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Coordinating polymer

A Macromolecular Division of lUPAC was created in 1967, and it created a permanent Commission on Macromolecular Nomenclature, parallel to the other nomenclature commissions. The Commission over the years has issued recommendations on basic definitions, stereochemical definitions and notations, stmcture-based nomenclature for regular single-strand organic polymers and regular single-strand and quasisingle-strand inorganic and coordination polymers, source-based nomenclature for copolymers, and abbreviations for polymers. AH of these are coUected in a compendium referred to as the lUPAC Purple Book (99). [Pg.120]

Coordination polymers with inorganic main chains. S. V. Vinogradova and O. V. Vinogradova Russ. Chem. Rev. (Engl. Transl.), 1975, 44, 510-521 (125). [Pg.59]

Organometallic coordination polymers involving alkoxo- and alkylamido-bridges. D. C. Bradley, Inorg. Macromol. Rev., 1970, 1,141-157 (59). [Pg.64]

This review deals with the chemistry and coordination complexes of isoelectronic analogues of common oxo-anions of phosphorus such as PO3, POl", RPOl" and R2POy. The article begins with a discussion of homoleptic systems in which all of the 0x0 ligands are replaced by imido (NR) groups. This is followed by an account of heteroleptic phosphorus-centered anions, including [RN(E)P(/<-NR )2P(E)NR]2-, [EP(NR)3]3-, [RP(E)(NR)2] and [R2P(E)(NR )] (E=0,S, Se, Te). The emphasis is on the wide variety of coordination modes exhibited by these poly-dentate ligands, which have both hard (NR) and soft (S, Se or Te) centers. Possible applications of their metal complexes include new catalytic systems, coordination polymers with unique properties, and novel porous materials. [Pg.143]

Grinding conditions are modified by the nature of supports. Gold clusters with a diameter of 1.5 nm were obtained on an aluminum-containing porous coordination polymer by grinding in an agate mortar in air for 20 min, followed by the reduction in a stream of H2 in N2 at 120°C for 2 h ]50]. In contrast, ball milling is favorable... [Pg.61]

The charge densities and compositions of many known solids with VxOy layers were screened for possible charge density matches with M(pyz)x (M = Fe, Co, Ni, Cu, Zn) layers [35, 52], as an aid in the synthesis of new heterometallic multilayered vanadates. Close matches were found with M(pyz)x (M = Fe, Co, Ni) coordination polymers, ranging from 0.022/A -0.053/A, and which might suitably form in the presence of the flexible types of V2O5 layers. For example, Co(pyz) layers of chains in Co(pyz)(V03)2 [53] have a charge density of... [Pg.262]

Under microwave irradiation and applying MCM-41-immobilized nano-iron oxide higher activity is observed [148]. In this case also, primary aliphatic alcohols could be oxidized. The TON for the selective oxidation of 1-octanol to 1-octanal reached to 46 with 99% selectivity. Hou and coworkers reported in 2006 an iron coordination polymer [Fe(fcz)2Cl2]-2CH30H with fez = l-(2,4-difluorophenyl)-l,l-bis[(l//-l,2,4-triazol-l-yl)methyl]ethanol which catalyzed the oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide as oxidant in 87% yield and up to 100% selectivity [149]. An alternative approach is based on the use of heteropoly acids, whereby the incorporation of vanadium and iron into a molybdo-phosphoric acid catalyst led to high yields for the oxidation of various alcohols (up to 94%) with molecular oxygen [150]. [Pg.104]

The reaction of the dinuclear gold(I) amidinate complex, [Au2(2,6-Me2Ph-form)2], with Hg(CN)2 (1 2 stoichiometry) in THF forms a 2D coordination polymer, [Au2(2,6-Me2Ph-form)2]-2Hg(CN)2 2THF, not the expected oxidative-addition product of the type formed vdth the ylides. White crystals and a yellow powder are formed. [Pg.13]

Mohamed, A.A., Abdou, H.E. and Fackler, J.P. Jr (2006) Mercury(ll) cyanide coordination polymer with dinuclear gold (1) amidinate. Structure of the 2-D [Au2(2,6-Me2-formamidinate)2]-2Hg (CN)2 2THF complex. Inorganic Chemistry, 45, 11-12. [Pg.40]

Another helical coordination polymer to contain binding at A-N3 is the product isolated from the reaction between /raas-[(NH3)2Pt(9-MeA-iV7)(9-MeH N7)]2+ (H = 9-methylhypoxanthine) and an excess of AgN03, 13 59). Unusually, in this material the 9-MeA is bound by metal ions at Nl, N3, and N7 simultaneously. The chain polymer is... [Pg.104]

A polymeric structure can be generated by intermolecular coordination of a metalloporphyrin equipped with a suitable ligand. Fleischer (18,90) solved the crystal structure of a zinc porphyrin with one 4-pyridyl group attached at the meso position. In the solid state, a coordination polymer is formed (75, Fig. 30). The authors reported that the open polymer persists in solution, but the association constant of 3 x 104 M 1 is rather high, and it seems more likely, in the light of later work on closed macrocycles (see above), that this system forms a cyclic tetramer at 10-3 M concentrations in solution (71,73). [Pg.249]

Lewis-Acid Catalyzed. Recently, various Lewis acids have been examined as catalyst for the aldol reaction. In the presence of complexes of zinc with aminoesters or aminoalcohols, the dehydration can be avoided and the aldol addition becomes essentially quantitative (Eq. 8.97).245 A microporous coordination polymer obtained by treating anthracene- is (resorcinol) with La(0/Pr)3 possesses catalytic activity for ketone enolization and aldol reactions in pure water at neutral pH.246 The La network is stable against hydrolysis and maintains microporosity and reversible substrate binding that mimicked an enzyme. Zn complexes of proline, lysine, and arginine were found to be efficient catalysts for the aldol addition of p-nitrobenzaldehyde and acetone in an aqueous medium to give quantitative yields and the enantiomeric excesses were up to 56% with 5 mol% of the catalysts at room temperature.247... [Pg.268]

Whereas the preceding provides only three examples of overcoming the kinetics delimma associated with the synthesis of coordination polymers, the messages are clear ... [Pg.468]


See other pages where Coordinating polymer is mentioned: [Pg.172]    [Pg.1060]    [Pg.46]    [Pg.112]    [Pg.138]    [Pg.288]    [Pg.61]    [Pg.306]    [Pg.73]    [Pg.76]    [Pg.107]    [Pg.100]    [Pg.13]    [Pg.13]    [Pg.661]    [Pg.454]    [Pg.104]    [Pg.139]    [Pg.253]    [Pg.463]    [Pg.463]    [Pg.464]    [Pg.35]    [Pg.39]    [Pg.45]    [Pg.52]    [Pg.55]    [Pg.67]    [Pg.119]   


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2D coordination polymer networks

2D coordination polymers

3D coordination polymers

Absorption coordination polymers

Ammonia metal coordination polymers

Anion coordination polymers

Applications of metal-coordinated imprinted polymers

Backbone structure coordination polymers

Backbone structure metal coordination polymers

Benzenedicarboxylate Coordination Polymers

Benzimidazoles, metal coordination polymers

Bridged Coordination Polymers

Cadmium coordination polymers

Calixarenes, metal coordination polymers

Catalytic Properties of Coordination Polymers

Chain Coordination Polymers

Chain polymers, five-coordination

Chiral porous coordination polymer

Cluster chemistry coordination polymers

Cobalt catalysts coordination polymers

Cobalt coordination polymers

Composites porous coordination polymers

Conjugated coordination polymers

Conjugated polymers coordination complexes

Conjugated systems metal coordination polymers

Coordination Polymer Design Approaches

Coordination Polymerisation in Polymer Chemistry and

Coordination Polymers with N-containing Multidentate Aromatic Ligands

Coordination Polymers, MOFs and Other Terminology

Coordination complexes porphyrin polymers

Coordination complexes singly-bridged polymers

Coordination network/polymer,

Coordination polymer impregnation with

Coordination polymer particles

Coordination polymer systems

Coordination polymerization polymer microstructural

Coordination polymers INDEX

Coordination polymers Zinc

Coordination polymers benzimidazoles

Coordination polymers building block approach

Coordination polymers channels

Coordination polymers characteristics

Coordination polymers characterized

Coordination polymers chemical synthesis

Coordination polymers classification

Coordination polymers complex case study

Coordination polymers construction

Coordination polymers crosslinked

Coordination polymers design factors

Coordination polymers dimensionality

Coordination polymers double-stranded

Coordination polymers electrical conductivity

Coordination polymers future applications

Coordination polymers heterometallic complexes

Coordination polymers interpenetrated structures

Coordination polymers interpenetrating

Coordination polymers magnetism

Coordination polymers nanostructures

Coordination polymers organolead

Coordination polymers organotin

Coordination polymers overview

Coordination polymers oxalato-bridged

Coordination polymers oxidative stability

Coordination polymers phthalocyanines

Coordination polymers porosity

Coordination polymers reaction mechanisms

Coordination polymers reversible

Coordination polymers structure

Coordination polymers synthetic approaches

Coordination polymers terminology

Coordination polymers thermal stability

Coordination polymers thioether-based

Coordination polymers three-dimensional

Coordination polymers three-dimensional networks

Coordination polymers traditional

Coordination polymers types

Coordination polymers, synthesis

Coordinative polymer bond

Copper coordination polymers

Crystal engineering of coordination polymers

Cyano-bridged coordination polymer

Cyclic polymers five-coordination

Cyclophane coordination polymers

Electroluminescence coordination polymers

Engineering of Coordination Polymers

Ferrocene-coordination polymers

Fluorescence coordination polymers

Functional Self-Assembled Zinc(II) Coordination Polymers

Helical coordination polymers, from

Heterogeneous metal-organic coordination polymers

Heterometallic coordination polymers

Heterotrimetallic coordination polymers

High-temperature polymer coordination

Homochiral Metal-Organic Coordination Polymers for Heterogeneous Enantioselective Catalysis Self-Supporting Strategy

Hydrogen bonds/bonding coordination polymers

ID coordination polymers

Inorganic coordination polymer

Internal coordinates of a polymer chain and its hindered rotation

Isocyanide coordination polymers

Lanthanide coordination polymers

Lanthanides, coordination polymers metal-organic frameworks

Lanthanides, coordination polymers molecular materials

Lanthanum coordination polymers

Layered structures coordination polymer networks

Lead alkoxides, coordination polymers

Lead carboxylates. coordination polymers

Lead halides, coordination polymers

Lead phosphinates, coordination polymers

Lead thiocyanates, coordination polymers

Linear transition metal coordination polymers

Luminance, coordination polymers

Luminescent organometallic coordination polymers

Macrostructures porous coordination polymers

Manganese coordination polymers

Metal coordination polymers

Metal coordination polymers chemical synthesis

Metal coordination polymers phthalocyanines

Metal coordination polymers porphyrins

Metal coordination polymers reaction mechanisms

Metal-Organic Coordination Polymers as Precursors of Oxides

Metal-Organic Porous Coordination Polymers

Metal-coordinated imprinted polymers

Metal-coordinated imprinted polymers approach

Metal-organic coordination polymers

Metal-organic frameworks coordination polymers

Microporous coordination polymer

Molecular weight metal coordination polymers

Multidentate ligands coordination polymers

Nanoparticles porous coordination polymers

Nets of coordination polymers and metal-organic frameworks

Nickel coordination polymers

Nonlinear optical properties metal coordination polymers

Organic zeolites coordination polymers

Palladium catalysts coordination polymers

Peroxides metal coordinating polymers

Photoluminescence coordination polymers

Photoreactive coordination polymers

Photoreactive ladder coordination polymers

Phthalocyanine polymers metal coordination complexes

Polymer coordination

Polymer coordination

Polymer main-chain coordination polymers

Polymer solutions coordinates of the demixtion critical point

Polymer/salt complexes coordinated

Polymers coordinated

Polymers coordinated

Polymers heterochain with coordinative

Polymers with -Coordinated Metals

Polypyridyl coordination polymers

Pore structure, porous coordination polymers

Porous Coordination Polymer Nanoparticles and Macrostructures

Porous and Coordination Polymers

Porous coordination polymer

Porous coordination polymer chemical

Porous coordination polymer thermal

Porous coordination polymer transformations

Porous coordination polymer zeolitic frameworks

Porous coordination polymers PCPs)

Porous coordination polymers channels

Porous coordination polymers frameworks

Porous coordination polymers layered polymer

Porous coordination polymers polymerizations

Porous materials coordination polymers

Porphyrin coordination polymer

Preformed polymers, metal coordination

Pyridine anionic polymer coordinating

Pyridine ligands metal coordination polymers

Quasi-single-strand coordination polymer

Quasi-single-strand coordination polymer nomenclature

Radiation metal coordination polymers

Rotaxane coordination polymers

Rotaxane coordination polymers frameworks

Ruthenium coordination polymers

Schiff base coordination polymers

Schiff-bases coordination lanthanide polymers

Secondary building units coordination polymers

Silver Coordination Polymers with Specific Topology

Silver coordination polymers

Soluble systems metal coordination polymers

Spacers coordination polymers

Surface-modified metal-coordinating imprinted polymers

Synthetic polymers from coordination polymerization

Synthetic strategies for inorganic supermolecules and coordination polymers

Temperature metal coordination polymers

Thin films coordination polymers

Transparency coordination polymers

Tungsten , coordination polymers

Zigzag chains coordination polymers

Zinc coordination polymers, self-assembled

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