Oil Dispersants

Title Alkyl Acrylate Copolymer VI Modifiers and Uses Thereof 

Patent Application Material Patentability Anticipated Issuing Date  

Research Focus Preparation of poly acrylate viscosity improvers containing grafted iV-phenyl-p-phenylenediamine as an antioxidant. 

Originality Departure from using oil viscosity improvers based on poly(ethylene-co- 

Observations Most automotive oil viscosity improvers are based on shear stable 

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A 25% dispersion of NaH crystals ia oil is obtained. The commercial product, after filtration, is a 60% dispersion of NaH crystals (5—50 p.m). The oil dispersions can be handled quite safely because the oil phase provides a barrier to air and moisture, whereas the unprotected crystals react vigorously. Traces of unreacted sodium metal give the product a gray color. 

Potassium, Pubidium, and Cesium idjdrides. Although all the other alkah metal hydrides have been synthesized and some of the properties measured, only potassium hydride [7693-26-7] is commercially available. KH is manufactured in small amounts and sold as a mineral oil dispersion. It is a stronger base than NaH and is used to make the strong reducing agent KBH(C2H )2 and the super bases RNHK and ROK (6). 

Potassium Hydride. Potassium hydride [7693-26-7] KH, made from reaction of molten potassium metal with hydrogen at ca 200°C, is suppHed in an oil dispersion. Pressure Chemical Company (U.S.) is a principal suppHer. KH is much more effective than NaH or LiH for enolization reactions (63,64). Use of KH as a base and nucleophile has been reviewed (65). 

Dimethyl carbonate is available from Aldrich Chemical Company, Inc. The checkers dried the tetrahydrofuran Immediately before use by distillation from the sodium ketyl of benzophenone under a nitrogen atmosphere. The submitters purchased sodium hydride (50% oil dispersion) from Alfa Products, Morton/Thiokol, Inc. The checkers used 12.24 g of a 50% dispersion of sodium hydride in mineral oil obtained from the same supplier. The dispersion was washed with three portions of pentane to remove the mineral oil and the remaining sodium hydride was allowed to dry under nitrogen. 

The sodium hydride-mineral oil dispersion was purchased from Alfa Products, Morton/Thiokol, Inc. 

NOTE Water-in-oil dispersants have an HLB of between 0 to 5. Examples include sorbitan tristearate (HLB = 3.5) and sorbitan monolaurate (HLB = 4.3). 

The submitters employed a dispersion of sodium hydride in mineral oil obtained from Prolabo, Paris. The checkers employed 17 g. of mineral oil dispersion containing 57% sodium hydride obtained from Alfa Inorganics, Inc. 

The multiple emulsion technique includes three steps 1) preparation of a primary oil-in-water emulsion in which the oil dispersed phase is constituted of CH2CI2 and the aqueous continuous phase is a mixture of 2% v/v acetic acid solution methanol (4/1, v/v) containing chitosan (1.6%) and Tween (1.6, w/v) 2) multiple emulsion formation with mineral oil (oily outer phase) containing Span 20 (2%, w/v) 3) evaporation of aqueous solvents under reduced pressure. Details can be found in various publications [208,209]. Chemical cross-linking is an option of this method enzymatic cross-linking can also be performed [210]. Physical cross-linking may take place to a certain extent if chitosan is exposed to high temperature. 

Titanium dioxide is an amorphous white powder characterized by brightness and a very high refractive index (2.4). It is insoluble in water and organic solvents, and is a very stable material, resistant to light, pH variation, oxidation, etc. Ti02 is available in oil-dispersible and water-dispersible forms. 

Some guidelines have been provided for defining the metastable region. If the seed crystals dissolve when added to the metastable solution, this implies that saturation conditions have not been reached. If the addition of the seed leads to the formation of an oil dispersion, it may be concluded that supersaturation has been realized (Anderson, 2000). 

In addition, a fluid loss additive for oil-based drilling fluids, which consists of fatty acid compounds and lignite or humic acid, an oil-soluble or oil-dispersible amine or amine salt with phosphorie acid, or an aliphatic amide or hydroxyamide [392], has been described. 

Lignite or humic acid oil-soluble or oil-dispersible amine [392]... 

A corrosion inhibitor with excellent film-forming and film-persistency characteristics is produced by first reacting Cig unsaturated fatty acids with maleic anhydride or fumaiic acid to produce the fatty acid Diels-Alder adduct or the fatty acid-ene reaction product [31]. This reaction product is further reacted in a condensation or hydrolyzation reaction with a polyalcohol to form an acid-anhydride ester corrosion inhibitor. The ester may be reacted with amines, metal hydroxides, metal oxides, ammonia, and combinations thereof to neutralize the ester. Surfactants may be added to tailor the inhibitor formulation to meet the specific needs of the user, that is, the corrosion inhibitor may be formulated to produce an oil-soluble, highly water-dispersible corrosion inhibitor or an oil-dispersible, water-soluble corrosion inhibitor. Suitable carrier solvents may be used as needed to disperse the corrosion inhibitor formulation. 

Polyesters may be used [27-30,223] instead of a fatty acid modifier for imidazoline. Thus a corrosion inhibitor with film-forming and film-persistency characteristics can be produced by first reacting, in a condensation reaction, a polybasic acid with a polyalcohol to form a partial ester. The partial ester is reacted with imidazoline or fatty diamines to result in a salt of the ester. Oil-soluble, highly water-dispersible corrosion inhibitor or oil-dispersible. 

The response of marine macrophytes on oil dispersion is dependent on the type of both oil and oil dispersant [292]. Germination inhibition of the marine macrophyte Phyllospora comosa was used to assess and compare the effects of oil dispersants and dispersed diesel fuel and crude oil combinations. The inhibition of germination by the water-soluble fraction of diesel fuel increased after adding all dispersants investigated. This contrasted with crude oil, in which the addition of some dispersants resulted in an enhanced germination rate. 

Many sea trials of dispersant chemicals to demonstrate the effectiveness of specific products or to elucidate the processes of oil dispersion into the water column have been described. Most tests have proved inconclusive, leading many to believe that dispersant chemicals are only marginally effective. Tests in a wave basin have been conducted to measure dispersant effectiveness under closely controlled conditions [261]. These tests show that dispersed oil plumes may be irregular and concentrated over small volumes, so extensive plume sampling was required to obtain accurate dispersant effectiveness measurements. In large-scale sea trials, dispersants have been shown effective, but only when sufficient sampling of the water column was done to detect small concentrated dispersed oil plumes and when it was known that the dispersant was applied primarily to the thick floating oil. 

The effectiveness of a number of crude oil dispersants, measured using a variety of evaluation procedures, indicates that temperature effects result from changing viscosity, dispersants are most effective at a salinity of approximately 40 ppt (parts per thousand), and concentration of dispersant is critical to effectiveness. The mixing time has little effect on performance, and a calibration procedure for laboratory dispersant effectiveness must include contact with water in a manner analogous to the extraction procedure otherwise, effectiveness may be inflated [587]. Compensation for the coloration produced by the dispersant alone is important only for some dispersants. 

Each oil-dispersant combination shows a unique threshold or onset of dispersion [589]. A statistic analysis showed that the principal factors involved are the oil composition, dispersant formulation, sea surface turbulence, and dispersant quantity [588]. The composition of the oil is very important. The effectiveness of the dispersant formulation correlates strongly with the amount of the saturate components in the oil. The other components of the oil (i.e., asphaltenes, resins, or polar substances and aromatic fractions) show a negative correlation with the dispersant effectiveness. The viscosity of the oil is determined by the composition of the oil. Therefore viscosity and composition are responsible for the effectiveness of a dispersant. The dispersant composition is significant and interacts with the oil composition. Sea turbulence strongly affects dispersant effectiveness. The effectiveness rises with increasing turbulence to a maximal value. The effectiveness for commercial dispersants is a Gaussian distribution around a certain salinity value. 

L. M. Flaherty, W. B. Katz, and S. Kaufmann. Dispersant use guidelines for freshwater and other inland environments. In Proceedings Volume, pages 25-30. Amer Soc Testing Mater Oil Dispersants New Ecol Approaches Symp (Williamsburg, VA, 10/12-10/14), 1987. 

A. Moet, M. Y. Bakr, M. Abdelmonim, and O. Abdelwahab. Factors affecting measurements of the efficiency of spilled oil dispersion. ACS Petrol Chem Div Preprints, 40(4) 564—566, August 1995. 

Dirt is attracted to and held on the skin and clothing mostly by fats and oils that are insoluble in water. Soap, an artificial, human-made (synthetic) substance, cleanses by making fats and oils dispersible in water soap acts as an emulsifier, a substance that disperses solids into liquids in which they are usually immiscible. When used as a body cleanser, for example, soap combines with oils and fats together with dirt particles on the skin, emulsifying and dispersing them in water in such a way that they can be disposed of with the water. 

A brown explosive form is produced if excess sodium is used in preparation of thiophene homologues—possibly because of sulfur compounds [1], As normally produced, it is a dry stable solid, but material prepared from acetylene and sodium-oil dispersions ignites in air [2],... 

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