Fuel gases

Gaseous fuels. Gas burners can be diffusion flame burners or pre-aeraled burners. Diffusion flame burners may be relatively simple, with fuel gas burning at an orifice in the presence of... 

In refining, the oligomerization process produces gasoline from C3 fractions containing approximately 75% propylene or fuel-gas containing ethylene and propylene. 

This process thus enables gasoline production to be increased if the propylene can not be used for petrochemical manufacture. It recovers ethylene economically from fuel-gas. 

Feedstocks Propylene fraction from FCC Fuel gas from FCC... 

Feedstocks are natural gas, refinery fuel gas, LPG and paraffinic naphthas. After elimination of CO2, the last traces of contaminants are converted to methane (methanation) or eliminated by adsorption on molecular sieves (PSA process). 

Hydrogen sulfide concentrates in refinery off gases. Before being used as fuel gas, the gas undergoes an amine (MEA, DEA, etc.) washing step in order to extract the H2S. 

In some undersaturated reservoirs with non commercial quantities of gas but too much to flare, gas has be used to fuel gas turbines and generate electricity for local use. 

Fuel economy Fuel-fired furnaces Fuel gas Fuel oil... 

Gas turbine Gas-turbine engines Gas turbine fuel Gas turbines... 

A viable electrocatalyst operating with minimal polarization for the direct electrochemical oxidation of methanol at low temperature would strongly enhance the competitive position of fuel ceU systems for transportation appHcations. Fuel ceUs that directiy oxidize CH OH would eliminate the need for an external reformer in fuel ceU systems resulting in a less complex, more lightweight system occupying less volume and having lower cost. Improvement in the performance of PFFCs for transportation appHcations, which operate close to ambient temperatures and utilize steam-reformed CH OH, would be a more CO-tolerant anode electrocatalyst. Such an electrocatalyst would reduce the need to pretreat the steam-reformed CH OH to lower the CO content in the anode fuel gas. Platinum—mthenium alloys show encouraging performance for the direct oxidation of methanol. 

This gas is of interest to industry as a fuel gas or even, on occasion, as a raw material from which ammonia and other compounds may be synthesized. 

The first gas producer making low heat-value gas was built in 1832. (The product was a combustible carbon monoxide—hydrogen mixture containing ca 50 vol % nitrogen). The open-hearth or Siemens-Martin process, built in 1861 for pig iron refining, increased low heat-value gas use (see Iron). The use of producer gas as a fuel for heating furnaces continued to increase until the turn of the century when natural gas began to supplant manufactured fuel gas (see Furnaces, fuel-fired). 

The importance of coal gasification as a means of produciag fuel gas(es) for iadustrial use caimot be underplayed. But coal gasification systems also have undesirable features. A range of undesirable products are also produced which must be removed before the products are used to provide fuel and/or to generate electric power (see Power generation) (22,41). 

Methanol, a clean burning fuel relative to conventional industrial fuels other than natural gas, can be used advantageously in stationary turbines and boilers because of its low flame luminosity and combustion temperature. Low NO emissions and virtually no sulfur or particulate emissions have been observed (83). Methanol is also considered for dual fuel (methanol plus oil or natural gas) combustion power boilers (84) as well as to fuel gas turbines in combined methanol / electric power production plants using coal gasification (85) (see Power generation). 

Natural gas upgra ding economics may be affected by additional factors. The increasing use of compressed natural gas (CNG) directiy as fuel in vehicles provides an alternative market which affects both gas price and value (see Gasoline and other motor fuels Gas, natural). The hostility of the remote site environment where the natural gas is located may contribute to additional costs, eg, offshore sites require platforms and submarine pipelines. 

Hexane refers to the straight-chain hydrocarbon, C H branched hydrocarbons of the same formula are isohexanes. Hexanes include the branched compounds, 2-methylpentane, 3-methylpentane, 2,2-dimethylbutane, 2,3-dimethylbutane, and the straight-chain compound, / -hexane. Commercial hexane is a narrow-boiling mixture of these compounds with methylcyclopentane, cyclohexane, and benzene (qv) minor amounts of and hydrocarbons also may be present. Hydrocarbons in commercial hexane are found chiefly in straight-mn gasoline which is produced from cmde oil and natural gas Hquids (see Gasoline AND OTHER MOTOR fuels Gas,natural). Smaller volumes occur in certain petroleum refinery streams. 

Low Temperature Carbonization. The Lurgi Sptlgas process was developed to carbonize brown coal at relatively low temperatures to produce tars and oils (Fig. 5). A shaft furnace internally heated by process-derived fuel gas (Spblgas) is used. The product can range from a friable coke breeze to hard lump coal depending on the quality of the briquettes used in the feed. The briquettes, made in normal extmsion presses, break down into smaller sizes during carbonization. 

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