Rate, erosion

The advantages claimed for organotin polymer-based antifouling paints include constant toxicant deHvery vs time, erosion rate and toxicant deHvery are controUable, no depleted paint residue to remove and dispose, 100% utilization of toxicant, polishing at high erosion rates, surface is self-cleaning, and function is continuously reactivated. 

The erosion of graphite in nozzle appHcations is a result of both chemical and mechanical factors. Changes in temperature, pressure, or fuel-oxidizing ratio markedly affect erosion rates. Graphite properties affecting its resistance to erosion include density, porosity, and pore size distribution... 

Interest in the application of turboexpanders turbine to FCC unit is very high, and deservedly so. The power recovery turboexpander offers practical improvement in FCC unit operating economics. Modern designs that encompass the entire system have fully overcome problems and concerns that may have existed decades ago. Expander metallurgy is available to vastly reduce erosion rates experienced when... 

How these factors affect erosion can be determined from the empirical equation shown in Table 4-14. The equation shows erosion rate proportional to a constant, the mass of the particle, its velocity, and angle of attack. 

If the amount of metal removal by erosion is significant the surface will probably be continually active. Metal loss will be the additive effect of erosion and active corrosion. Sometimes the erosion rate is higher than that of active corrosion. The material selection judgment can then disregard coirosion and proceed on the basis of erosion resistance provided the corrosion rates of aetive surfaces of the alloys considered are not much different. As an example of magnitudes, a good high-chromium iron may lose metal from erosion only a tenth as fast as do the usual stainless steels. 

Modification of alkyd resins with high proportions of silicones considerably reduces rates of attack, but the most spectacular extension of life is shown by fluorinated polymers such as polyvinylidene fluoride where erosion rates can be reduced to 0 -1 /tm/year. If this level of durability can be achieved an initial coating, if firmly adherent and free from any breaks, may often be expected to maintain protection over a metal substrate for the likely life of the structure. The considerably increased first cost, as compared with more conventional coatings, has to be balanced against the probable saving in maintenance costs or consequences of failure. 

All tests are designed to provide high erosion rates on small specimens so that the test can be conducted in a reasonable time, and although vibratory and high-velocity jet methods may not simulate flow conditions they give rise to high-intensity erosion and can be used, therefore, for screening materials. 

Rivers transport suspended sediments derived from the disintegration of basin surface layers. With reduced velocity, sediment is deposited in the river channel. The finest material is carried to the sea. It has been estimated that the average mechanical denudation rate for continents is 0.056 mm year (35). This is based on a total suspended load of 13.5 x 10 metric tons year (S). Presently, about two-thirds of the world s total suspended sediment load derives from Southern Asia and large Pacific Islands. Berner has estimated the increase in sediment loss in the U.S. and world since prehuman times to be approximately 200% (35). Current estimated erosion rate from the major land forms is provided in Table I. The relatively recent construction of large sediment trapping dams that normally caused sediment to be deposited in river valleys or transported to the ocean has drastically reduced sediment yields in great rivers. 

Table I. Global Erosion Rates of Cropland, Grassland and Forest...

Land Type U.S. Area lO m Erosion Rate tons km yr World Area 10 km Erosion Rate tons km yr... 

Soil is a key component of the rock cycle because weathering and soil formation processes transform rock into more readily erodible material. Rates of soil formation may even limit the overall erosion rate of a landscape. Erosion processes are also a key linkage in the rock cycle... 

Human or natural actions that significantly alter the erosion resistance of the ground surface can lead to dramatic increases in erosion rates. Channel networks dissect natural landscapes down to a fine-scale limit controlled by a threshold of channel initiation (Montgomery and Dietrich, 1992). In effect, channels begin where sufficient discharge collects to overcome the erosion resistance of the ground surface (Horton, 1945 Montgomery and Dietrich, 1988). Consequently, human or natural actions... 

Fig. 8-10 Erosion rate as a function of relief for (a) mid-latitude medium-sized drainage basins (modified from Ahnert, 1970), and (b) for Hydrographer s Volcano, Papua New Guinea (data source Ruxton and McDougall, 1967).

In contrast, under transport-limited conditions, weathering rates are ultimately limited by the formation of soils that are sufficiently thick or impermeable to restrict free access by water to unweathered material. Erosion rates... 

A General Concordance Between Erosion Rates and Uplift Rates... 

In regions where the erosion regime is weathering limited, susceptibility of the bedrock to chemical and physical weathering controls erosion rates. This susceptibility relates directly to the chemical and physical properties of the rock. Susceptibility also depends on local climate. Moreover, weathering rates are affected by the... 

The effect of different backbones on ero.sion rates was demonstrated in a study of the homologous poly[ (p-carboxyphenoxy)alkane] series. As the number of methylene groups in the backbone increased from 1 to 6, thus decreasing the reactivity of the anhydride linkage and rendering the polymer more hydrophobic, the erosion rates underwent a decrease of three orders of magnitude (4). 

FIGURE 2 pH dependance of the erosion rate of PCPP versus time. Discs of PCPP were formulated into 1.4-cm-diameter discs 1 mm thick by compression molding, and placed into 0.1 M phosphate buffers at various pH values at 37°C. The cumulative percentage of the polymer which degraded was measured by absorbance at 250 nm. 

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