Valves and Pumps

Aqueous hydrogen fluoride of greater than 60% maybe handled in steel up to 38°C, provided velocities are kept low (<0.3 m/s) and iron pickup in the process stream is acceptable. Otherwise, mbber or polytetrafluoroethylene (PTFE) linings are used. For all appHcations, PTFE or PTEE-lined materials are suitable up to the maximum use temperature of 200°C. PTEE is also the material of choice for gasketing. AHoy 20 or Monel is typically used for valve and pump appHcations. Materials unacceptable for use in HE include cast iron, type 400 stainless steel, hardened steels, titanium, glass, and siHcate ceramics. 

Handling Temperatures. Optimum temperature for pumping is in 37—48°C range. Piping should be stainless steel, aluminum, or galvanized iron. Valves and pumps should be bronze, cast-iron with bronze trim, or stainless steel. A pump of 3.15-L/s (50-gal/min) capacity unloads a tank car of warm glycerol in ca 4 h. 

AH columns, distributors, and ancHlary hardware such as piping, valves, and pumps must be constmcted of corrosion-resistant materials, or coated with an appropriate substance. AH streams that contact the hardware during each step of the cycHc operation need to be considered in this selection. 

The products for these appHcations are fabricated from materials from brass mills (manufacturers of copper and alloy mill products), wire mills, and foundries (manufacturers of castings). Brass mill products consist of sheet, strip, plate, rod, bar, tube, pipe, forgings, extmsions, and mechanical wire. Wire mills make electrical wire. Foundry castings consist primarily of plumbing products and industrial valves and pumps. 

Uses. Copper—nickel—iron alloys, UNS C 96200 (90 10 copper nickel) and UNS C 96400 (70 30 copper nickel), are used in corrosion-resistant marine (seawater) appHcations. UNS C 96400 is used for corrosion-resistant marine elbows, flanges, valves, and pumps. Leaded nickel—brass, UNS C 97300 (12% nickel-silver), is used for hardware fittings, valves, and statuary and ornamental castings. 

The leaded nickel bronzes, UNS 97600 (20% nickel-silver) and UNS C 97800 (25% nickel-silver), are used for marine, ornamental, and sanitary castings, and valves and pumps, and for ornamental hardware, sanitary castings, valves, and musical instmment parts, respectively. 

The coefficient of linear expansion of these alloys in the temperature range of 21 to 100°C (70 to 212°F) is 12.2 X lO C (6.8 X 10"V°F), which is slightly above that of cast iron (National Bureau of Standards). Since these loys have practically no elasticity, it is necessary to use expansion joints in relatively short pipe hnes. Connections for flanged pipe, fittings, valves, and pumps are made to 125-lb American Standarci drilling. 

Chlorimet 2 has 63 percent Ni and 32 percent Mo and is somewhat similar to Hastelloy B-2. It is available only in cast form, mainly as valves and pumps. This is a tough alloy, very resistant to mechanical and thermal snock. It can be machined with carbide-tipped tools and welded with metal-arc techniques. 

Because of its chemical inertness over a wide temperature range it is used in a variety of seals, gaskets, packings, valve and pump parts and in laboratory equipment. 

It was claimed that the maximum continuous operating temperature in most chemical environments was 120°C and even 140-150°C in some instances. The major chemical applications were in the form of pipe and tank linings and injection moulded valve and pump parts. Coatings could be applied to metals by means of fluidised bed, water suspension and organic dispersion techniques. 

A Statistical Analysis of Nuclear Power Plant (Pump and Valve) Failure Rale Variability me Preliminary Results Nuclear All IPRDS data base records for the pumps and valves selected for analysis The set of valves and pumps selected for analysis from the IPRDS data base 104. 

The corrosive and mechanical effects of flow are observed in pipes, especially at bends and downstream of flow disturbances, tube and shell heat exchangers, valves and pumps. More corrosion and/or harder materials are used in such areas. Austenitic stainless steels work harden and hence are superior in flowing conditions to ferritic stainless steels of otherwise similar corrosion resistance. Hard... 

Copper alloys in wrought or cast form are used for other purposes in ships and other marine installations, such as for propellers bearings, valves and pumps. One widespread application of aluminium-brass is its use for heating coils in tankers carrying crude oil or petroleum products. Some corrosion problems encountered in this and other applications on board ship have been described by Gilbert and Jenner . 

Storage vessels can be made in a large variety of shapes and sizes. Absorption and distillation towers are available in several different forms and many sizes. Reaction vessels such as coppers, stills and Cellarius receivers can be supplied in the special materials to withstand thermal shock. Valves and pumps of many types are available to suit all conditions. Piping can be... 

Where a brine system services a multiple-temperature installation such as a range of food stores, the coolant maybe too cold for some conditions, causing excessive dehydration of the product. In such cases, to cool these rooms the brine must be blended. A separate three-way blending valve and pump will be required for each room (see Figure 12.6). 

These galvanic corrosion processes take place when one or more elemental constituents of an alloy is leached, often leaving a weak, porous structure, although the component dimensions often are unchanged. Dealloying particularly affects equipment constructed of cupronickels, bronzes, brasses, and gunmetal, such as FW heaters, strainers, valves, and pump impellers. 

Four different types of tasks are performed by automation. Two involve the sequencing of valves and pumps Involved 1n the setup and completion of the designed experiment through the operation of the test and hydraulic fluid systems. The other tasks involve the control of the temperature bath and data collection. To perform these tasks, a1r-actuated solenoids and optically coupled sol Id-state relays are used. These devices are controlled by an electrical circuit consisting of the device connected 1n series with a power supply and a channel on the actuator card In the HP 3497. The power supply 1s either 24 VDC for use with the solenoids or 5 VDC for the solid-state relays. The actuator output channel acts as a simple on/off switch which allows power to be supplied to the solenoid or relay when closed. The logic of the circuit 1s controlled by application programs running on the local HP 1000. 

Limited aperture releases are conceptualized in Figure 4-2. For these releases material is ejected from holes and cracks in tanks and pipes, leaks in flanges, valves, and pumps, and severed or ruptured pipes. Relief systems, designed to prevent the overpressuring of tanks and process vessels, are also potential sources of released material. 

Valve and pump components, balls for non-return valves. .. 

Design the control valve and pump so that both the maximum and minimum flow rates can be handled with the valve never less than 10 percent open. 

Research has been done showing that rapid pressnre-driven LC analysis can be done with little solvent consumption, demonstrating this as a viable process analytical tool. Using electrokinetic nanoflow pumps LC can be miniaturized to the point of being a sensor system. Developments in terms of sampling to enable sampling directly from a process stream, to the separation channel on a chip are critical for the application of miniaturized process LC. The components (valves and pumps) required for hydrodynamic flow systems appear to be a current limitation to the fnll miniatnrization of LC separations. Detection systems have also evolved with electrochemical detection and refractive index detection systems providing increased sensitivity in miniaturized systems when compared to standard UV-vis detection or fluorescence, which may require precolumn derivatization. 

Table S.4 shows the preconcentration programme that was used in this investigation. Sample volumes of 10, 20 and SO ml were used successfully and the enriched metals were in all three instances eluted with S ml of HNO3 (2 M). The control unit is equipped with a CRT display to simplify the input of the desired preconcentration parameters. During the preconcentration, the current settings of valves and pumps are displayed.

Fig. 6.1.4 Components of the high-performance liquid chromatography (HPLC) system for oxidized pterins with column switching. The autosampler starts the chromatography software, which controls valves and pumps. Pump 3 is used only for rinsing the precolumn. Details of the three valves and their different positions are explained in Fig. 6.1.5...

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