Stationary source

A comparison of typical emissions from various common combushon sources may be seen in Table 6-1. 

Emissions from industrial processes are varied and often complex (4). These emissions can be controlled by applying the best available technology. The emissions may vary slightly from one facility to another, using apparently similar equipment and processes, but in spite of this slight variation, similar control technology is usually applied (5). For example, a 

Contaminant Power plant emission (gm/kg fuel) Refuse burning emission (gm. kg refuse) Uncontrolled automotive emiSHon (gm/kg fuel)  

In any discussion of the importance of emissions from a particular process for an area, several factors must be considered—(1) the percentage of the total emissions of the area that the particular process emits, (2) the degree of toxicity of the emissions, and (3) the obvious characteristics of the source (which can be related to either sight or smell). 

In the manufacture of varnish, heat is necessary for formulation and purificahon. The same may be true of operations preparing paints, shellac, inks, and other protective or decorative coahngs. The compounds emitted to the atmosphere are gases, some with extremely low odor thresholds. Acrolein, with an odor threshold of about 4000 /xg/m, and reduced sulfur compounds, with odor thresholds of 2 are bofh possible emissions 

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T. J. Tyson, "The Mathematical Modeling of Combustion Devices," paper presented at Proceedings of the Stationary Source Combustion Symposium, Vol. 

Air Quality Criteria forTead Supplement to the 1986 Addendum, U.S. EPA, Environmental Criteria and Assessment Office, Washington, D.C., 1990. Technical Support Document to Proposed Airborne Toxic Control Measure for Emissions of Toxic Metalsfrom Non-Ferrous Metal Melting, State of California Air Resources Board, Stationary Source Division, Sacramento, Calif., 1992. 

Hazardous Air Pollutants. Tide 3 of the CAAA of 1990 addresses the release of hazardous air poUutants (HAPs) by requiring both the identification of major stationary sources and area source categories for 189 toxic chemicals and the promulgation of control standards. Major sources of air toxics, also referred to as HAPs, include any stationary source or group of sources emitting 10 or more tons/yr of any single Hsted toxic chemical or 25 tons/yr of a combination of any Hsted toxic. Area sources of HAPs include smaller plants that emit less than the 10 or 20 tons/yr thresholds. The major sources of HAPs are typically industrial faciHties. However, Tide 3 requites the EPA to study potential health affects associated with emissions of HAPs from electric UtiHty boilers (11). 

The laser-Doppler anemometer measures local fluid velocity from the change in frequency of radiation, between a stationary source and a receiver, due to scattering by particles along the wave path. A laser is commonly used as the source of incident illumination. The measurements are essentially independent of local temperature and pressure. This technique can be used in many different flow systems with transparent fluids containing particles whose velocity is actually measured. For a brief review or the laser-Doppler technique see Goldstein, Appl. Mech. Rev., 27, 753-760 (1974). For additional details see Durst, MeUing, and Whitelaw, Principles and Practice of Laser-Doppler Anemometry, Academic, New York, 1976. 

John D McKennO/ Ph D / President and Chaiiman, ETS International, Inc., Member, Amencan In stitute of Chemical Engineers, Air and Wa.ste Management Association. (Air Pollution Management of Stationary Source.s)... 

Sources Subject to Prevention of Significant Deterioration (PSD) Sources subject to PSD regulations (40 CFR, Sec. 52.21, Aug. 7, 1980) are major stationary sources and major modifications located in attainment areas and unclassified areas. A major stationaiy source was defined as any source hsted in Table 25-4 with the potential to emit 100 tons per year or more of any pollutant regulated under the Clean Air Act (CAA) or any other source with the potential to emit 250 tons per year or more of any CAA pollutant. The potential to emit is defined as the maximum capacity to emit the pollutant under apphcable emission standards and permit conditions (after apphcation of any air pollution control equipment) excluding secondaiy emissions. A major modification is defined as any physical or operational change of a major stationaiy source producing a significant net emissions increase of any CAA pollutant (see Table 25-5). 

In addition to using annuahzed cost comparisons in evaluating an air-poUution-control (APC) equipment installation, the impact of the 1990 Clean Air Act Amendments (CAAA) and resulting regulations also must be included in the evaluation. The CAAA prescribes specific pollution-control requirements for particular industries and locations. As an example, the CAAA requires that any major stationary source or... 

The instrumental analyzer procedure, EPA Method 3A, is commonly used for the determination of oxygen and carbon dioxide concentrations in emissions from stationary sources. An integrated continuous gas sample is extracted from the test location and a portion of the sample is conveyed to one or more instrumental analyzers for determination of O9 and CO9 gas concentrations (see Fig. 25-30). The sample gas is conditioned prior to introduction to the gas analyzer by removing particulate matter and moisture. Sampling is conducted at a constant rate for the entire test run. Performance specifications and test procedures are provided in the method to ensure reliable data. 

Particulates Procedures for testing a particulate source are more detailed than those used for sampling gases. Because particulates exhibit inertial effects and are not uniformly distributed within a stack, sampling to obtain a representative sample is more complex than for gaseous pollutants. EPA Method 5 (as shown in Fig. 25-32) is the most widely used procedure for determination of particulate emissions from a stationary source. In-stack samphng guidehnes are presented in EPA Method 17. 

Sulfur Dioxide EPA Method 6 is the reference method for determining emissions of sulfur dioxide (SO9) from stationary sources. As the gas goes through the sampling apparatus (see Fig. 25-33), the sulfuric acid mist and sulfur trioxide are removed, the SO9 is removed by a chemical reaction with a hydrogen peroxide solution, and, finally, the sample gas volume is measured. Upon completion of the rim, the sulfuric acid mist and sulfur trioxide are discarded, and the collected material containing the SO9 is recovered for analysis at the laboratory. The concentration of SO9 in the sample is determined by a titration method. 

Fluorides Two EPA reference methods, Method 13A and Method 13B, can be used to determine total fluoride emissions from a stationary source. The difference in the two methods is the analyti-... 

SW-846, is used to measure emissions of semivolatile principal organic constituents. Method 0010 is designed to determine destruction and removal efficiency (DRE) of POHCs from incineration systems. The method involves a modification of the EPA Method 5 sampling train and may be used to determine particulate emission rates from stationary sources. The method is applied to semivolatile compounds, including polychlorinated biphenyls (PCBs), chlorinated dibenzodioxins and dibenzofurans, polycyclic organic matter, and other semivolatile organic compounds. 

Nitric oxide, NO, results from high-temperature combustion, both in stationary sources such as power plants or industrial plants in the production of process heat and in internal combustion engines in vehicles. The NO is oxidized in the atmosphere, usually rather slowly, or more rapidly if there is ozone present, to nitrogen dioxide, NO2. NO2 also reacts further with other constituents, forming nitrates, which is also in fine parhculate form. 

IDENTIFICATION AND QUANTIFICATION.—Such plan provisions shall expressly identify and quantify the emissions, if any, of any such pollutant or pollutants which will be allowed, from the construction and operation of major new or modified stationary sources in each such area. The plan shall demonstrate to the satisfaction of the Administrator that the emissions quantified for this purpose will be consistent with the achievement of reasonable further progress and will not interfere with the attainment of the applicable national ambient air quality standard by the applicable attainment date. 

Erode, R. W., Screening Procedures for Estimating the Air Quality Impact of Stationary Sources. EPA- 450/4-88-010. U. S. Environmental Protection Agenc), Research Triangle Park, NC. 1988. 

EPA is required to identify alternative control technologies for all categories of stationary sources of VOC or NOj that have the potential to emit 25 tons per year or more of either pollutant. 

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