Liquids drops

Settling and sedimentation. In settling processes, particles are separated from a fluid by gravitational forces acting on the particles. The particles can be solid particles or liquid drops. The fluid can be a liquid or a gas. 

Figure 3.1a shows a flash drum used to separate by gravity a vapor-liquid mixture. The velocity of the vapor through the flash drum must be less than the settling velocity of the liquid drops. Figure 3.11) shows a simple gravity settler for removing a... 

The amount of processing required in the field depends upon the composition of the gas and the temperature and pressure to which the gas will be exposed during transportation. The process engineer is trying to avoid liquid drop-out during transportation, since this may cause slugging, corrosion and possibly hydrate formation (refer to Section 10.1.3). For dry gases (refer to Section 5.2.2) the produced fluids are... 

Condensable hydrocarbon components are usually removed from gas to avoid liquid drop out in pipelines, or to recover valuable natural gas liquids where there is no facility for gas export. Cooling to ambient conditions can be achieved by air or water heat exchange, or to sub zero temperatures by gas expansion or refrigeration. Many other processes such as compression and absorption also work more efficiently at low temperatures. 

The gas processing options described in the previous section were designed primarily to meet on-site usage or evacuation specifications. Before delivery to the customer further processing would normally be carried out at dedicated gas processing plants, which may receive gas from many different gas and oil fields. Gas piped to such plants is normally treated to prevent liquid drop out under pipeline conditions (dew point control) but may still contain considerable volumes of natural gas liquids (NGL) and also contaminants. 

The Kelvin equation (Eq. HI-18), which gives the increase in vapor pressure for a curved surface and hence of small liquid drops, should also apply to crystals. Thus... 

The correct treatment of boundaries and boundary effects is crucial to simulation methods because it enables macroscopic properties to be calculated from simulations using relatively small numbers of particles. The importance of boundary effects can be illustrated by considering the following simple example. Suppose we have a cube of volume 1 litre which is filled with water at room temperature. The cube contains approximately 3.3 X 10 molecules. Interactions with the walls can extend up to 10 molecular diameters into the fluid. The diameter of the water molecule is approximately 2.8 A and so the number of water molecules that are interacting with the boundary is about 2 x 10. So only about one in 1.5 million water molecules is influenced by interactions with the walls of the container. The number of particles in a Monte Carlo or molecular dynamics simulation is far fewer than 10 -10 and is frequently less than 1000. In a system of 1000 water molecules most, if not all of them, would be within the influence of the walls of the boundary. Clecirly, a simulation of 1000 water molecules in a vessel would not be an appropriate way to derive bulk properties. The alternative is to dispense with the container altogether. Now, approximately three-quarters of the molecules would be at the surface of the sample rather than being in the bulk. Such a situation would be relevcUit to studies of liquid drops, but not to studies of bulk phenomena. 

A. Single liquid drop in immiscible liquid, drop formation, discontinuous (drop) phase coefficient... 

L. Liquid drop in immiscible liquid, free rise or fall, continuous phase coefficient, circulating single drops... 

T. Single liquid drops in gas, gas side coefficient =2 + ANiS,Ni [E] Used for spray drying (arithmetic partial pressure difference). [88] p. 489... 

H. Liquid drops in baffled tank with flat six-blade turbine 2.621 X iQ- [E] Use arithmetic couceutratiou difference. Studied for five systems. [154] p. 437... 

Suction Limitations of a Pump Whenever the pressure in a liquid drops below the vapor pressure corresponding to its temperature, the liquid will vaporize. When this happens within an operating pump, the vapor bubbles will be carried along to a point of higher pressure, where they suddenly collapse. This phenomenon is known as cavitation. Cavitation in a pump should be avoided, as it is accompanied by metal removal, vibration, reduced flow, loss in efficiency, and noise. When the absolute suction pressure is low, cavitation may occur in the pump inlet and damage result in the pump suction and on the impeller vanes near the inlet edges. To avoid this phenomenon, it is necessary to maintain a required net positive suction head (NPSH)r, which is the equivalent total head of liquid at the pump centerline less the vapor pressure p. Each pump manufacturer publishes curves relating (NPSH)r to capacity and speed for each pump. 

P. True not bulk) density of solids or liquid drops kg/m Ibm/ft Ibm/ft ... 

Pipe Lines The principal interest here will be for flow in which one hquid is dispersed in another as they flow cocurrently through a pipe (stratified flow produces too little interfacial area for use in hquid extraction or chemical reaction between liquids). Drop size of dispersed phase, if initially very fine at high concentrations, increases as the distance downstream increases, owing to coalescence [see Holland, loc. cit. Ward and Knudsen, Am. In.st. Chem. Eng. J., 13, 356 (1967)] or if initially large, decreases by breakup in regions of high shear [Sleicher, ibid., 8, 471 (1962) Chem. Eng. ScL, 20, 57 (1965)]. The maximum drop size is given by (Sleicher, loc. cit.)... 

Equipment Operation Spray nozzles suffer from caking on the outside and clogging on the inside. When the nozzle is below the bed surface, fast capture of the liquid drops by bed particles, as well as scouring of the nozzle by particles, prevents caking. Blockages inside the nozzle are also common, particularly for slurries. The nozzle design shoiild be as simple as possible and provision for in situ cleaning or easy removal is essential. 

Expansion turbines—three in Phase 1 and two in Phase 2—cool the gas to -90°C, at which point more liquid drops out in another separator. In this system, the cold methane gas emerges from the expansion turbines at a reduced pressure of 325 psi and is recirculated to the original heat exchanger to reduce the temperature of the natural gas entering the plant. 

Liquids are able to flow. Complicated stream patterns arise, dependent on geometric shape of the surrounding of the liquid and of the initial conditions. Physicists tend to simplify things by considering well-defined situations. What could be the simplest configurations where flow occurs Suppose we had two parallel plates and a liquid drop squeezed in between. Let us keep the lower plate at rest and move the upper plate at constant velocity in a parallel direction, so that the plate separation distance keeps constant. Near each of the plates, the velocities of the liquid and the plate are equal due to the friction between plate and liquid. Hence a velocity field that describes the stream builds up, (Fig. 15). In the simplest case the velocity is linear in the spatial coordinate perpendicular to the plates. It is a shear flow, as different planes of liquid slide over each other. This is true for a simple as well as for a complex fluid. But what will happen to the mesoscopic structure of a complex fluid How is it affected Is it destroyed or can it even be built up For a review of theories and experiments, see Ref. 122. Let us look into some recent works. 

Fluid in a container is a combination of hquid and vapor. Before container mpture, the contained liquid is usually in equilibrium with the saturated vapor. If a container mptures, vapor is vented and the pressure in the liquid drops sharply. Upon loss of equilibrium, liquid flashes at the liquid-vapor interface, the liquid-container-wall interface, and, depending on temperature, throughout the liquid. 

The correlation factor, k, is a function of the liquid drop size, liquid viscosity, liquid load, disengaging space, type of mesh weave, etc. k varies somew hat with system pressure as pressure increases the k value decreases. The manufacturers should be consulted for final design k valves for a sys-... 

Other useful distributor types have been referred to and previously illustrated. For redistribution, the v apor risers may be 12 in.-18 in. tall, and with protective hats to prevent liquid dropping from the tray/section above. The space between the cover hat on the riser and the bed above should be 18 in. to 12 in. minimum to allow for proper v apor redistribution entering the packed section above. The importance of a level distributor cannot be overemphasized. 

In conventional compressed air systems, vapor and liquid removal is limited. Most two-stage compressors will include an intercooler between stages. On air-cooled units for 100 to 200psig service, the air between stages is not cooled sufficiently to cause substantial liquid drop out and provision is not usually made for its removal. Water-cooled intercoolers used on larger compressors will usually cool sufficiently to condense considerable moisture at cooler pressure. Drainage facilities must always... 

If the curved surface is convex, as in the case of liquid drops, or the surface of mercury depressed in a capillary tube, p >p, but if it is concave, as in the case of a liquid ascending and wetting a capillary tube, r is negative and p [Pg.203]

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