Fireworks

Sulphur is used in the manufacture of matches and fireworks, as a dust insecticide and for vulcanising rubber. Most of the world supply of sulphur, however, is used for the manufacture of sulphuric acid (p. 296). 

The ability of the solid chlorates(V) to provide oxygen led to their use in matches and fireworks. Bromates(V) and iodates(V) are used in quantitative volumetric analysis. Potassium hydrogen diiodate(V), KHflOjlj, is used to standardise solutions of sodium thiosulphate(Vf) since in the presence of excess potassium iodide and acid, the reaction... 

Fire retardant treatments Fire-tube furnace Fireworks... 

R. Lancaster and co-workers. Fireworks Principles andPractices, Chemical Publishing Co., New York, 1972. 

The word match is of uncertain origin. In common parlance, a match is a short, slender, elongated piece of wood or cardboard, suitably impregnated and tipped to permit, through pyrochemical action between dry soHds with a binder, the creation of a small transient flame. The word match also is used for fuse lines which after ignition on one end serve as fire-transfer agents in fireworks and for explosives (qv). Such items belong in the field of pyrotechnics... 

The principle of the safety match is also used in the pull-wire fuse lighter used to start a fuse train for the ignition of fireworks items or more frequently for blasting work. This is a reversed pull match whereby the striker material is coated on a pull wire, and the match head material is within a small metal cup in a cardboard tube. Pulling the coated wire vigorously out of the device ignites the match mixture in the tube for fire transfer to the tubular fuse train. 

Uses. Phosphoms(V) sulfide is used in the manufacture of lubricating oil additives, insecticides, ore flotation agents, and specialty chemicals. Phosphoms sesquisulfide, P4S2, has been used extensively in the manufacture of stnkeanywhere matches (qv). In addition, small quantities are used in fireworks (see Pyrotechnics). 

Other typical pyrotechnic fuels include charcoal, sulfur, boron, siUcon, and synthetic polymers such as poly(vinyl alcohol) and poly(vinyl chloride). Extensive use has been made of natural products such as starches and gums, and the use of these materials continues to be substantial in the fireworks industry. MiUtary pyrotechnics have moved away from the use of natural products due to the inherent variabiUty in these materials depending on climatic conditions during the growth of the plants from which the compounds are derived. 

Types of Fireworks. Fireworks are conveniendy classified as consumer or display. 

Consumer Fireworks. An assortment of small fireworks devices are permitted for use by private citizens in many areas in the United States and elsewhere throughout the wodd. These devices consist of items such as wire sparklers, fountains, Roman candles, sky rockets, mines, and small aerial shells. 

Antimony trisulfide is used ia fireworks, ia certain types of matches, as a pigment, and ia the manufacture of mby glass. 

Cadmium hydroxide is the anode material of Ag—Cd and Ni—Cd rechargeable storage batteries (see Batteries, secondary cells). Cadmium sulfide, selenide, and especially teUuride find utiUty in solar cells (see Solarenergy). Cadmium sulfide, Hthopone, and sulfoselenide are used as colorants (orange, yellow, red) for plastics, glass, glazes, mbber, and fireworks (see Colorants for ceramics Colorants forplastics Pigments). 

CdS colorants find use in plastics, paints, soaps, mbber, paper, glass, printing inks, ceramic gla2es, textiles, and fireworks. Luminescent pigments based on CdS—ZnS are also produced. Pigments based on CdS sell for 35—60/kg. The redder materials are more expensive. 

Group 2 Nitrate/metal/sulphur compositions Compositions with >65% chlorate Black powder Nitrate/boron compositions Burn violently Large firework shells Fuse unprotected signal flares Non-pressed report bullets (bird scarers) Report cartridges (unpacked) Black matches (uncovered) Accelerating single-item explosions... 

Group 3 Nitrate/metal compositions without sulphur Compositions with <35-65% chlorate Compositions with black powder Lead oxide/silicon with >60% lead oxides Perchlorate/metal Burn fast Large firework shells Fuse protected signal flares Pressed report cartridges in primary packagings Quickmatches in transport packagings Waterfalls Silver wheels Volcanoes Black powder delays Burn very violently with single-item explosions... 

Large firework shells without flash compositions in transport packagings... 

HS(G)123 Working together on firework displays - a guide to safety for firework display organizers and... 

HS(Gjl24 Giving your own firework display - how to run and fire it safely... 

Concerned mainly with the security of explosives and restncted substances. Applicable to the acquisition, keeping, handling and control of explosives, e.g. blasting explosives, detonators, fuses, ammunitions, propellants, pyrotechnics and fireworks. 

Black powder, a mixture of potassium nitrate, sulfur, and carbon, may have been invented in 10th centuiy China for fireworks. There is written record they used it in bamboo tubes to propel stone projm - es. There is evidence that Arabs invented it around 1300 A. D. using a gun rf... 

Bicycles d Motorcycles d Alcohol-related accidents d Fireworks d... 

Smoke bomb A firework type of device that produces smoke used for the observation of airflow within a space. 

Knallerbse, /, (Fireworks) torpedo, knallfahig, a. detonating, explosive. Knallflamme. /. oxyhydrogen flame. 

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