Mineral-Petroleum Applications

Tara gum s property of thickening is used to maintain the stability [87, 88] and appearance of salad dressings, sauces, pickles, spicy seasonings, and barbecue sauces. Tara gum and guar gum are consistent with the very sour emulsions, with effective rates of 0.2% to 0.8% of the total weight. 

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Solutions of TKPP have been shown to have unique and advantageous properties for use in formulating a wide variety of well fluids. Its reasonable cost, worldwide availability, and nontoxic properties make it a preferred additive for use in many petroleum applications. It has been shown to be a most effective salt with respect to inhibiting hydration and swelling of clay minerals commonly encountered in drilling operations and/or reservoirs. Avoiding clay problems is the major impetus for the incorporation of potassium ions in well fluids, and the use of TKPP provides advantages over and above those available from other potassium salts. 

Descriptions and discussions of gravity sedimentation in textbooks (and this one is no exception) are usually dominated by water treatment and mineral processing applications. One must not lose sight, however, of the many chemical, pharmaceutical, nuclear, petrochemical or petroleum applications where gravity settling is used to resolve emulsions or to separate other liquid-liquid dispersions. As the density difference in such cases is nearly always low, the benefits of coalescence are usually sought. The present book, as per its title, is concerned primarily with solid-liquid systems and a reader interested in separation of liquid-liquid dispersions is referred to an excellent review of such applications (and of electrostatic coalescence)... 

Mineral Oil Hydraulic Fluids. No human studies examining dermal end points were located. In animals, no information on dermal effects following inhalation or oral exposure were located. A number of mineral oil hydraulic fluids have been tested for acute dermal toxicity in rabbits. Signs of skin irritation have been observed following application of a naphthenic petroleum-based hydraulic fluid designated as MIL-H-5606... 

Mineral Oil Hydraulic Fluids. No specific methods were located for interfering with the mechanism of action for toxic effects produced by mineral oil hydraulic fluids. Unstable alveoli and distal airways have been proposed as major factors in the respiratory symptoms that occur after the ingestion of other petroleum-derived materials. Continuous positive airway pressure or continuous negative chest wall pressure, as well as the application of supplemental oxygen, have been recommended to counteract the resultant pneumonitis (Eade et al. 1974 Klein and Simon 1986). 

Table 5.8 gives an indication of the range of elements that may be determined. Most procedures will require an analyte concentration of 10-3 mol dm 3 or more, although with special conditions, notably potentiometric end-point detection, the sensitivity may be extended to 1(H mol dm 3. The analysis of mixtures of metal ions necessitates masking and demasking, pH adjustments and selective separation procedures. Areas of application are spread throughout the chemical field from water treatment and the analysis of refined food and petroleum products to the assay of minerals and alloys. Table 5.10 gives some selected examples. 

No increase in the incidence of tumor-bearing mice was noted in animals treated with 25 mg of undiluted petroleum diesel three times per week for up to 105 weeks in male and female C3H/HeN (diesel-treated had an incidence of 2/27 and mineral oil-treated negative controls did not develop any tumors). Jet A did, however, produce an increased incidence (26%) of tumors (primarily squamous cell carcinoma and fibrosarcoma) (Clark et al. 1988). It was noted that both types of fuels produced inflammatory and degenerative changes at the application that led to "early mortality" and that the nonneoplastic lesions and their attendant effects were so severe that the application of Jet A was discontinued at week 62. 

Factor analysis extracts information from the sample data set (e.g., IR spectra) and does not rely on reference minerals. However, because abstract factors have no physical meaning, reference minerals may be needed in target transformations or other procedures to extract mineralogical information. One valuable piece of information obtainable without the use of extraneous data is the number of components required to represent the data within experimental error. Reported applications of factor analysis to mineralogy by FTIR are few (12). However, one commercial laboratory is offering routine FTIR mineral analyses to the petroleum industry, based on related methods (22). 

Occurs in nature in abundance the principal forms are bauxites and lat-erites. The mineral corundum is used to produce precious gems, such as ruhy and sapphire. Activated aluminas are used extensively as adsorbents because of their affinity for water and other polar molecules and as catalysts because of their large surface area and appropriate pore sturcture. As adsorbents, they are used for drying gases and liquids and in adsorption chromatography. Catalytic properties may be attributed to the presence of surface active sites (primarily OFT, 02, and AF+ ions). Such catalytic applications include sulfur recovery from H2S (Clauss catalysis) dehydration of alcohols, isomerization of olefins and as a catalyst support in petroleum refining. 

Lead sulfide occurs in nature as the mineral galena. Most lead comes from this ore. Additionally, lead sulfide has several industrial applications. It is used in infrared detectors transistors photoconductive cells high temperature lubricants and for glazing earthenware. It also is used as a catalyst in petroleum refining for removal of mercaptans from petroleum distillates. 

The Oil Snapper product is based on Serengeti s Enhanced Urea Technology and contains the minerals and chemical compounds needed by microbes to degrade petroleum hydrocarbons. This product is applicable to soils contaminated with most petroleum hydrocarbons, including diesel, No. 6 fuel oil, hydraulic oil, and crude oil. 

X-ray fluorescence can be used to analyse all types of samples. Its applications are numerous, whether in research and development or in quality control of production. Initially, X-ray fluorescence was used in industries that treat metals of primary fusion or alloys and, more generally, in the mineral industry (for use one ceramics, cements, steel, glass, etc.). Because of the ease of use of common X-ray fluorescence instruments, its scope of application has expanded into other areas the photographic industry and semi-conductors (for impurity control in silicon chips), the petroleum industry, geology, paper mills, gas analyses (such as nitrogen), toxicology and environmental applications (dust, fumes from combustion, heavy metals, and dangerous materials in waste such as Pb, As, Cr, Cd, etc.). 

Bitumen describes a black or dark brown masticlike material that is thermoplastic in nature and softens upon heating. The sources of bitumen are petroleum or coal deposits. The natural product is commonly called gilsonite or pitch, a mineral formed by an old weathered petroleum flow at the surface of the earth that has left behind the larger molecules from the petroleum. A principal source in the past has been Lake Trinidad, a 445,000 m2 deposit on the island of Trinidad. Bitumen from petroleum or crude oil is called asphalt (qv). It is the material left behind after all the valuable compounds, eg, gasolines, have been distilled out of the cmde oil. The amount and quality of asphalt is dependent on the source of the crude oil used in the refining process. Some cmde oils have a higher content of asphaltic bitumen left after the distillation process. Bitumen from coal is coal-tar pitch. It remains after the valuable coal oils and tars have been distilled out of the coal tars produced by distractive distillation. Most industrial applications for bitumen products use asphalt or coal-tar pitch because the supply is more uniform and plentiful. 

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