Carbon dioxide industrial processes

In general the energy demands for the carbon dioxide reduction process decrease with the extent of retention of oxygen in the product molecules, e.g., reactions (3) and (4) are much less energy exhausting than is reaction (5). It is thus anticipated that in the short run the industrial utilization of... 

While carbon dioxide capture technologies are new to the power industry, they have been deployed for the past 60 years by the oil, gas, and chemical industries. They are an integral component of natural gas processing and of many coal gasification processes used for the production of syngas, chemicals, and liquid fuels. There are three main carbon dioxide capture processes for power generation (1) postcombustion, (2) precombustion, and (3) oxyfuel. 

Martinache, J.D., et al.. Processing of polyamide 11 with supercritical carbon dioxide. Industrial Engineering Chemistry Research, 2001. 40(23) p. 5570-5577. 

In most of the above cases the carbon dioxide based process is in direct competition with earlier extraction processes in which organic solvents such as hexane, methylene chloride or ethyl acetate have been used. There is increasing resistance to the use of synthetic chemical solvents in the food industry, a fact which should increasingly favour the use of the C02-based process in the above applications. 

The control of carbon dioxide emission from burning fossil fuels in power plants or other industries has been suggested as being possible with different methods, of which sequestration (i.e., collecting CO2 and injecting it to the depth of the seas) has been much talked about recently. Besides of the obvious cost and technical difficulties, this would only store, not dispose of, CO2 (although natural processes in the seas eventually can form carbonates, albeit only over very long periods of time). 

Supercritical Extraction. The use of a supercritical fluid such as carbon dioxide as extractant is growing in industrial importance, particularly in the food-related industries. The advantages of supercritical fluids (qv) as extractants include favorable solubiHty and transport properties, and the abiHty to complete an extraction rapidly at moderate temperature. Whereas most of the supercritical extraction processes are soHd—Hquid extractions, some Hquid—Hquid extractions are of commercial interest also. For example, the removal of ethanol from dilute aqueous solutions using Hquid carbon dioxide... 

In addition to the processes mentioned above, there are also ongoing efforts to synthesize formamide direcdy from carbon dioxide [124-38-9J, hydrogen [1333-74-0] and ammonia [7664-41-7] (29—32). Catalysts that have been proposed are Group VIII transition-metal coordination compounds. Under moderate reaction conditions, ie, 100—180°C, 1—10 MPa (10—100 bar), turnovers of up to 1000 mole formamide per mole catalyst have been achieved. However, since expensive noble metal catalysts are needed, further work is required prior to the technical realization of an industrial process for formamide synthesis based on carbon dioxide. 

Ca.rhona.tlon, GalHum can be extracted by fractional carbonation which consists of treating the aluminate solution with carbon dioxide in several controlled stages. This process is no longer under industrial operation (6). 

Semiconductors. Phosphine is commonly used in the electronics industry as an -type dopant for siUcon semiconductors (6), and to a lesser extent for the preparation of gaUium—indium—phosphide devices (7). For these end uses, high purity, electronic-grade phosphine is required normally >99.999% pure. The main impurities that occur in phosphine manufactured by the acid process are nitrogen [7727-37-9] hydrogen [1333-74-0] arsine [7784-42-17, carbon dioxide [124-38-9], oxygen [7782-44-7], methane [74-82-8], carbon monoxide [630-08-0], and water [7732-42-1]. Phosphine is purified by distillation under pressure to reduce the level of these compounds to <1 ppm by volume. The final product is sold as CYPURE (Cytec Canada Inc.) phosphine. 

ZeoHte-based materials are extremely versatile uses include detergent manufacture, ion-exchange resins (ie, water softeners), catalytic appHcations in the petroleum industry, separation processes (ie, molecular sieves), and as an adsorbent for water, carbon dioxide, mercaptans, and hydrogen sulfide. 

The choice of a specific CO2 removal system depends on the overall ammonia plant design and process integration. Important considerations include CO2 sHp required, CO2 partial pressure in the synthesis gas, presence or lack of sulfur, process energy demands, investment cost, availabiUty of solvent, and CO2 recovery requirements. Carbon dioxide is normally recovered for use in the manufacture of urea, in the carbonated beverage industry, or for enhanced oil recovery by miscible flooding. 

Catalytic Oxidization. A principal technology for control of exhaust gas pollutants is the catalyzed conversion of these substances into innocuous chemical species, such as water and carbon dioxide. This is typically a thermally activated process commonly called catalytic oxidation, and is a proven method for reducing VOC concentrations to the levels mandated by the CAAA (see Catalysis). Catalytic oxidation is also used for treatment of industrial exhausts containing halogenated compounds. 

A substantial portion of fhe gas and vapors emitted to the atmosphere in appreciable quantity from anthropogenic sources tends to be relatively simple in chemical structure carbon dioxide, carbon monoxide, sulfur dioxide, and nitric oxide from combustion processes hydrogen sulfide, ammonia, hydrogen chloride, and hydrogen fluoride from industrial processes. The solvents and gasoline fractions that evaporate are alkanes, alkenes, and aromatics with relatively simple structures. In addition, more complex... 

Vords, M., and G. Honti. 1974. Explosion of a liquid CO2 storage vessel in a carbon dioxide plant. First International Symposium on Loss Prevention arui Safety Promotion in the Process Industries. 

The Kolbe-Schmitt reaction is limited to phenol, substituted phenols and certain heteroaromatics. The classical procedure is carried out by application of high pressure using carbon dioxide without solvent yields are often only moderate. In contrast to the minor importance on laboratory scale, the large scale process for the synthesis of salicylic acid is of great importance in the pharmaceutical industry. 

Steam traps are installed in condensate, mechanical return systems and are a frequently overlooked item for reducing operating costs. Large industrial process plants typically have many hundreds of steam traps installed to recover low-energy condensate and remove (potentially corrosive) air and carbon dioxide. 

In large and extensive industrial process plants, it is not unusual to find unvented condensate receivers or reboilers at the end of a long steam-condensate line. These vessels tend to act as collection and storage points for carbon dioxide, which may redissolve in condensate. These satellite stations should be vented and receive an amine booster feed. 

Self-Test 4.17B The properties of carbon dioxide gas are well known in the bottled beverage industry. In an industrial process, a tank of volume 100. I. at 20.°C contains 20. mol C02. Use the data in Table 4.5 and the van der Waals equation to estimate the pressure in the tank. 

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