Vaporized fuel oil

There are direct substitutions of possible interest that would not be feasible without drastic changes in the feed system or pressure. Thus if the available substitute for natural gas is, eg, a manufactured gas containing much CO, there would almost always be a mismatch of the WIs unless the fuel could be further modified by mixing with some other gaseous fuel of high volumetric heating value (propane, butane, vaporized fuel oil, etc). Moreover, if there are substantial differences in eg, as a result of the presence of considerable H2 as well as CO in the substitute gas, the variation in dame height and dashback tendency can also make the substitution unsatisfactory for some purposes, even if the WI is reproduced. Refinements and additional criteria are occasionally appHed to measure these and other effects in more complex substitution problems (10,85). 

Vaporized fuel oil gas behaves very elosely to natural gas beeause it provides high performanee with a minimum reduetion of eomponent life. About 40% of the turbine power installed operates on liquid fuels. Liquid fuels ean vary from light volatile naphtha through kerosene to the heavy viseous residuals. The elasses of liquid fuels and their requirements are shown in Table 12-1. 

Natural gas requires no fuel treatment however, low-Btu gas, espeeially if derived from various coal gasification processes, requires various types of cleaners for use in a gas turbine. These cycles can get very complex as indicated by a typical system, which utilizes a steam bottoming cycle to achieve high efficiency. Vaporized fuel oil gas is already cleansed of its impurities in the vaporization process. 

An alternate approach to fuel washing is to utilize a vaporized fuel oil system (VFO). This technology was developed as a method for converting natural gas fuel systems to liquid fuel. The process involves mixing steam with the liquid fuel and then vaporizing the mixture. The vaporized mixture exhibits the same combustion properties as natural gas. 

R is an alkyl group with one to five carbons. Eg, vapor oil, kerosene, fuel oils. N,N-Diphenylthiourea [102-08-9],... 

Thermal decomposition of spent acids, eg, sulfuric acid, is required as an intermediate step at temperatures sufficientiy high to completely consume the organic contaminants by combustion temperatures above 1000°C are required. Concentrated acid can be made from the sulfur oxides. Spent acid is sprayed into a vertical combustion chamber, where the energy required to heat and vaporize the feed and support these endothermic reactions is suppHed by complete combustion of fuel oil plus added sulfur, if further acid production is desired. High feed rates of up to 30 t/d of uniform spent acid droplets are attained with a single rotary atomizer and decomposition rates of ca 400 t/d are possible (98). 

Commercial-scale processes have been developed for the production of hydrogen sulfide from heavy fuel oils and sulfur as well as from methane, water vapor, and sulfur. The latter process can be carried out in two steps reaction of methane with sulfur to form carbon disulfide and hydrogen sulfide followed by hydrolysis of carbon disulfide (116). 

Flash Point. As fuel oil is heated, vapors are produced which at a certain temperature "flash" when ignited by an external ignition source. The flash point is the lowest temperature at which vapor, given off from a Hquid, is in sufficient quantity to enable ignition to take place. The flash point is in effect a measure of the volatiHty of the fuel. The measurement of flash point for pure Hquids is relatively straightforward. However, the measured value may depend slightly on the method used, especially for Hquid mixtures, since the composition of the vapor evolved can vary with the heating rate. Special... 

Filter P per Processing. In the fabrication of fuel oil and air filters for vehicles such as motorcycles and diesel locomotives, heat processing of the filter paper is required to cure the resin (usually phenoHc) with which the paper (qv) is impregnated (see Phenolic resins). The cure-oven exhaust, which contains water vapor, alcohols, and dimers and trimers of phenol, produces a typical blue haze aerosol having a pungent odor. The concentration of organic substances in the exhaust is usually rather low. 

ASTM (atmospheric) ASTM D 86 Petroleum fractions or products, including gasolines, turbine fuels, naphthas, kerosines, gas oils, distillate fuel oils, and solvents that do not tend to decompose when vaporized at 760 mmHg... 

If a fuel is in the liquid state, such as fuel oil, most of it must be vaporized to the gaseous state before combustion occurs. This vaporization can be accomplished by supplying heat from an outside source, but usually the liquid fuel is first atomized and then the finely divided fuel particles are sprayed into a hot combustion chamber to accomplish the gasification. 

When the burner went out, the solenoid valve took a few see-onds to elose, and during this time some oil entered the furnaee. In addition, the line between the last valve and the furnaee may have drained into the furnaee. The flash point of the fuel oil was 65°C, too high for the oil to be deteeted by the eombustible gas deteetor. Even though the oil was vaporized by the hot furnaee, it would have eondensed in the sample tube of the gas deteetor or on the sintered metal that surrounds the deteetor head. 

Unfortunately, this was not the case for the plant in this example, and the worker wrongly chose to maintain production. By the time he arrived at the furnace, some of the fuel oil from burner "A" was deposited on the furnace tubes. Due to the heat from burner "B," the oil had vaporized and had been carried into the furnace stack. An explosion occurred when the mixture of air and unburned fuel came into the flammable range. 

Hot water boilers are potentially more susceptible to gas-side corrosion than steam boilers due to the lower temperatures and pressures encountered on low- and medium-temperature hot water boilers. With low-temperature hot water especially, the water-return temperature may drop below the water dewpoint of 50°C, causing vapor in the products of combustion to condense. This, in turn, leads to corrosion if it persists for long periods. The remedy is to ensure that adequate mixing of the return water maintains the water in the shell above 65°C at all times. Also, if medium or heavy fuel oil is to be used for low- or medium-temperature applications it is desirable to keep the heat transfer surfaces above 130°C, this being the approximate acid dewpoint temperature of the combustion gases. It may be seen, therefore, how important it is to match the unit or range of unit sizes to the expected load. 

Recycling to monomers, fuel oils or other valuable chemicals from the waste polymers has been attractive and sometimes the system has been commercially operated [1-4]. It has been understood that, in the thermal decomposition of polymers, the residence time distribution (RTD) of the vapor phase in the reactor has been one of the major factors in determining the products distribution and yield, since the products are usually generated as a vapor phase at a high temperature. The RTD of the vapor phase becomes more important in fluidized bed reactors where the residence time of the vapor phase is usually very short. The residence time of the vapor or gas phase has been controlled by generating a swirling flow motion in the reactor [5-8]. 

Example 25.6 A medium fuel oil is to be burnt in a furnace with 10% excess air. Ambient temperature is 10°C and 60% relative humidity. Saturated vapor pressure of air at 10°C is 0.0123 bar. The analysis of the fuel is given in Table 25.4 ... 

A dust or vapor explosion sometimes happens accidentally in industries, causing great damage. Several readily available materials are explosive when mixed with air in the form of a dust or vapor, so such explosions can be induced as a sabotage technique. Among suitable materials are flour, cornstarch, powdered milk, cocoa, very fine aluminum or magnesium powder, gasoline, and fuel oil. 

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