidification can be effected by an air washer which employs direct water sprays (see Evaporation). Regulation is maintained by cycling the water sprays or by temperature control of the air or water. Where a large humidification capacity is required, an ejector which direcdy mixes air and water in a no22le may be employed. Steam may be used to power the no22le. Live low pressure steam can also be released directly into the air stream. Capillary-type humidifiers employ wetted porous media to provide extended air and water contact. Pan-type humidifiers are employed where the required capacity is small. A water filled pan is located on one side of the air duct. The water is heated electrically or by steam. The use of steam, however, necessitates additional boiler feed water treatment and may add odors to the air stream. Direct use of steam for humidification also requires careful attention to indoor air quahty. 

This reaction is first conducted on a chromium-promoted iron oxide catalyst in the high temperature shift (HTS) reactor at about 370°C at the inlet. This catalyst is usually in the form of 6 x 6-mm or 9.5 x 9.5-mm tablets, SV about 4000 h . Converted gases are cooled outside of the HTS by producing steam or heating boiler feed water and are sent to the low temperature shift (LTS) converter at about 200—215°C to complete the water gas shift reaction. The LTS catalyst is a copper—zinc oxide catalyst supported on alumina. CO content of the effluent gas is usually 0.1—0.25% on a dry gas basis and has a 14°C approach to equihbrium, ie, an equihbrium temperature 14°C higher than actual, and SV about 4000 h . Operating at as low a temperature as possible is advantageous because of the more favorable equihbrium constants. The product gas from this section contains about 77% H2, 18% CO2, 0.30% CO, and 4.7% CH. ... 

Fig. 2. Schematic flow diagram of the ALMA fluidized-bed process (121). BFW BFW = boiler feed water.

Eig. 1. Monopressure process using catalytic NO abatement, where BEW = boiler feed water, CH = high level compression, CM = medium level compression, CW = cooling water, and D = makeup driver, EX = expander, and E = filter. 

Phosphonic acid is an intermediate in the production of alkylphosphonates that are used as herbicides and as water treatment chemicals for sequestration, scale inhibition, deflocculation, and ion-control agents in oil weUs, cooling tower waters, and boiler feed waters. For example, aqueous phosphonic acid reacts with formaldehyde and ammonium chloride in the presence of hydrochloric acid to yield aminotri(methylenephosphonic acid) [6419-19-8]. 

Organophosphoms compounds, primarily phosphonic acids, are used as sequestrants, scale inhibitors, deflocculants, or ion-control agents in oil wells, cooling-tower waters, and boiler-feed waters. Organophosphates are also used as plasticizers and flame retardants in plastics and elastomers, which accounted for 22% of PCl consumed. Phosphites, in conjunction with Hquid mixed metals, such as calcium—zinc and barium—cadmium heat stabilizers, function as antioxidants and stabilizer adjutants. In 1992, such phosphoms-based chemicals amounted to slightly more than 6% of all such plastic additives and represented 8500 t of phosphoms. Because PVC production is expected to increase, the use of phosphoms additive should increase 3% aimually through 1999. 

Fig. 11. Ocelot plant flow diagram. MEA, monoethano1 amine BFW, boiler feed water.

Fig. 25. Schematic of large fossil steam turbine system where BFPT = boiler feed pump turbine. To convert MPa to psi, multiply by 145.

Abundant supplies of fresh water are essential to the development of industry. Enormous quantities are required for the cooling of products and equipment, for process needs, for boiler feed, and for sanitary and potable water supply. 

Demineralization. Softening alone is insufficient for most high-pressure boiler feed waters and for many process streams, especially those used in the manufacture of electronics equipment. In addition to the removal of hardness, these processes require removal of all dissolved soHds, such as sodium, sihca, alkalinity, and the mineral anions (Cl , and NO ). 

Boiler feed water pretreatment systems have advanced to such an extent that it is now possible to provide boilers with ultrapure water. However, this degree of purification requires the use of elaborate pretreatment systems. The capital expenditures for such pretreatment equipment trains can be considerable and are often not justified when balanced against the capabiUty of internal treatment. 

Boiler feed-water systems that use dernineralized or evaporated makeup or pure condensate may be protected from caustic attack through coordinated phosphate and pH control. Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic or acid concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate. 

Overall comparison between amine and carbonate at elevated pressures shows that the amine usually removes carbon dioxide to a lower concentration at a lower capital cost but requires more maintenance and heat. The impact of the higher heat requirement depends on the individual situation. In many appHcations, heat used for regeneration is from low temperature process gas, suitable only for boiler feed water heating or low pressure steam generation, and it may not be usefiil in the overall plant heat balance. 

Fig. 1. Typical heater configuration. BFW = boiler feed water SSH = super high pressure steam HP = high pressure and ID = induced draft..

Catalyst contamination from sources such as turbine lubricant and boiler feed water additives is usuaUy much more severe than deactivation by sulfur compounds in the turbine exhaust. Catalyst formulation can be adjusted to improve poison tolerance, but no catalyst is immune to a contaminant that coats its surface and prevents access of CO to the active sites. Between 1986 and 1990 over 25 commercial CO oxidation catalyst systems operated on gas turbine cogeneration systems, meeting both CO conversion (40 to 90%) and pressure drop requirements. 

Site development Boiler feed-water treatment... 

The centrifugal pump is the type most widely used in the chemical industiy for transferring liquids of aU types—raw materials, materials in manufacture, and finished produc ts—as well as for general services of water supply, boiler feed, condenser circulation, condensate return, etc. These pumps are available through avast range of sizes, in capacities from 0.5 mVh to 2 X 10 mVh (2 gal/min to 10 gaJ/min), and for discharge heads (pressures) from a few meters to approximately 48 MPa (7000 Ibf/iu"). The size and type best suited to a particular apphcation can be determined only by an engineering study of the problem. 

The injector is a special type of jet pump, operated by steam and used for boiler feed and similar services, in which the fluid being pumped is discharged into a space under the same pressure as that of the steam being used to operate the injector. 

The efficiency of an ejecdor or jet pump is low, being only a few percent. The head developed by the ejector is also low except in special types. The device has the disadvantage of diluting the fluid pumped by mixing it with the pumping fluid. In steam injectors for boiler feed and similar seiwices in which the heat of the steam is recovered, efficiency is close to 100 percent. 

Process Water Purification Boiler feed water is a major process apphcation of RO. Sealants and colloids are particularly well rejected by membranes, and TDS is reduced to a level that makes ion exchange or continuous deionization for the residual ions very economic. Even the extremely high quahty water required for nuclear power plants can be made from seawater. The iiltra-high quahty water required for production of electronic microcircuits is usually processed starting with two RO systems operating in series, followeci by many other steps. 

Thermal power plant auxiliaries such as flow control of primary air fan, ID fan and forced-draught fans, boiler feed pumps circulating water pumps and condensate pumps, coal handling plant (e.g. ball mill, wagon tippler, and stacker reclaimer)... 

These applications have considerably more stringent performance requirements than any other application. Circulating water pumps, boiler feed pumps, forced-draught (FD) and induced-draught (ID) fans, pulverizers (ball mills) and condensate pumps are components in a thermal power station that may require extra safety in a standard motor to make it able to fulfil these requirements and withstand abnormal service conditions and system disturbances. Abnormal operating conditions may be one or more of the following ... 

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