Polychlorinated biphenyls sources

Cacela D, Beltman D, and Lipton J (2002) Polychlorinated biphenyl source attribution in Green Bay, Wisconsin,... 

SW-846, is used to measure emissions of semivolatile principal organic constituents. Method 0010 is designed to determine destruction and removal efficiency (DRE) of POHCs from incineration systems. The method involves a modification of the EPA Method 5 sampling train and may be used to determine particulate emission rates from stationary sources. The method is applied to semivolatile compounds, including polychlorinated biphenyls (PCBs), chlorinated dibenzodioxins and dibenzofurans, polycyclic organic matter, and other semivolatile organic compounds. 

Polychlorinated Biphenyl (PCB) Sources, Fire Training Areas, and Fill... 

The major energy-related sources of water pollution are from thermal pollution, surface water pollution from oil spills, polychlorinated biphenyls, and groundwater contamination. 

Although the major concern about the fate of organic pollntants in soil has been about pesticides in agricultural soils, other scenarios are also important. The disposal of wastes on land (e.g., at landfill sites) has raised questions about movement of pollutants contained in them into the air or neighboring rivers or water conrses. The presence of polychlorinated biphenyls (PCBs) or PAHs in snch wastes can be a significant source of pollution. Likewise, the disposal of some industrial wastes in landfill sites (e.g., by the chemical industry) raises questions about movement into air or water and needs to be carefully controlled and monitored. 

Valnes of have been measnred for a number of polychlorinated biphenyl (PCB) congeners and applied to a nnmber of commercial PCB mixtures. Both the number and the position of the chlorine snbstitnents affected the depletion of C, and this reflected the mannfacturing procednres that involved kinetic isotope effects as well as the source of the biphenyl starting material (Jarman et al. 1998). It was snggested that this could be applied to determine the source of PCBs in the environment. 

Volatilization. Transfer of chemicals across the air/water interface can result in either a net gain or loss of chemical, although in many cases the bulk concentration in the air above a contaminated water body is low enough to be neglected (20). When the atmosphere is the primary source of the contaminant, as for example polychlorinated biphenyls in some parts of the Laurentian Great Lakes, atmospheric concentrations obviously cannot be neglected. The Whitman two-film or two-resistance approach (21) has been applied to a number of environmental situations (20, 22, 23). Transport across the air/water interface is viewed as a two-stage process, in which both phases of the interface can offer resistance to transport of the chemical. The rate of transfer depends on turbulence in the water body and in the atmosphere, the... 

Maugh P (1973) An unrecognized source of polychlorinated biphenyls. Science 180 1527-1528 McCave IN (1984) Size spectra and aggregation of suspended particles in the deep ocean. Deep-Sea Res 31 329-352... 

The polychlorinated biphenyls (PCBs) have been used commercially since 1929 as dielectric and heat exchange fluids and in a variety of other applications. The presence of PCBs in human and wildlife tissues was first recognized in 1966. Investigations in many parts of the world have since revealed widespread distribution of PCBs in the environment, including remote areas with no PCB production or use. There is evidence that the major source of PCB exposure in the general environment is the redistribution of PCBs previously introduced into the environment. It is believed that large bodies of water, such as the Baltic Sea and the Canadian Great Lakes, may... 

Highly halogenated organic compounds such as polychlorinated biphenyls and perchloroethylene appear to be too highly oxidised and low in energy content to serve as sources of electrons and energy for microbial metabolism. Bacteria are more likely to use them as electron acceptors in cell-membrane-based respiration processes [154]. The environmental fate of halogenated polymers such as polyvinylchloride or Teflon may depend on the question of whether it will be appropriate to sustain de-halorespiration processes. 

The quantitative environmental analysis of surfactants, such as alcohol ethoxylates, alkylphenol ethoxylates (APEOs) and linear alkylbenzene sulfonates (LASs), is complicated by the presence of a multitude of isomers and oligomers in the source mixtures (see Chapter 2). This issue bears many similarities to the quantitation problems that have occurred with halogenated aromatic compound mixtures, e.g. polychlorinated biphenyls (PCBs) [1]. 

Polychlorinated biphenyls (PCBs) have been used in various industrial processes during the past 40 years but were not recognized as major environmental contaminants until 1966 (1). Fish as a major food source have attained the dubious honor of being the most frequently cited PCB contamination problem (2). In the following presentation disposition of PCBs in fish will be discussed from four points of view accumulation, metabolism, distribution and elimination. No attempt will be made to cover PCB residue levels found in fish in nature (3) or acute or chronic toxicity of PCBs in fish (4-20). 

Source Hexachlorobenzene may enter the environment from incomplete combustion of chlorinated compounds including mirex, kepone, chlorobenzenes, pentachlorophenol, PVC, polychlorinated biphenyls, and chlorinated solvents (Ahling et al., 1978 Dellinger et al., 1991). In addition, hexachlorobenzene may enter the environment as a reaction by-product in the production of carbon tetrachloride, dichloroethylene, hexachlorobutadiene, trichloroethylene, tetrachloro-ethylene, pentachloronitrobenzene, and vinyl chloride monomer (quoted, Verschueren, 1983). 

Polychlorinated biphenyls (PCBs) and radioactive substances, predominantly emitted by industrial sources, are not specific to any type of farming activity. As with heavy metals, similar levels of contamination are to be expected in organic and conventional food sources. 

The Remediation Technologies, Inc. (RETEC), Thermatek thermal desorption system is an ex situ high-temperature treatment technology that treats soils, sediments, and sludges contaminated with volatile organic compounds (VOCs) and polychlorinated biphenyls (PCBs). The process uses a conventional Holo-Flite thermal desorption unit with RETEC s proprietary modifications, using an indirect heating source. 

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