Ethylene cellulosics

Collectors. Oleic acid, mixtures of oleic and linolic acid, sodium oleat, tall oil, saponified tall oil and mixtures of these substances, coriander oil, rape oil, mustard oil, pyridine base, water-soluble carbohydrates of the green oil type, also in saponated form, fatty acids and their salts, fish oil, hydroxy-ethylene-cellulose, carboxy-methyl-cellulose. 

Extraction of lignocellulosic materials and biomass CO2, SO2, N2O, H2O, methylamine, ethanol, ethylene Cellulose or ligno-cellulosic materials from wood or wood pulp... 

Fluorinated ethylene-propylene resin Poly(vinylidene fluoride) Ethylene-tetrafluoroethylene copolymer Ethylene- chlorotrifluoro- ethylene copolymer Cellulose- filled Glass-fiber- reinforced... 

Figure 3 shows the production of acetaldehyde in the years 1969 through 1987 as well as an estimate of 1989—1995 production. The year 1969 was a peak year for acetaldehyde with a reported production of 748,000 t. Acetaldehyde production is linked with the demand for acetic acid, acetic anhydride, cellulose acetate, vinyl acetate resins, acetate esters, pentaerythritol, synthetic pyridine derivatives, terephthaHc acid, and peracetic acid. In 1976 acetic acid production represented 60% of the acetaldehyde demand. That demand has diminished as a result of the rising cost of ethylene as feedstock and methanol carbonylation as the preferred route to acetic acid (qv). 

Pentaerythritol in rosin ester form is used in hot-melt adhesive formulations, especially ethylene—vinyl acetate (EVA) copolymers, as a tackifier. Polyethers of pentaerythritol or trim ethyl ol eth an e are also used in EVA and polyurethane adhesives, which exhibit excellent bond strength and water resistance. The adhesives maybe available as EVA melts or dispersions (90,91) or as thixotropic, one-package, curable polyurethanes (92). Pentaerythritol spko ortho esters have been used in epoxy resin adhesives (93). The EVA adhesives are especially suitable for cellulose (paper, etc) bonding. 

Water-Soluble Films. Water-soluble films can be produced from such polymers as poly(vinyl alcohol) (PVOH), methylceUulose, poly(ethylene oxide), or starch (qv) (see Cellulose ethers Polyethers Vinyl polymers). Water-soluble films are used for packaging and dispensing portions of detergents, bleaches, and dyes. A principal market is disposable laundry bags for hospital use. Disposal packaging for herbicides and insecticides is an emerging use. 

The white cell adsorption filter layer is typically of a nonwoven fiber design. The biomaterials of the fiber media are surface modified to obtain an optimal avidity and selectivity for the different blood cells. Materials used include polyesters, eg, poly(ethylene terephthalate) and poly(butylene terephthalate), cellulose acetate, methacrylate, polyamides, and polyacrylonitrile. Filter materials are not cell specific and do not provide for specific filtration of lymphocytes out of the blood product rather than all leukocytes. 

Polymers. Hydrocarbons from petroleum and natural gas serve as the raw material for virtually all polymeric materials commonly found in commerce, with the notable exception of rayon which is derived from cellulose extracted from wood pulp. Even with rayon, however, the cellulose is treated with acetic acid (qv), much of which is manufactured from ethylene (see Fibers, regenerated cellulosics). 

Other Polymers. Besides polycarbonates, poly(methyl methacrylate)s, cycfic polyolefins, and uv-curable cross-linked polymers, a host of other polymers have been examined for their suitabiUty as substrate materials for optical data storage, preferably compact disks, in the last years. These polymers have not gained commercial importance polystyrene (PS), poly(vinyl chloride) (PVC), cellulose acetobutyrate (CAB), bis(diallylpolycarbonate) (BDPC), poly(ethylene terephthalate) (PET), styrene—acrylonitrile copolymers (SAN), poly(vinyl acetate) (PVAC), and for substrates with high resistance to heat softening, polysulfones (PSU) and polyimides (PI). 

Hydroxyethyl cellulose (HEC), a nonionic thickening agent, is prepared from alkali cellulose and ethylene oxide in the presence of isopropyl alcohol (46). HEC is used in drilling muds, but more commonly in completion fluids where its acid-degradable nature is advantageous. Magnesium oxide stabilizes the viscosity-building action of HEC in salt brines up to 135°C (47). HEC concentrations are ca 0.6—6 kg/m (0.2—21b/bbl). 

Polymer Blends. The miscibility of poly(ethylene oxide) with a number of other polymers has been studied, eg, with poly (methyl methacrylate) (18—23), poly(vinyl acetate) (24—27), polyvinylpyrroHdinone (28), nylon (29), poly(vinyl alcohol) (30), phenoxy resins (31), cellulose (32), cellulose ethers (33), poly(vinyl chloride) (34), poly(lactic acid) (35), poly(hydroxybutyrate) (36), poly(acryhc acid) (37), polypropylene (38), and polyethylene (39). 

Other blends such as polyhydroxyalkanoates (PHA) with cellulose acetate (208), PHA with polycaprolactone (209), poly(lactic acid) with poly(ethylene glycol) (210), chitosan and cellulose (211), poly(lactic acid) with inorganic fillers (212), and PHA and aUphatic polyesters with inorganics (213) are receiving attention. The different blending compositions seem to be limited only by the number of polymers available and the compatibiUty of the components. The latter blends, with all natural or biodegradable components, appear to afford the best approach for future research as property balance and biodegradabihty is attempted. Starch and additives have been evaluated ia detail from the perspective of stmcture and compatibiUty with starch (214). 

Propylene oxide has found use in the preparation of polyether polyols from recycled poly(ethylene terephthalate) (264), haUde removal from amine salts via halohydrin formation (265), preparation of flame retardants (266), alkoxylation of amines (267,268), modification of catalysts (269), and preparation of cellulose ethers (270,271). 

Emulsion polymerizations of vinyl acetate in the presence of ethylene oxide- or propylene oxide-based surfactants and protective coUoids also are characterized by the formation of graft copolymers of vinyl acetate on these materials. This was also observed in mixed systems of hydroxyethyl cellulose and nonylphenol ethoxylates. The oxyethylene chain groups supply the specific site of transfer (111). The concentration of insoluble (grafted) polymer decreases with increase in surfactant ratio, and (max) is observed at an ethoxylation degree of 8 (112). 

Ce = cellulosics, EVA = ethylene-vinyl acetate copolymers, F = foods, GAS = gasoline, LUB = lubricants, PA = polyamides, PES = polyesters,... 

Ethylenediamine (70,71), benzyl alcohol and acetone (72), ethylene glycol (73) and C2—C g carboxyUc acids (74) are claimed to increase the reactivity of cellulose toward acetylation. Sodium hydroxide and Hquid ammonia (71) are excellent swelling agents and have been used to activate cellulose before esterification. Ultrasonic treatment of cellulose slurries (75) reportedly swells the fibers and improves reactivity. 

In one process to produce highly activated cellulose for acetylation, cellulose is treated with NaOH (mercerization) followed by a hydroxyalkylating agent, eg, ethylene oxide or propylene oxide, to give a cellulose hydroxyalkyl ether with a DS of 0.05—0.3 (76). The resulting water-insoluble material is highly reactive to conventional acetic anhydride—sulfuric acid acetylation. 

The manufacturing process for organo-soluble EHEC is similar to that for EC except that alkah cellulose reacts first with ethylene oxide to a low hydroxyethyl MS value of - 0.5 at a low temperature, - 50° C, followed by reaction of the ethyl chloride at a higher temperature. Additional by-products, which are removed during purification, include glycols and the reaction products of the glycols with ethyl chloride (glycol ethers). 

When exposed to heat, cotton fabrics, like most substances, increase in temperature to an extent that is proportional to their specific heats. Altering the chemical composition of the fabrics such that large amounts of heat are absorbed and released in repeatable cycles of controllable temperature ranges produces fabrics that are described as temperature adaptable. The process insolubili2es poly(ethylene glycol)s cross-linked with methylolamides in the cotton fabric (78). As with flame-retardant cellulose, attachment is through an ether linkage to the cellulose at a relatively low DS. 

Cyclohexanoae is miscible with methanol, ethanol, acetone, benzene, / -hexane, nitrobenzene, diethyl ether, naphtha, xylene, ethylene glycol, isoamyl acetate, diethylamine, and most organic solvents. This ketone dissolves cellulose nitrate, acetate, and ethers, vinyl resias, raw mbber, waxes, fats, shellac, basic dyes, oils, latex, bitumea, kaure, elemi, and many other organic compounds. 

Industrial ethyl alcohol can be produced synthetically from ethylene [74-85-17, as a by-product of certain industrial operations, or by the fermentation of sugar, starch, or cellulose. The synthetic route suppHes most of the industrial market in the United States. The first synthesis of ethanol from ethylene occurred in 1828 in Michael Faraday s lab in Cambridge (40). 

Nonionic Surface-Active Agents. Approximately 14% of the ethyleae oxide consumed ia the United States is used in the manufacture of nonionic surfactants. These are derived by addition of ethylene oxide to fatty alcohols, alkylphenols (qv), tall oil, alkyl mercaptans, and various polyols such as poly(propylene glycol), sorbitol, mannitol, and cellulose. They are used in household detergent formulations, industrial surfactant appHcations, in emulsion polymeri2ation, textiles, paper manufacturing and recycling, and for many other appHcations (281). 

Around Izod notch Low-density polyethylene Ethylene-propylene block copolymers Cellulose nitrate and propionate ABS and high-impact polystyrene Bis-phenol A polycarbonate... 

Over the past years considerable attention has been paid to the dispersing system since this controls the porosity of the particle. This is important both to ensure quick removal of vinyl chloride monomer after polymerisation and also to achieve easy processing and dry blendable polymers. Amongst materials quoted as protective colloids are vinyl acetate-maleic anhydride copolymers, fatty acid esters of glycerol, ethylene glycol and pentaerythritol, and, more recently, mixed cellulose ethers and partially hydrolysed polyfvinyl acetate). Much recent emphasis has been on mixed systems. 

An example of the first type is the emulsion stabiliser as exemplified by sodium oleyl sulphate, cetyl pyridinium chloride and poly(ethylene oxide) derivatives. For a number of applications it is desirable that the latex be thickened before use, in which case thickening agents such as water-soluble cellulose ethers or certain alginates or methacrylates may be employed. Antifoams such as silicone oils are occasionally required. 

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