Additive factor

The inset in Figure XIV-6 shows the coalescence time tc for the droplets for the pH corresponding to each DLVO curve. Does DLVO theory adequately explain the variation of tc with pH What additional factors may play a role ... 

An advantage of Eq. (90) for computational purposes is that the solutions are subject to single-valued boundary conditions. It is also readily verified that inclusion of an additional factor qjj the right-hand side of Eq. (89) adds a... 

Replacing the nuclear and electronic momenta by the modifications shown above in the kinetic energy terms of the full electronic and nuclear-motion hamiltonian results in the following additional factors appearing in H ... 

Finally, we note that the size and shape of the particles of the packing, the packing technique, and column dimensions and configuration are additional factors which influence a GPC experiment. In addition, the flow rate, the sample size, the sample concentration, the solvent, and the temperature must all be optimized. Details concerning these considerations are found in analytical chemistry references, as well as in the technical literature of instrument manufacturers. 

Natural gas upgra ding economics may be affected by additional factors. The increasing use of compressed natural gas (CNG) directiy as fuel in vehicles provides an alternative market which affects both gas price and value (see Gasoline and other motor fuels Gas, natural). The hostility of the remote site environment where the natural gas is located may contribute to additional costs, eg, offshore sites require platforms and submarine pipelines. 

Initiators. The degree of polymerization is controlled by the addition rate of initiator(s). Initiators (qv) are chosen primarily on the basis of half-life, the time required for one-half of the initiator to decay at a specified temperature. In general, initiators of longer half-Hves are chosen as the desired reaction temperature increases they must be well dispersed in the reactor prior to the time any substantial reaction takes place. When choosing an initiator, several factors must be considered. For the autoclave reactor, these factors include the time permitted for completion of reaction in each zone, how well the reactor is stirred, the desired reaction temperature, initiator solubiUty in the carrier, and the cost of initiator in terms of active oxygen content. For the tubular reactors, an additional factor to take into account is the position of the peak temperature along the length of the tube (9). 

Phosphorothioates generally protect normal tissues more than tumors. Tumor protection reported in some animal studies can pardy be explained by physiological effects of the particular dmgs, which are specific to rodents (4). WR-2721 does not appear to protect human and most animal tumors, apparentiy because of the low availabiUty of the dmg to tumor cells (4). Many tumors appear to have a reduced capillary density (44), which may mean that these tumors have altered levels of alkaline phosphatase, the enzyme that converts WR-2721 to WR-1065. A reduced abiUty of thiols to protect the hypoxic cells characteristic of many tumors may also contribute to their selectivity for normal tissues. The observation that WR-1065 protects cultured normal human fibroblasts, but not fibrosarcoma tumor cells, suggests that additional factors may contribute to the selectivity of radioprotection by WR-2721 m vivo (18). 

Watei has an unusually high (374°C) ctitical tempeiatuie owing to its polarity. At supercritical conditions water can dissolve gases such as O2 and nonpolar organic compounds as well as salts. This phenomenon is of interest for oxidation of toxic wastewater (see Waste treatments, hazardous waste). Many of the other more commonly used supercritical fluids are Hsted in Table 1, which is useful as an initial screening for a potential supercritical solvent. The ultimate choice for a specific appHcation, however, is likely to depend on additional factors such as safety, flammabiUty, phase behavior, solubiUty, and expense. 

Theie aie several additional factors that must be considered in selecting pigments for a specific coating application (40). These factors include processing stabihty requirements, pigment uniformity and reproducibiUty, particle size distribution, dispersibiUty, and compatibiUty of all materials to be used. 

Thickener control philosophies are usually based on the idea that the Iindertlow density obtained is the most important performance criterion. The o ertlow clarity is also a consideration, but this is generally not as critical. Additional factors which must be considered are optimization of tlocciilant usage and protection of the raking mechanism. 

These methods of classification are not mutually exclusive. Thus filters usually are divided first into the two groups of cake and clarifying equipment, then into groups of machines using the same land of driving force, then further into batch and continuous classes. This is the scheme of classification underlying the discussion of filters of this subsection. Within it, the other aspects of operating cycle, the nature of the sohds, and additional factors (e.g., types and classification of filter media) will be treated explicitly or implicitly. 

Mass-transfer coefficients seem to vary as the 0.7 exponent on the power input per unit volume, with the dimensions of the vessel and impeller and the superficial gas velocity as additional factors. A survey of such correlations is made by van t Riet (Ind Eng. Chem Proc Des Dev., IS, 3.57 [1979]). Table 23-12 shows some of the results. 

The temperature is approximately 20°F below the 265°F temperature limit. The sections differ by less than 1 F. This is probably just luck because that good a balance is not really necessary. Also, it should be noted that to maintain simplicity the additional factors were ignored, such as the 10°F temperature pickup in the return stream due to internal wall heat transfer. Also, nozzle pressure drops for the exit and return were not used. Balance piston leakage was not used as it was in Example 5-3. When all the factors are used, the pressures for each section would undoubtedly need additional adjustment as would the efficiency. However, for the actual compression process, the values are quite realistic, and for doing an estimate, this simpler approach may be quite adequate,... 

It is not unusual to find more than one compressor suited to the job. Additional factors, such as inherent reliability and efficiency of the v arious types, should be considered. First cost will be an unavoidable factor that must be addressed. If, after consideration of all pertinent factors, there is still an overlap, then it may be advisable to inquire about more than one type of compressor. Normally this doesn t happen, because once the types are reviewed, some factor sways the decision. If, however, more than one compressor will be inquired, a specification should be prepared for each. It is quite difficult to write a comprehensive multipurpose specification. While there are some areas that will be the same, a repeat of each document will make evaluation much easier and cleaner later on... 

Further substitution can introduce additional factors, especially nonbonded repulsions, which influence conformational equilibria. For example, methyl substitution at C—2, as in 2-methyl-l-butene, introduces a methyl-methyl gauche interaction in the conformation analogous to B, with the result that in 2-methyl-l-butene the two eclipsed conformations are of approximately equal energy. Increasing the si2e of the group at... 

Now you can reconsider the material balance equations by adding those additional factors identified in the previous step. If necessary, estimates of unaccountable losses will have to be calculated. Note that, in the case of a relatively simple manufacturing plant, preparation of a preliminary material-balance system and its refinement (Steps 14 and 15) can usefully be combined. For more-complex P2 assessments, however, two separate steps are likely to be more appropriate. An important rule to remember is that the inputs should ideally equal the outputs - but in practice this will rarely be the case. Some judgment will be required to determine what level of accuracy is acceptable, and we should have an idea as to what the unlikely sources of errors are (e.g., evaporative losses from outside holding ponds may be a materials loss we cannot accurately account for). In the case of high concentrations of hazardous wastes, accurate measurements are needed to develop cost-effective waste-reduction options. It is possible that the material balance for a number of unit operations will need to be repeated. Again, continue to review, refine, and, where necessary, expand your database. The compilation of accurate and comprehensive data is essential for a successful P2 audit and subsequent waste-reduction action plan. Remember - you can t reduce what you don t know is therel... 

In this formula, P is present worth or present value, F is future value, i is the interest or discount rate, and n is the number of periods. Economically, there is an additional factor at work in present value, and that factor is pure time preference, or impatience. However, this issue is generally ignored in business accounting, because the firm has no such emotions, and opportunities can be measured in terms of financial return. 

The preceding section described the state of transition expected in a deflagration process when the mixture in front of the flame is sufficiently preconditioned by a combination of compression effects and local quenching by turbulent mixing. However, additional factors determine whether the onset of detonation can actually occur and whether the onset of detonation will be followed by a self-sustaining detonation wave. 

However, such strategies are vulnerable to additional factors such as increased time pressure, and working alone. The combined influences of such factors may be more important than each negative factor in isolation. 

Additional factors influencing column performance are the type and quality of the packing process, which mainly determines the theoretical plate count (N) of the column. In contrast to HPLC columns the efficiency of the separation itself is determined predominantly by the quality of the sorbent alone (pore... 

H)-diones although the latter appears less probable. Additional factors, such as the cyclization of the first-formed ring-opened products with a 5-ethoxycarbonyl group are often important. ... 

It has been satisfactorily demonstrated by Henning that the vapours of odoriferous substances obey the general gas laws, and there is consequently no need to assume any additional factor of the nature of specific solubility. 

For crossflow designs the additional factor of the horizontal depth of packing has to be included in the basic calculations. The accuracy of the design is directly related to the number of calculations in the selection program. Whereas counterflow can be dealt with as a single entity, crossflow has to cope with the changes that occur at every level of pack, both vertically and horizontally. 

The thermodynamic driving force behind the corrosion process can be related to the corrosion potential adopted by the metal while it is corroding. The corrosion potential is measured against a standard reference electrode. For seawater, the corrosion potentials of a number of constructional materials are shown in Table 53.1. The listing ranks metals in their thermodynamic ability to corrode. Corrosion rates are governed by additional factors as described above. 

There are two types of flexible intermediate drives used to transmit torsional power belt drives and chain drives. Flexible belts are used in industrial power transmission applications primarily when the speeds of the driver and driven shafts must be different or when the shafts must be widely separated. The trend toward higher speed primary drivers and the need to achieve a slower, useful driven speed are additional factors favoring the use of belts. In addition to V-belts, there are round belts and flat belts. Chain drives are typically used in applications where space is limited or obstructions prevent direct coupling of machine-train components. 

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