Vaporization phenomena

The experimental data permit the extension of cold-flow work resulting in the desired high temperature, oil penetration correlations. The additional information on particle sizes, velocities, and spray stability was used to confirm and revise our present understanding of the flashing/ atomization/vaporization phenomena occurring in the ACR. 

Finally, it is important to be reminded constantly of some of the basic assumptions adopted in describing the present class of droplet vaporization phenomena, particularly those of dilute spray and quasi-steady gas-processes. These assumptions fall in certain practical situations improvements in these aspects of modehng are essential. 

The heat capacity is calculated from the enthalpy data of Guinchant (2) and Ewald (3). its value to provide the best fit of the melting, sublimation and vaporization phenomena. 

Merrill, R. C. 1983. Liquid-liquid-vapor phenomena in cryogenic liquefied natural gas systems. Ph.D. diss., Univ. of Notre Dame. 

Proper selection of the cyling variables is strongly recommended to exploit the vaporization phenomena avoiding related problems. 

Within the WE-NET project (see section 9.2.1.), Mitsubishi Heavy Industries is planning to conduct small-scale LH2 spill experiments for a detailed investigation of the vaporization phenomena with the purpose to develop and validate respective computer models [29]. 

In this chapter we shall study in some detail the critical phenomena in binary systems and especially the relation between critical phenomena and intermolecular forces. In 2-3 we summarize the basic tbermod3naamic relations we need in the subsequent treatment. In 4-7 we consider critical vaporization phenomena while in 8 we study critical solution phenomena. 

There are two approaches to explain physical mechanism of the phenomenon. The first model is based on the existence of the difference between the saturated vapor pressures above two menisci in dead-end capillary. It results in the evaporation of a liquid from the meniscus of smaller curvature ( classical capillary imbibition) and the condensation of its vapor upon the meniscus of larger curvature originally existed due to capillary condensation. 

At first we tried to explain the phenomenon on the base of the existence of the difference between the saturated vapor pressures above two menisci in dead-end capillary [12]. It results in the evaporation of a liquid from the meniscus of smaller curvature ( classical capillary imbibition) and the condensation of its vapor upon the meniscus of larger curvature originally existed due to capillary condensation. We worked out the mathematical description of both gas-vapor diffusion and evaporation-condensation processes in cone s channel. Solving the system of differential equations for evaporation-condensation processes, we ve derived the formula for the dependence of top s (or inner) liquid column growth on time. But the calculated curves for the kinetics of inner column s length are 1-2 orders of magnitude smaller than the experimental ones [12]. 

Here, r is positive and there is thus an increased vapor pressure. In the case of water, P/ is about 1.001 if r is 10" cm, 1.011 if r is 10" cm, and 1.114 if r is 10 cm or 100 A. The effect has been verified experimentally for several liquids [20], down to radii of the order of 0.1 m, and indirect measurements have verified the Kelvin equation for R values down to about 30 A [19]. The phenomenon provides a ready explanation for the ability of vapors to supersaturate. The formation of a new liquid phase begins with small clusters that may grow or aggregate into droplets. In the absence of dust or other foreign surfaces, there will be an activation energy for the formation of these small clusters corresponding to the increased free energy due to the curvature of the surface (see Section IX-2). 

The more highly complexed hydrates of calcium chloride (CaCl2 nH2 O where n > 2) may also exhibit the characteristics of a Class 2 dryiag agent, because the hydrated species can physically absorb additional water to form a saturated solution. The term absorption is used to describe the phenomenon that occurs when a gas or vapor penetrates the soHd stmcture to produce a saturated solution ... 

Cavitation Loosely regarded as related to water hammer and hydrauhc transients because it may cause similar vibration and equipment damage, cavitation is the phenomenon of collapse of vapor bubbles in flowing liquid. These bubbles may be formed anywhere the local liquid pressure drops below the vapor pressure, or they may be injected into the hquid, as when steam is sparged into water. Local low-pressure zones may be produced by local velocity increases (in accordance with the Bernouhi equation see the preceding Conservation Equations subsection) as in eddies or vortices, or near bound-aiy contours by rapid vibration of a boundaiy by separation of liquid during water hammer or by an overaU reduction in static pressure, as due to pressure drop in the suction line of a pump. 

Suction Limitations of a Pump Whenever the pressure in a liquid drops below the vapor pressure corresponding to its temperature, the liquid will vaporize. When this happens within an operating pump, the vapor bubbles will be carried along to a point of higher pressure, where they suddenly collapse. This phenomenon is known as cavitation. Cavitation in a pump should be avoided, as it is accompanied by metal removal, vibration, reduced flow, loss in efficiency, and noise. When the absolute suction pressure is low, cavitation may occur in the pump inlet and damage result in the pump suction and on the impeller vanes near the inlet edges. To avoid this phenomenon, it is necessary to maintain a required net positive suction head (NPSH)r, which is the equivalent total head of liquid at the pump centerline less the vapor pressure p. Each pump manufacturer publishes curves relating (NPSH)r to capacity and speed for each pump. 

The phase-distribution restrictions reflect the requirement that ff =ff at equilibrium where/is the fugacity. This may be expressed by Eq. (13-1). In vapor-hquid systems, it should always be recognized that all components appear in both phases to some extent and there will be such a restriction for each component in the system. In vapor-liquid-hquid systems, each component will have three such restrictions, but only two are independent. In general, when all components exist in all phases, the uumDer of restricting relationships due to the distribution phenomenon will be C(Np — 1), where Np is the number of phases present. 

Foams Two excellent reviews (Shedlovsky, op. cit. Lemlich, op. cit.) covering the literature pertinent to foams have been published. A foam is formed when bubbles rise to the surface of a liquid and persist for a while without coalescence with one another or without rupture into the vapor space. The formation of foam, then, consists simply of the formation, rise, and aggregation of bubbles in a hquid in which foam can exist. The hfe of foams varies over many magnitudes—from seconds to years—but in general is finite. Maintenance of a foam, therefore, is a dynamic phenomenon. 

The real atmosphere is more than a dry mixture of permanent gases. It has other constituents—vapor of both water and organic liquids, and particulate matter held in suspension. Above their temperature of condensation, vapor molecules act just like permanent gas molecules in the air. The predominant vapor in the air is water vapor. Below its condensation temperature, if the air is saturated, water changes from vapor to liquid. We are all familiar with this phenomenon because it appears as fog or mist in the air and as condensed liquid water on windows and other cold surfaces exposed to air. The quantity of water vapor in the air varies greatly from almost complete dryness to supersaturation, i.e., between 0% and 4% by weight. If Table 2-1 is compiled on a wet air basis at a time when the water vapor concentration is 31,200 parts by volume per million parts by volume of wet air (Table 2-2), the concentration of condensable organic vapors is seen to be so low compared to that of water vapor that for all practical purposes the difference between wet air and dry air is its water vapor content. 

VFO works well in gas turbines. In a nine-month test program, the combustion properties of VFO were studied in a combustion test module. A gas turbine was also operated on VFO. The tests were conducted to study the combustion characteristics of VFO, the erosive and corrosive effects of VFO, and the operation of a gas turbine on VFO. The combustion tests were conducted on a combustion test module built from a GE Frame 5 combustion can and liner. The gas turbine tests were conducted on a Ford model 707 industrial gas turbine. Both the combustion module and gas turbine were used in the erosion and corrosion evaluation. The combustion tests showed the VFO to match natural gas in flame patterns, temperature profile, and flame color. The operation of the gas turbine revealed that the gas turbine not only operated well on VFO, but its performance was improved. The turbine inlet temperature was lower at a given output with VFO than with either natural gas or diesel fuel. This phenomenon is due to the increase in exhaust mass flow provided by the addition of steam in the diesel for the vaporization process. Following the tests, a thorough inspection was made of materials in the combustion module and on the gas turbine, which came into contact with the vaporized fuel or with the combustion gas. The inspection revealed no harmful effects on any of the components due to the use of VFO. 

Hydrocarbon vapor migration within the carbon canister is a significant factoi during the real time diurnal test procedure. The phenomenon occurs after the canister has been partially charged with fuel vapors. Initially the hydrocarbons will reside primarily in the activated carbon that is closest to the fuel vapor source. Over time, the hydrocarbons will diffuse to areas in the carbon bed with lower HC concentration. Premature break through caused by vapor migration for twc different canisters is shown in Fig. 17. The canister with the L/D ratio of 5.0 shows substantially lower bleed emissions than the canister with an L/D ratio of 3.0. 

Volatilization — Volatilization is a physico-chemical phenomenon of particular interest to environmental managers as well as safety managers. It is the tendency of a material to transfer from a liquid phase (either pure or dissolved as in aqueous systems) to a gaseous phase (commonly air). The volatilization, or evaporation as it is more commonly called, is controlled by a number of factors, the most important of which are the vapor pressure of the material, temperature (vapor pressure increases with temperature), and air/material interfacial surface area, and the action of active mass transfer agents such as wind. 

Historically, this phenomenon was referred to as unconfined vapor cloud explosion, but, in general, the term unconfined is a misnomer. It is more accurate to call this type of explosion simply a vapor cloud explosion. ... 

In this section, the phenomenon of BLEVE is discussed according to theories proposed by Reid (1976), Board (1975), and Venart (1990). Reid (1979, 1980) based a theory about the BLEVE mechanism on the phenomenon of superheated liquids. When heat is transferred to a liquid, the temperature of the liquid rises. When the boiling point is reached, the liquid starts to form vapor bubbles at active sites. These active sites occur at interfaces with solids, including vessel walls. 

Fireworks displays are fascinating to watch. Neon lights and sodium vapor lamps can transform the skyline of a city with their brilliant colors. The eerie phenomenon of the aurora borealis is an unforgettable experience when you see it for the first time. All of these events relate to the generation of light and its transmission through space. 

At any temperature, molecules can escape from the surface of a liquid (vaporizing or evaporating) to enter the gas phase as vapor. At the special temperature at which the vapor pressure just equals the atmospheric pressure, a new phenomenon occurs. There, bubbles of vapor can form anywhere within the liquid. At this temperature, the liquid boils. 

Equation (7) is an interesting example of the versatility of the hypothesistesting technique that Barnett has exploited. Thus, suppose it is assumed that the important fluid properties which control the burn-out phenomenon are density pL, specific heat, CPL, and thermal conductivity kL of the liquid phase, together with density of the vapor phase pv and the latent heat L Then, for burn-out in a uniformly heated round tube we have... 

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