Utilization, disposal

Using existing equipment for new process may overtax existing ancillary units e.g., utilities/disposal/ fire protection etc. Possibility of hazardous event. 

Supporters claim that CERCLA and the court rulings promote economic efficiency because they internalize externalities they make "polluters" pay. Such reasoning has an economic basis only when companies did not practice due care (i.e., utilize disposal practices whose benefits exceeded costs at the time of disposal). Economic efficiency is about the present and the future, not about the past. What should be done about sunk costs or past behavior is not an economic question except insofar as those policies that pay for sunk costs might affect current and future decisions. 

Feiler HD, Storch T J, Southworth R. 1980. Organics in municipal sludges Survey of forty cities. In Proceedings of the national conference on municipal industrial sludge utility disposal, 53-57. 

An alternative to using spray bulbs and wands to clean an isolator is utilizing disposable wipes soaked in an appropriate solvent to clean all areas that had potential to become contaminated with high-potency material. This allows the material to be solu-blized and removed from the surface. This wipedown can then be followed with... 

Data needed include expected variations in conditions costs of materials, labor, equipment, and utilities disposal limitations sources legal definitions and restrictions environmental impact measures and numerical values for the criteria. For all the species involved in the process, we need physical and thermodynamic data, and such reactivity and safety properties as flammability, corrosivity, abrasiveness, and propensity for dust explosions of solids, stability, environmental persistence and health indicators such as the LDjg, carcinogenicity, mutagenicity, and toxicity and those listed in Table 16.16. 

Sinclair et al. (79) have compared the environmental (primarily carbon) footprint of a monoclonal antibody (mAb) production facility using traditional stainless steel bioreactors with that of a facility utilizing disposable equipment for cell culture, mixing solutions, holding tanks, and liquid transfer. The mAbs are intended for use in therapeutic applications and are produced in a facility containing three 2000-L disposable bioreactors. The authors cradle-to-grave analysis took into account facility... 

Electrochemical cells based on a wall-jet pattern are very common in systems that utilize disposable electrodes. The basic principle behind these cells is to increase mass transfer towards the electrode surface both by using a flow system and manipulating the flow profile. 

Specifying the hot utility or cold utility or AT m fixes the relative position of the two curves. As with the simple problem in Fig. 6.2, the relative position of the two curves is a degree of freedom at our disposal. Again, the relative position of the two curves can be changed by moving them horizontally relative to each other. Clearly, to consider heat recovery from hot streams into cold, the hot composite must be in a position such that everywhere it is above the cold composite for feasible heat transfer. Thereafter, the relative position of the curves can be chosen. Figure 6.56 shows the curves set to ATn,in = 20°C. The hot and cold utility targets are now increased to 11.5 and 14 MW, respectively. 

Product quality specification Contractual agreements Capacity and availability Concurrent operations Monitoring and control Testing metering Standardisation Flaring and venting Waste disposal Utilities systems... 

The ratio of reactants had to be controlled very closely to suppress these impurities. Recovery of the acrylamide product from the acid process was the most expensive and difficult part of the process. Large scale production depended on two different methods. If soHd crystalline monomer was desired, the acrylamide sulfate was neutralized with ammonia to yield ammonium sulfate. The acrylamide crystallized on cooling, leaving ammonium sulfate, which had to be disposed of in some way. The second method of purification involved ion exclusion (68), which utilized a sulfonic acid ion-exchange resin and produced a dilute solution of acrylamide in water. A dilute sulfuric acid waste stream was again produced, and, in either case, the waste stream represented a... 

Manufacture Various methods for the manufacture of acrylates are summarized in Figure 1, showing thek dependence on specific raw materials. For a route to be commercially attractive, the raw material costs and utilization must be low, plant investment and operating costs not excessive, and waste disposal charges minimal. 

The need to meet environmental regulations can affect processing costs. Undesirable air emissions may have to be eliminated and Hquid effluents and soHd residues treated and disposed of by incineration or/and landfilling. It is possible for biomass conversion processes that utilize waste feedstocks to combine waste disposal and treatment with energy and/or biofuel production so that credits can be taken for negative feedstock costs and tipping or receiving fees. 

Suitable ventilating equipment, consisting mainly of carbon absorbers which effectively absorb mercury vapor from recirculated air, must be employed to maintain standards below the value permitted in the occupational environment. When the possibiUty of higher exposures exists, small disposable masks utilizing a mercury vapor absorbent may be employed. 

The acidic contaminants can also be removed by employing a system that utilizes extractions, precipitation, distillation, and other treatments for rendering the waste stream acceptable for current disposal standards (18—20). First Chemical Corporation uses such a system. Residual nitric acid can be removed by a multistage countercurrent Hquid-Hquid extraction. The nitric acid (ca 25%) is then reconcentrated by distillation for further use. 

The nitroparaffins have been utilized for many appHcations (114). Some of these uses have been discontinued because of economic and environmental considerations. For instance, significant quantities of 1-nitropropane once were used for the production of hydroxylammonium sulfate and propionic acid by hydrolysis. The need to dispose of an acid waste stream from this process made it uneconomical, so it was discontinued. 

Consumption of nonwoven roU goods is often reported in two broad areas, according to product appHcation disposables and durables. In general, disposable products account for 85% of the volume and 60% of the value of nonwoven roU goods consumption (19). Items within each disposable or durable product category reflect the diversity of appHcations which utilize nonwovens. 

Landfill G as Recovery. This process has emerged from the need to better manage landfill operations. Landfill gas is produced naturally anaerobic bacteria convert the disposed organic matter into methane, carbon monoxide, and other gases. The quantity of methane gas is substantial and could be utilized as fuel, but generally is not. Most of the methane simply leaks into the surrounding atmosphere. 

The advantages claimed for organotin polymer-based antifouling paints include constant toxicant deHvery vs time, erosion rate and toxicant deHvery are controUable, no depleted paint residue to remove and dispose, 100% utilization of toxicant, polishing at high erosion rates, surface is self-cleaning, and function is continuously reactivated. 

Formerly, water was accepted by a second user for reuse while it was still under control of the first user (5). Today, the used water is treated in such a manner that it can be used again before ultimate disposal. Furthermore, a distinction can be made between direct reuse, where the water is reclaimed without dilution or natural purification, and indirect use, where treated used water is returned to the environment for subsequent utilization as a raw water supply. 

Because of increasing environmental concerns, the disposal of all batteries is being reviewed (70—76). Traditionally silver batteries were reclaimed for the silver metal and all other alkaline batteries were disposed of in landfills or incinerators. Some aircraft and industrial nickel —cadmium batteries are rebuilt to utilize the valuable components. 

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