Conjugated coordination polymers

Boron—nitrogen coordination polymers, with ferrocene, 6, 208 Boron nucleophiles, in conjugate additions asymmetric 1,4-additions, 10, 388 mechanisms, 10, 384 to nitroolehns, 10, 388 to a,/3-unsaturated amides, 10, 386 to a,/3-unsaturated esters, 10, 386 to a,/3-unsaturated ketones, 10, 384 Boron-silicon bonds, addition to alkenes, 10, 760 to alkynes, 10, 758 to allenes, 10, 760 to carbenoids, 10, 766 to 1,3-dienes, 10, 762 to isocyanides, 10, 765... 

The past seven years have seen significant advances in the preparation of coordination polymers. A vast assortment of conjugated polymers has been prepared that incorporate bpy, phen, and other polydentate ligands. Complexation to metal ions affords new polymeric materials with properties modified by the presence of the transition metal. 

Because of the strong coloration, depending on their state of oxidation, intrinsically conducting polymers have frequently been studied with SRRS [507, 508]. Molecular vibrations could be assigned based on various approaches. Most frequently band positions of the monomers and of already known oligomers were compared with those of the polymers. Alternatively, band positions were calculated based on an effective conjugation coordinate [509-516]. In a typical example shown in Fig. 5.84, SRR spectra of poly aniline are displayed as a function of electrode potential. 

Scope of controlled synthesis via chain-growth condensation polymerization From aromatic polyamides to Tt-conjugated polymers 13CC8281. Solid-state reactivity and structural transformations involving coordination polymers 13CSR1755. 

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