Isobutyl acetate chloride

Acetamido-4-amino-6-chloro-s-triazine, see Atrazine Acetanilide, see Aniline, Chlorobenzene, Vinclozolin Acetic acid, see Acenaphthene, Acetaldehyde, Acetic anhydride. Acetone, Acetonitrile, Acrolein, Acrylonitrile, Aldicarb. Amyl acetate, sec-Amyl acetate, Bis(2-ethylhexyl) phthalate. Butyl acetate, sec-Butyl acetate, ferf-Butyl acetate, 2-Chlorophenol, Diazinon. 2,4-Dimethylphenol, 2,4-Dinitrophenol, 2,4-Dinitrotoluene, 1,4-Dioxane, 1,2-Diphenylhydrazine, Esfenvalerate. Ethyl acetate, Flucvthrinate. Formic acid, sec-Hexyl acetate. Isopropyl acetate, Isoamyl acetate. Isobutyl acetate, Methanol. Methyl acetate. 2-Methvl-2-butene. Methyl ferf-butvl ether. Methyl cellosolve acetate. 2-Methvlphenol. Methomvl. 4-Nitrophenol, Pentachlorophenol, Phenol. Propyl acetate. 1,1,1-Trichloroethane, Vinyl acetate. Vinyl chloride Acetoacetic acid, see Mevinphos Acetone, see Acrolein. Acrylonitrile. Atrazine. Butane. 

BuAc Isobutyl acetate MeCI Methylene chloride... 

Propyl chloride Chlorobenzene. Bromobenzene. a-bromnaphthalene Ethyl ether. , Ethylisoamyl ether Phenetol.. . Anisol. . . Ethyl acetate. Isobutyl acetate Ethyl benzoate Isobutyl alcohol Ethyl alcohol. Allyl alcohol. Methyl alcohol Benzyl alcohol. Acetone. . . Acetophenone. ... 

With sodium, sodium isoamyl is formed, but in ethereal solution in a stream of carbon dioxide, isobutyl acetic acid results. Mercury di-isoamyl heated with zinc in a sealed tube for thirty-six hours at 180° C. yields zinc di-isoamyl. The mercury compound and glacial acetic acid heated for sixteen hours at 200° C. give isopentane, metallic mercury, and amyl acetate. Treatment with thallic chloride gives isoamyl mercuric chloride and thallous chloride. ... 

Isobutyl acetate [110-19-0] is a colorless, neutral liquid with a pleasant, fruity odor. It is miscible with organic solvents, but immiscible with water. Isobutyl acetate has a high solvency for cellulose nitrate, colophony, damar resin, ketone and ketone-formaldehyde resins, maleate resins, urea and melamine resins, and phenolic and alkyd resins. Polymers such as polystyrene, poly(vinyl ethers), poly(vinyl acetate), polyacrylates, chlorinated rubber and vinyl chloride copolymers, as well as fats, greases, and oils are readily dissolved. Postchlorinated poly(vinyl chloride) is less soluble. Polyisobutene, cellulose ethers, polymethacrylates, poly(vinyl butyrals), natural rubber, and manila copal are swollen. Shellac, cellulose acetate, cellulose acetobutyrate, poly(vinyl chloride), and poly(vinyl formal) are insoluble. 

Furfural 4-Heptanone 2-Hexanone Isoamyl acetate Isoamyl chloride Isobutyl acetate Isopropyl acetate 3-Methoxybutanol Methoxybutyl acetate Methoxyethanol... 

Dimethyl phthalate 1,4-Dioxane Dipropylene glycol dimethyl ether Dipropylene glycol ethyl ether Erucamide Ethoxydiglycol Ethoxyethanol acetate Ethyl acetate 2-Ethyl-1-butanol Ethyl chloride Ethylene carbonate Ethylene chlorohydrin Ethylene glycol diacetate Ethylene glycol isopropyl ether Ethylene glycol propyl ether 2-Ethyl hexanol 2-Ethyl hexyl acetate Ethyl morpholine Furan Furfuryl alcohol Heptane 4-Heptanone 2-Hexanone Isoamyl acetate Isoamyl alcohol Isobutyl acetate Isocetyl salicylate Isooctyl alcohol Isophorone 2-lsopropoxy-1-propanol Isopropyl alcohol Isopropyl ether ... 

Ethyl-(S)-lactate Isoamyl chloride Isobutyl acetate Methoxyethanol Methyl abietate Methyl ethyl ketone Methyl isobutyl ketone Methyl propionate 2-Nitropropane Propyl propionate... 

Isoamyl acetate see 3-Methylbutyl ethanoate Isoamyl alcohol see 3-Methylbutan-l-ol heta.-Isoamylene see 2-Methylbut-2-ene Isohutane see 2-Methylpropane Isohutanoic acid see 2-Methylpropanoic acid Isohutanol see 2-Methylpropan-l-ol Isobutene see 2-Methylpropene Isobutyl acetate see 2-Methylpropyl ethanoate Isobutyl alcohol see 2-Methylpropan-l-ol Isobutylbenzene see (2-Methylpropyl)benzene Isobutyl chloride see l-Chloro-2-methylpropane Isobutylene see 2-Methylpropene Isobutylene oxide see 2,2-Dimethyloxirane Isobutyl ethanoate see 2-Methylpropyl ethanoate Isobutyl methyl ketone see 4-Methylpentan-2-one Isobutyraldehyde see 2-Methylpropanal Isobutyric acid see 2-Methylpropanoic acid Isocyanic acid butyl ester see Butyl isocyanate Isohexane see 2-Methylpentane Isooctane see 2,2,4-Tiimethylpentane Isopentane see 2-Methylbutane Isopentanol see 3-Methylbutan-l-ol Isopentyl alcohol see 3-Methylbutan-l-ol Isoprene see 2-Methylbuta-l,3-diene Isopropanol see Propan-2-ol Isopropenylbenzene... 

FIGURE 7 Generic solvent-exchange method, direct injection GC/FID. From bottom to top blank injection and GC volatiles test solution. Peaks I, methanol 2, n-pentane 3, ethanol 4, acetone 5 isopropyl alcohol 6, acetonitrile 7, methyl acetate 8, methylene chloride 9 methyl tertiary butyl ether 10, n-hexane 11, propanol 12, methyl ethyl ketone 13, ethyl acetate 14, sec-butanol 15, tetrahydrofuran 16, cyclohexane 17, hexamethyidisiloxane 18, benzene 19, n-heptane 20, butyl alcohol 21, 1,4-dioxane 22, methyl isobutyl ketone 23, pyridine 24, toluene 25, isobutyl acetate 26, n-butyl acetate 27, p-xylene 28, dimethylacetamide 29, solvent impurities. 

Anhydrous stannous chloride, a water-soluble white soHd, is the most economical source of stannous tin and is especially important in redox and plating reactions. Preparation of the anhydrous salt may be by direct reaction of chlorine and molten tin, heating tin in hydrogen chloride gas, or reducing stannic chloride solution with tin metal, followed by dehydration. It is soluble in a number of organic solvents (g/100 g solvent at 23°C) acetone 42.7, ethyl alcohol 54.4, methyl isobutyl carbinol 10.45, isopropyl alcohol 9.61, methyl ethyl ketone 9.43 isoamyl acetate 3.76, diethyl ether 0.49, and mineral spirits 0.03 it is insoluble in petroleum naphtha and xylene (2). 

Acetone, methyl ethyl ketone, methyl isobutyl ketone, dimethylformamide, ethyl acetate, and tetrahydrofuran are solvents for vinyhdene chloride polymers used in lacquer coatings methyl ethyl ketone and tetrahydrofuran are most extensively employed. Toluene is used as a diluent for either. Lacquers prepared at 10—20 wt % polymer sohds in a solvent blend of two parts ketone and one part toluene have a viscosity of 20—1000 mPa-s (=cP). Lacquers can be prepared from polymers of very high vinyhdene chloride content in tetrahydrofuran—toluene mixtures and stored at room temperature. Methyl ethyl ketone lacquers must be prepared and maintained at 60—70°C or the lacquer forms a sohd gel. It is critical in the manufacture of polymers for a lacquer apphcation to maintain a fairly narrow compositional distribution in the polymer to achieve good dissolution properties. 

In addition to homopolymers of varying molecular and particle structure, copolymers are also available commercially in which vinyl chloride is the principal monomer. Comonomers used eommercially include vinyl acetate, vinylidene chloride, propylene, acrylonitrile, vinyl isobutyl ether, and maleic, fumaric and acrylic esters. Of these the first three only are of importance to the plastics industry. The main function of introducing comonomer is to reduce the regularity of the polymer structure and thus lower the interchain forces. The polymers may therefore be proeessed at much lower temperatures and are useful in the manufacture of gramophone records and flooring compositions. 

Hexone (methyl isobutyl ketone) sec-Hexyl acetate Hydrazine Hydrogen chloride... 

J361 to over 5700, mw — 38000—600000, colorl, amorph or cryst, mp 240—250°, d (amorph) 1.04—1.065g/cc RI 1.59—1.60. Sol in CCI4, et benz, tol, et acet, benz, methyl et ketone, chlf, tetrahydrofuran, methyl isobutyl ketone, methylene chloride, o-dichlorobenz, py and cyclohexane. Styrene polymer can be prepd in many ways. The simplest procedure is that of heating the pure monomer. The general reaction can be represented as ... 

Dermal Effects. Skin irritation was noted in wildlife officers at the RMA after they handled sick or dead ducks without gloves (NIOSH 1981). Although the investigators concluded that diisopropyl methylphosphonate contributed to the local effects, a number of other compounds were present. Analysis of the pond water indicated the presence of a number of organic and inorganic contaminants, including diisopropyl methylphosphonate (11.3 ppm) aldrin (0.368 ppm) dieldrin (0.0744 ppm) dicyclo-pentadiene, bicycloheptadiene, diethyl benzene, dimethyl disulfide, methyl acetate, methyl isobutyl ketone, toluene, and sodium (49,500 ppm) chloride (52,000 ppm) arsenic (1,470 ppm) potassium (180 ppm) fluoride (63 ppm) copper (2.4 ppm) and chromium (0.27 ppm). Because of the presence of numerous compounds, it is unclear whether diisopropyl methylphosphonate was related to the irritation. 

St styrene, MMA methyl methacrylate, IB isobutene, VAc vinyl acetate, VC1 vinyl chloride, DiPF diisopropyl fumarate, AA acrylic acid, MAn maleic anhydride, IBVE isobutyl vinyl ether. 

Commonly used solvents inclnde liqnid carbon dioxide, propane, bntane, light oil, triethy-lamine, acetone, methanol, hexane, dimethyl ether, cmde oil, benzene, isopropyl ether, toluene, tricresyl phosphate, methyl isobutyl ketone, methyl chloride, and bntyl acetate. In addition to remediation uses, solvent extraction has been applied in a variety of indnstries, including food processing, pharmaceuticals, fine chemicals, and mining and minerals processing. 

An example of CO2 enhanced aqueous extraction is shown in Figure 7 for tetrabutylammonium picrate (TBAP). Three common solvents for PTC butyl acetate, methyl isobutyl ketone (MIBK) and methylene chloride were used as the organic phase. 

Figure 7. TBAP distribution coefficient as a function of CO2 pressure at room temperature (23-25 °C). Organic solvents used butyl acetate, methyl isobutyl ketone and methylene chloride. 20 mL 8.770 x 10 M TBAP aqueous solution, 20 mL organic solvent (17).

Fusion of 2-methylpyrido[2,3- [l>3]oxazin -one 555 with ammonium acetate, hydrazine hydrate, benzylamine, and aniline in the presence of anhydrous zinc chloride at 150-160 °C gave the pyrido[2,3-. Also, amination of the 2-isopropyl or isobutyl analogues of 555 (R = = H) with benzylamine in ethylene glycol... 

In order to shorten the reaction time, various heavy metal salts (zinc, lead, and manganese acetates) of weak organic acids, zinc or cobalt and tin chlorides are added to the reaction mixture [11]. For example, refluxing an uncatalyzed mixture of 3 moles of isobutyl alcohol and urea for 150 hr at 108°-126°C gives a 49% yield of the carbamate. Adding lead acetate or cobalt chloride to the same reaction lowers the reaction time to 75 hr, at which point an 88-92 % yield is obtained. In another example, ethylene glycol (1 mole) and urea (2 moles) are heated for 3 hr at 135°-155°C with Mn(OAc)2 to give a 78% yield of the diurethane [11]. The commercial production of butyl carbamate uses catalytic quantities of cupric acetate [12]. 

Methyl chloride Methylcyclohexanol 5-Methyl-3-heptanone Methyl acetate Methyl acrylate Methyl bromide Methyl cellosolve Methyl cellosolve acetate Methyl chloroform Methyl iodide Methyl isoamyl acetate Methyl isobutyl carbinol... 

Methyl alcohol (6) Methylene chloride (5) Methyl ethyl ketone (8) Methyl ethyl ketone (8) Methyl isobutyl ketone (8) Vinyl acetate (inhibited) (14) Caustic soda solution (3) Caustic soda solution (3) Furfural (7) Caustic soda solution (3)... 

Chemicals and Standard Solutions. Cyclohexanone, cyclohexanol, 1,3,5-trichlorobenzene, 1,2,4-trichlorobenzene, phenol, 4-methylphenol, 4-chloro-phenol, 1,2,3,4-tetrahydroisoquinoline, 1-chlorohexane, 1-chlorododecane, and 1-chlorooctadecane were obtained from Aldrich. Acetone, tetrahydrofuran, ethyl acetate, toluene, dimethyl sulfoxide, and methanol were obtained from J. T. Baker. Distilled-in-glass isooctane, methylene chloride, ethyl ether, and pentane were obtained from Burdick and Jackson. Analytical standard kits from Analabs provided methyl ethyl ketone, isopropyl alcohol, ethanol, methyl isobutyl ketone, tetrachloroethylene, dodecane, dimethylformamide, 1,2-dichlorobenzene, 1-octanol, nitrobenzene, 2,4-dichlorophenol, and 2,5-dichlorophenol. All chemicals obtained from the vendors were of the highest purity available and were used without further purification. High-purity water... 

Note Column headings key 135-TCB 1,3,5-trichlorobenzene 124-TCB 1,2,4-trichlorobenzene TCEE tetrachloroethylene MECL2 methylene chloride CHOL cyclohexanol ACET acetone NO2 benzene nitrobenzene MIBK methyl isobutyl ketone CHONE cyclohexanone DCB 1,2-dichlorobenzene THIQ 1,2,3,4-tetrahydroisoquinoline p-CLPHEN 4-chlorophenol THF tetrahydrofuran 24DCLPHEN 2,4-dichlorophenol 25DCLPHEN 2,5-dichlorophenol. 

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