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Porous coordination polymers frameworks

TMA can coordinate to not only Cu2+ to form the typical 3-D framework polymer but also to Co2+ to form a porous host-guest compound Co(TMA) (py) with a different structure. The guest pyridine molecules in this compound may be removed from the channels without the collapse of the framework, and the pyridine-removed porous material adsorbs other guest molecules.[187] Polymerization of TMA with a Ni2+ macro-cyclic complex leads to a porous coordination polymer with a unique structure. In the... [Pg.647]

Jee B, Eisinger K, Gul-E-Noor F et al (2010) Continuous wave and pulsed electron spin resonance spectroscopy of paramagnetic framework cupric ion in the Zn(Il) doped porous coordination polymer Cu3 xZnx(btc)2. J Phys Chem C 114 16630-16639... [Pg.40]

It is well known that porous zeolites show cation-exchange properties due to their anionic frameworks, while porous coordination polymers constructed from cationic metal ions and... [Pg.249]

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Coordinating polymers

Polymer coordination

Polymers coordinated

Porous coordination polymer

Porous coordination polymer zeolitic frameworks

Porous polymers

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