Oil heavy

Filler for cracks and fissures, particularly in highways. Mixtures of bitumen, heavy oils, polymer or sulfur are used. 

The increase in demand for good quality white products and the reduced consumption of fuel-oil related to pollution controls are going to be important factors in residue processing and heavy oil conversion in the years to come. 

Edmister, W.C. and K.K. Okamoto (1959), Applied hydrocarbon thermodynamics. Part 13 equilibrium flash vaporization for heavy oils under sub-atmospheric pressures . Petroleum Refiner, Vol. 38, No. 9, p. 271. 

In some cases bacteria may have biodegraded the oil, i.e. destroyed the light fraction. Many shallow accumulations have been altered by this process. An example would be the large heavy oil accumulations in Venezuela. 

Add 23 g. of powdered (or flake ) sodium hydroxide to a solution of 15 ml. (18 g.) of nitrobenzene in 120 ml. of methanol contained in a 250 ml. short-necked bolt-head flask. Fix a reflux water-condenser to the flask and boil the solution on a water-bath for 3 hours, shaking the product vigorously at intervals to ensure thorough mixing. Then fit a bent delivery-tube to the flask, and reverse the condenser for distillation, as in Fig. 59, p. 100, or Fig. 23(D), p. 45). Place the flask in the boiling water-bath (since methanol will not readily distil when heated on a water-bath) and distil off as much methanol as possible. Then pour the residual product with stirring into about 250 ml. of cold water wash out the flask with water, and then acidify the mixture with hydrochloric acid. The crude azoxybenzene separates as a heavy oil, which when thoroughly stirred soon solidifies, particularly if the mixture is cooled in ice-water. 

Bromo-4-aminotoluene, Suspend the hydrochloride in 400 ml, of water in a 1-Utre beaker equipped with a mechanical stirrer. Add a solution of 70 g. of sodium hydroxide in 350 ml. of water. The free base separates as a dark heavy oil. After cooUng to 15-20°, transfer the mixture to a separatory funnel and run off the crude 3-bromo-4-amino-toluene. This weighs 125 g. and can be used directly in the next step (3). 

Method 2. Equip a 1 htre thre necked flask with a double surface reflux condenser, a mechanical stirrer and a separatory funnel, and place 12 -2 g. of dry magnesium turnings, a crystal of iodine, 50 ml. of sodium-dried ether and 7-5 g. (5 ml.) of a-bromonaphthalene (Section IV,20) in the flask. If the reaction does not start immediately, reflux gently on a water bath until it does remove the water bath. Stir the mixture, and add a solution of 96 g. (65 ml.) of a-bromonaphthalene in 250 ml. of anhydrous ether from the separatory funnel at such a rate that the reaction is vmder control (1 -5-2 hours). Place a water bath under the flask and continue the stirring and refluxing for a further 30 minutes. The Grignard reagent collects as a heavy oil in the bottom of the flask ... 

Typical percentage compositions of light and heavy oils are given below. 

Processing heavy oils and bitumens represents a challenge for the current refinery processes, because heavy oils and bitumens poison the metal catalysts used m the refineries. In our research at the Loker Institute, we found the use of superacid catalysts, which are less sensitive to heavy oils, an attractive solution to their processing, particularly hydrocracking. 

Since the formamide reaction solution is going to be a lot cleaner than the tarry mess of the original recipe, the chemist has yet another option to explore. Instead of hydrolyzing in the reaction pot, the chemist can add SOOmL of clean dHjO and stir just like in the crappy original method except that this time the chemist is going to look for a heavy oil layer that will settle at the bottom. The up-... 

METHOD 2 [89]--1M MDA or benzedrine and 1M benzaldehyde is dissolved in 95% ethanol (Everclear), stirred, the solvent removed by distillation then the oil vacuum distilled to give 95% yellow oil which is a Schiff base intermediate. 1M of this intermediate, plus 1M iodomethane, is sealed in a pipe bomb that s dumped in boiling water for 5 hours giving an orangy-red heavy oil. The oil is taken up in methanol, 1/8 its volume of dH20 is added and the solution refluxed for 30 minutes. Next, an equal volume of water is added and the whole solution boiled openly until no more odor of benzaldehyde is detected (smells like almond extract). The solution is acidified with acetic acid, washed with ether (discard ether), the MDMA or meth freebase liberated with NaOH and extracted with ether to afford a yield of 90% for meth and 65% for MDMA. That s not a bad conversion but what s with having to use benzaldehyde (a List chemical) Strike wonders if another aldehyde can substitute. 

Heavy oil conversion Heavy oils Heavy spar Heavy water... 

The price differential at which coal becomes competitive with gas depends on plant size and the cost of capital, but based on estimates by the International Energy Agency (21) the required price ratio for gas to coal in North America falls into the range of 3.1 to 3.7 on an equivalent energy basis ( /MJ). Current prices give a gas/coal cost ratio nearer 1.5 to 2.0. As a result, all projected new methanol capacity is based on natural gas or heavy oil except for the proposed coal-based plant in China. 

Heavy oil, ie, grade nos. 4, 5, and 6, and residual fuel oils light oils, ie, no. 2 heating oil, kerosene, and jet fuel and petroleum coke are deflvered at... 

As in the case of coal, synthetic natural gas can be produced from heavy oil by partially oxidizing the oil to a mixture of carbon monoxide and hydrogen... 

J. G. Speight, The Desulfuricyation of Heavy Oils and Residua, Marcel Dekker, Inc., New York, 1981. 

Coal, tar, and heavy oil fuel reserves are widely distributed throughout the world. In the Western hemisphere, Canada has large tar sand, bitumen (very heavy cmde oil), and coal deposits. The United States has very large reserves of coal and shale. Coal comprises ca 85% of the U.S. recoverable fossil energy reserves (6). Venezuela has an enormous bitumen deposit and Brazil has significant oil shale (qv) reserves. Coal is also found in Brazil, Colombia, Mexico, and Pern. Worldwide, the total resource base of these reserves is immense and may constitute >90% of the hydrocarbon resources in place (see... 

Heavy cmde oil is widely distributed, and it is difficult to estimate reserves separate from normal cmde oil reserves or from tar sands deposits. Estimates of petroleum reserves frequendy include a large heavy oil component, which can only be produced at significantly higher cost than light oil. 

Most heavy oil production is concentrated in California, Canada, and Venezuela. There is significant production of heavy oil in California from the Kern River field near Bakersfield and in Canada from the Cold Lake deposit in Alberta. Production generally involves steam drives, or the injection of steam into reservoirs through special wells in prescribed sequences. Oil—water mixtures are recovered, and often separated water is treated and reinjected. 

Distinctions between tar sands bitumens and heavy oils are based largely on differences in viscosities. The bitumen in oil sand has a specific gravity of less than 0.986 g/mL (12°API), and thus oil sands may be regarded as a source of extremely heavy cmde oil. Whereas heavy oils might be produced by the same techniques used for the lighter cmde oils, the bitumens in tar sands are too viscous for these techniques. Consequently these oil-bearing stones have to be mined and specially processed to recover contained hydrocarbon. 

Production of maleic anhydride by oxidation of / -butane represents one of butane s largest markets. Butane and LPG are also used as feedstocks for ethylene production by thermal cracking. A relatively new use for butane of growing importance is isomerization to isobutane, followed by dehydrogenation to isobutylene for use in MTBE synthesis. Smaller chemical uses include production of acetic acid and by-products. Methyl ethyl ketone (MEK) is the principal by-product, though small amounts of formic, propionic, and butyric acid are also produced. / -Butane is also used as a solvent in Hquid—Hquid extraction of heavy oils in a deasphalting process. 

The partial-oxidation process differs only in the initial stages before the water gas shift converter. Because it is a noncatalyzed process, desulfurization can be carried out further downstream. The proportions of a mixture of heavy oil or coal, etc, O2, and steam, at very high temperature, are so adjusted that the exit gases contain a substantial proportion of H2 and carbon monoxide. 

J. A. Green and co- Method Development and Application to Cerro Negro Heavy Petroleum, NIPER-452 (DE90000200, 2... 

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