Deposition sensors

The history of electrochemical sensors began in the thirties of the twentieth century, when the pH-sensitive glass electrode was deployed, but no noteworthy development was carried out till the middle of that century. In 1956, Clark invented his oxygen-sensor based on a Ft electrode in 1959, the first piezoelectric mass-deposition sensor (a quartz crystal microbal-ance) was produced. In the sixties, the first biosensors (Clark and Lyons, 1962) and the first metal oxide semiconductor-based gas sensors (Taguchi, 1962) started to appear. 

T. Jantson, T. Avarmaa, H. Mandar, T. Uustare, R. Jaaniso, Nanocrystalhne Ct203-Ti02 thin films by pulsed laser deposition . Sensors and Actuators B Chemical, 109, 24-31, (2005). 

B. Min, S. Choi, Sn02 thin film gas sensor fabricated by ion beam deposition . Sensors and Actuators B Chemical, 98, 239-246, (2004). 

Piezoelectric mass deposition sensor (quartz crystal microbalance)... 

Gourari, H., Lumbreras, M., Van Landschoot, R. and Schoonman, X, Electrode nature effects on stannic oxide type layers prepared by electrostatic spray deposition , Sensor Actual B, 1999,58,365-9. 

Yang, J. Y. and Martin, D. C. (2004) Microporous conducting polymers on neural microelectrode arrays - i - electrochemical deposition. Sensors and Actuators B Chemical 101,133-42. 

A unique but widely studied polymeric LB system are the polyglutamates or hairy rod polymers. These polymers have a hydrophilic rod of helical polyglutamate with hydrophobic alkyl side chains. Their rigidity and amphiphilic-ity imparts order (lyotropic and thermotropic) in LB films and they take on a F-type stmcture such as that illustrated in Fig. XV-16 [182]. These LB films are useful for waveguides, photoresists, and chemical sensors. LB films of these polymers are very thermally stable, as was indicated by the lack of interdiffusion up to 414 K shown by neutron reflectivity of alternating hydrogenated and deuterated layers [183]. AFM measurements have shown that these films take on different stmctures if directly deposited onto silicon or onto LB films of cadmium arachidate [184]. 

Functionalized conducting monomers can be deposited on electrode surfaces aiming for covalent attachment or entrapment of sensor components. Electrically conductive polymers (qv), eg, polypyrrole, polyaniline [25233-30-17, and polythiophene/23 2JJ-J4-j5y, can be formed at the anode by electrochemical polymerization. For integration of bioselective compounds or redox polymers into conductive polymers, functionalization of conductive polymer films, whether before or after polymerization, is essential. In Figure 7, a schematic representation of an amperomethc biosensor where the enzyme is covalendy bound to a functionalized conductive polymer, eg, P-amino (polypyrrole) or poly[A/-(4-aminophenyl)-2,2 -dithienyl]pyrrole, is shown. Entrapment of ferrocene-modified GOD within polypyrrole is shown in Figure 7. 

Acoustic Wave Sensors. Another emerging physical transduction technique involves the use of acoustic waves to detect the accumulation of species in or on a chemically sensitive film. This technique originated with the use of quartz resonators excited into thickness-shear resonance to monitor vacuum deposition of metals (11). The device is operated in an oscillator configuration. Changes in resonant frequency are simply related to the areal mass density accumulated on the crystal face. These sensors, often referred to as quartz crystal microbalances (QCMs), have been coated with chemically sensitive films to produce gas and vapor detectors (12), and have been operated in solution as Hquid-phase microbalances (13). A dual QCM that has one smooth surface and one textured surface can be used to measure both the density and viscosity of many Hquids in real time (14). 

Optical Coatings. Thin surface coatings are appHed to optical components to improve performance. Wideband antireflection coatings for the visible and ir regions need materials with a refractive iadex of for the best efficieacy. Cerium fluoride, a stable material resistant to humidity damage, has a suitable iadex, 1.63 ia the visible, 1.59 ia the iafrared, and is transparent over the range 0.5 p.m to 5 p.m. It is one of the compounds used to build up the multilayers deposited on lenses, sensors, and the like. 

Entrapment of biochemically reactive molecules into conductive polymer substrates is being used to develop electrochemical biosensors (212). This has proven especially useful for the incorporation of enzymes that retain their specific chemical reactivity. Electropolymerization of pyrrole in an aqueous solution containing glucose oxidase (GO) leads to a polypyrrole in which the GO enzyme is co-deposited with the polymer. These polymer-entrapped GO electrodes have been used as glucose sensors. A direct relationship is seen between the electrode response and the glucose concentration in the solution which was analyzed with a typical measurement taking between 20 to 40 s. 

Nowadays all over the world considerable attention is focused on development of chemical sensors for the detection of various organic compounds in solutions and gas phase. One of the possible sensor types for organic compounds in solutions detection is optochemotronic sensor - device of liquid-phase optoelectronics that utilize effect of electrogenerated chemiluminescence. In order to enhance selectivity and broaden the range of detected substances the modification of working electrode of optochemotronic cell with organic films is used. Composition and deposition technique of modifying films considerably influence on electrochemical and physical processes in the sensor. 

Canada, and Mexico (23). The National Atmospheric Deposition Program has established the nationwide sampling network of —100 stations in the United States. The sampler is shown in Fig. 14-9 with a wet collection container. The wet collection bucket is covered with a lid when it is not raining. A sensor for rain moves the lid to open the wet collector bucket and cover the dry bucket at the beginning of a rainstorm. This process is reversed when the rain stops. 

The chemical and electronic properties of elements at the interfaces between very thin films and bulk substrates are important in several technological areas, particularly microelectronics, sensors, catalysis, metal protection, and solar cells. To study conditions at an interface, depth profiling by ion bombardment is inadvisable, because both composition and chemical state can be altered by interaction with energetic positive ions. The normal procedure is, therefore, to start with a clean or other well-characterized substrate and deposit the thin film on to it slowly at a chosen temperature while XPS is used to monitor the composition and chemical state by recording selected characteristic spectra. The procedure continues until no further spectral changes occur, as a function of film thickness, of time elapsed since deposition, or of changes in substrate temperature. 

Recent applications of e-beam and HF-plasma SNMS have been published in the following areas aerosol particles [3.77], X-ray mirrors [3.78, 3.79], ceramics and hard coatings [3.80-3.84], glasses [3.85], interface reactions [3.86], ion implantations [3.87], molecular beam epitaxy (MBE) layers [3.88], multilayer systems [3.89], ohmic contacts [3.90], organic additives [3.91], perovskite-type and superconducting layers [3.92], steel [3.93, 3.94], surface deposition [3.95], sub-surface diffusion [3.96], sensors [3.97-3.99], soil [3.100], and thermal barrier coatings [3.101]. 

The sensor usually consists of a coil of wire made from the material that is wound on a former and the whole sealed to prevent oxidization, although a film of the metal deposited on a ceramic substrate can also be used. The resistor is connected in a Wheatstone bridge network (Figure 17.17), using fixed resistors in the other three arms. The instrument connected across the bridge is calibrated directly in terms of temperature. The range is limited by the linearity of the device and the upper temperature, which can be measured, must be well below the melting point of the material. 

Schubert J, Schdning MJ, Schmidt C, Siegert M, Mesters St, Zander W, Kordos P, Liith H, Legin A, Mourzina YG, Seleznev B, Vlasov YG (1999) Chalcogenide-based thin film sensors prepared by pulsed laser deposition technique. Appl Phys A Mater Sci Process 69 803-805... 

The sensor ch consists of a glass de on to which a SO-nm thick gold film has been deposited. The gold film is then covered with a linker-layer to which a matrix of carboxylated dextran is attached. The dextran, which extends typically 100 nm out fi om the sur6ce, provides a hydrophilic, activatable and flexible polymer to which biomolecules can be coupled throu amine, sulphydryl, carboxyl and other groups. 

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