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Coordination complexes singly-bridged polymers

The structure of coordination polymers formed with 3,6-bis(pyridin-3-yl)-l,2,4,5-tetrazine and zinc salts can be controlled by the choice of alcoholic solvents. Infinite lattice compounds of the form [Zn2L2(N03)4(Me0H)2(//-L)] and [Zn2(/U-L)3(N03)4](CH2C12)2) have been structurally characterized. The former structure shows an alternating single- and double-bridged species whereas the latter exists as a non-interpenetrated ladder complex.273... [Pg.1167]

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Bridging coordination

Complex polymers

Coordinating polymers

Polymer bridge

Polymer complexation

Polymer coordination

Polymer single

Polymers coordinated

Singly complexed