131-17-9 Diallyl phthalate

Diallyl Phthalate (and Diallyl 1,3-Phthalate). These allyl polymers are prepared from... 

Polycarbonate acrylonitrile-butadiene-styrene alloy Allyl-diglycol- carbonate polymer Diallyl phthalate molding Cellulose acetate Cellulose-acetate-butyrate resin... 

The three isomeric diallyl phthalates are colorless Hquids of mild, odor, low volatiUty, and relatively slow polymerisation ia the early stages. At ca 25% conversion, the viscous Hquid undergoes gelation and polymerisation accelerates however, the last monomer disappears at a slow rate. 

The monomers are prepared by conventional esterification. Diallyl phthalate (DAP) [131-17-9] is prepared from phthaUc anhydride and aEyl alcohol ... 

Properties of two diallyl phthalate monomers, are given in Table 5. The Hquids are soluble in common organic solvents but insoluble in water. 

For all three diallyl phthalate isomers, gelation occurs at nearly the same conversion DAP prepolymer contains fewer reactive allyl groups than the other isomeric prepolymers (36). More double bonds are lost by cyclisation in DAP polymerisation, but this does not affect gelation. The heat-distortion temperature of cross-linked DAP polymer is influenced by the initiator chosen and its concentration (37). Heat resistance is increased by electron beam irradiation. 

Because of its low price, compatibility, low viscosity and ease of use styrene is the preferred reactive diluent in general purpose resins. Methyl methacrylate is sometimes used, but as it does not copolymerise alone with most unsaturated polyesters, usually in conjunction with styrene in resins for translucent sheeting. Vinyl toluene and diallyl phthalate are also occasionally employed. The use of many other monomers is described in the literature. 

Diallyl phthalate (see also Section 25.3) has also been used as a laminating resin but because of its higher price it has been largely replaced by the glycol-saturated acid-unsaturated aeid polyesters. 

On heating with a peroxide, diallyl phthalate will polymerise and eventually cross-link because of the presence of two double bonds (Figure 25.13). 

Group of plastics composed of resins formulated by addition polymerization of monomers containing allyl groups (e.g., diallyl phthalate). 

Aortal Aery Me ABS Alkyd Alloy /Blands Barrier Resin CeliAwie Diallyl Phthalates Engineering Plastics Epoxies Fluorepdlymars Liquid Crystal Melamine Nitrile Resins Nylon Phenolic Polyamlde-lmide Polycarbonate polyester Polyethylene Polyimictes Polypropylene Polyurethanes PVC... 

Zone 5 acrylic, diallyl phthalate, epoxy, phenol-formaldehyde, TP polyester, and polytetrafluoroethylene. 

Diallyl Phthalate (DAP, DAIP) Powder Excellent humidity resistance. Withstands temperatures over 400 F. Easily processed. Dimensional stability excellent. May be compression, transfer and injection molded. Low cost. Precision potentiometers, RF connectors, waveguide auxiliaries, attenuators, heating panels, heated battery cases. 

Between 250 and 450°F (121 and 232°C), plastics used include glass or mineral-filled phenolics, melamines, alkyds, silicones, nylons, polyphenylene oxides, polysulfones, polycarbonates, methylpentenes, fluorocarbons, polypropylenes, and diallyl phthalates. The addition of glass fillers to the thermoplastics can raise the useful temperature range as much as 100°F and at the same time shortens the molding cycle. 

Color Urea, melamine, polycarbonate, polyphenylene oxide, polysulfone, polypropylene, diallyl phthalate, and phenolic are examples of what is needed in the temperature range above 200°F (94°C) for good color stability. Most TPs will be suitable below this range. 

Moisture Deteriorating effects of moisture are well known as reviewed early in this chapter (OTHER BEHAVIOR, Drying Plastic). Examples for high moisture applications include polyphenylene oxide, polysulfone, acrylic, butyrate, diallyl phthalate, glass-bonded mica, mineral-filled phenolic, chlorotrifluoroethylene, vinylidene, chlorinated polyether chloride, vinylidene fluoride, and fluorocarbon. Diallyl phthalate, polysulfone, and polyphenylene oxide have performed well with moisture/steam on one side and air on the other (a troublesome... 

Dimensional stability There is plastics with very good dimensional stability, and they are suitable where some age and environmental dimensional changes are permissible. These materials include polyphenylene oxide, polysulfone, phenoxy, mineral-filled phenolic, diallyl phthalate, epoxy, rigid vinyl, styrene, and various RPs. Such products will gain from an after-bake for dimensional stabilization. Glass fillers will improve the dimensional stability of all plastics. 

Phenolic glass and a diallyl phthalate glass material are available with very low shrinkage. Glass and other mineral fillers minimize the thermal expansion differential problem. Phenoxy and polyphenylene oxides are examples of being low in shrinkage and thermal expansion. 

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