Pyrotechnics fuels

Gasoline Isopentane Liquefied petroleum gas fuel, nuclear Nitric acid fuel, picnic stoves Methyl alcohol fuel, pyrophoric Trimethylaluminum fuel, pyrotechnics Dextrin Polyvinyl chloride fuel, rocket... 

R.W. and Mannix, G.S. (2001) Magnesium-fueled pyrotechnic compositions and processes based on elvax-cyclohexane coating technology,... 

The regulation Hsts 137 toxic and reactive substances and a threshold quantity for each. The regulation also appHes to flammable Hquids and gases in quantities of 10,000 lb or more (>4.5 metric tons), except hydrocarbon fuels and Hquids stored in unpressuri2ed, ambient temperature tanks, as weU as to the manufacture of any quantities of explosives (see Exlosives and propellants) and pyrotechnics (qv). 

A pyrotechnic composition contains one or more oxidizers in combination with one or more fuels. Oxidizers used in pyrotechnics, such as potassium nitrate, KNO, are soflds at room temperature and release oxygen when heated to elevated temperatures. The oxygen then combines with the fuel, and heat is generated by the resulting chemical reaction. Chemicals that release fluorine or chlorine on heating, such as polytetrafluoroethylene (Teflon)... 

Other typical pyrotechnic fuels include charcoal, sulfur, boron, siUcon, and synthetic polymers such as poly(vinyl alcohol) and poly(vinyl chloride). Extensive use has been made of natural products such as starches and gums, and the use of these materials continues to be substantial in the fireworks industry. MiUtary pyrotechnics have moved away from the use of natural products due to the inherent variabiUty in these materials depending on climatic conditions during the growth of the plants from which the compounds are derived. 

Pyrotechnic mixtures may also contain additional components that are added to modify the bum rate, enhance the pyrotechnic effect, or serve as a binder to maintain the homogeneity of the blended mixture and provide mechanical strength when the composition is pressed or consoHdated into a tube or other container. These additional components may also function as oxidizers or fuels in the composition, and it can be anticipated that the heat output, bum rate, and ignition sensitivity may all be affected by the addition of another component to a pyrotechnic composition. An example of an additional component is the use of a catalyst, such as iron oxide, to enhance the decomposition rate of ammonium perchlorate. Diatomaceous earth or coarse sawdust may be used to slow up the bum rate of a composition, or magnesium carbonate (an acid neutralizer) may be added to help stabilize mixtures that contain an acid-sensitive component such as potassium chlorate. Binders include such materials as dextrin (partially hydrolyzed starch), various gums, and assorted polymers such as poly(vinyl alcohol), epoxies, and polyesters. Polybutadiene mbber binders are widely used as fuels and binders in the soHd propellant industry. The production of colored flames is enhanced by the presence of chlorine atoms in the pyrotechnic flame, so chlorine donors such as poly(vinyl chloride) or chlorinated mbber are often added to color-producing compositions, where they also serve as fuels. 

The process of designing a pyrotechnic mixture begins with the selection of oxidizer and fuel, and proceeds to incorporate additional components to achieve the exact pyrotechnic effect and bum rate desired in the end item. It is at this point that pyrotechnics takes on the dual nature of an art and science, and experience is often the only thing that can be reHed upon for the solution of a difficult problem. 

Copper(II) nitrate [1003143-3] Cu(N02)2 3H20 electronics, fuel oil treatment, colorant, pyrotechnics, catalyst... 

Pfortner, H. 1985. The effects of gas explosions in free and partially confined fuel/air mMtXKS." Propellants, Explosives, Pyrotechnics. 10 151-155. 

Small arms ammo can be so severely affected by moisture that a special indicating lacquer was developed for 20mm rounds which changes color from grey to black on w exposure (Ref 59) Effect of Moisture on Pyrotechnics Pyrot formulations usually contain finely powdered metal fuels such as Mg, Al, Fe, Cu, etc, all of which can react with moisture to yield H2. This effect has been dubbed gassing in pyrot circles, and is the major problem associated with the storage of hermetically sealed ammo of this... 

Probably the largest use of Ni is in the manuf of Monel metal, stainless steels, Ni-chrome resistance wire, in alloys for electronic and space applications, and as a catalyst (Raney Ni). It is also used as a fuel in pyrotechnics (Ref 2) and... 

The smoke producing material and the pyrotechnic fuel block required to volatilize the smoke material are in separate compartments. The smoke-producing material is atomized and vaporized in the venturi nozzle by the hot gases formed by the burning of the fuel block... 

An important example of the first type is the oil smoke pot which is powered by a slow burning, gassy pyrotechnic mixt such as amm nitrate and amm chloride with a small amount of carbonaceous fuel. The resulting gas jet pulls a stream of oil from a reservoir and injects it into a venturi where the formation of the aerosol takes place... 

Photo flash powders are loose mixts of powdered oxidizers such as Ba nitrate and K perchlorates with metallic fuels, principally Mg, A1 and Zr. These ingredients have such small particle sizes that they bum with expl violence for durations of less than 0.1 sec. At present photoflash powders are used exclusively in military aerial photography, whereas civilian applications are served by electrically ignited Zr or Hf wire containing flashbulbs. Since 1970. non-electric, pyrotechnically functioned, flash cubes have appeared on the market (USPs 3535063,3540813 3674411)... 

Fundamental research in pyrotechnics is published in the US in Combustion and Flame by the Combustion Institute, and in the UK in Combustion Science and Technology and in Fuel . Germany has the new, journal, Propellants and Explosives (German Chemical Society), which is the successor to the discontinued Explosivstoffe . A necessary caveat is that these journals are strongly oriented toward combustion or propulsion so that only rarely do they yield pyrotechnic information. Likewise, the various publications of the learned societies contain much data on thermodynamics, spectroscopy, and instrumental analysis which are useful in the study of pyrotechnics. In the USSR the situation is somewhat better as Physics of Combustion and Explosion (Fizika Gorenia i Vzryva) of the Siberian Branch Academy of Sciences USSR is exclusively oriented toward subjects of interest, as several scientific institutes are primarily devoted to research in pyrotechnics. The same authors do publish also, however, in the journals of the Academy of Science USSR (of which there are several) as well as in the corresponding journals of the academies of the various republics, so that the impression is created of a high level of activity... 

Weldon et al, Evaluation of Metal Fuels for Use in Pyrotechnic Delays , Australian Weapons Research Establishment Technical Memorandum CPD 162 (1970) 37) R.H. Weldon et al,... 

Pyrotechnics are often used in the production of fireworks and primers. A pyrotechnic contains both a fuel and an oxidizer formulated to produce a lot of energy. The energy is then used to produce a flame or glow (matchstick) or combined with other volatile substances to produce smoke and light (fireworks) or large quantities of gas (firework rockets). 

With the possible exception of delay fuses, any pyrotechnic mixture represents a hazard worthy of report. Although the cause of frequent accidents reviewed in [2], compositions intended to explode or deflagrate are generally outside the field of this work and few are listed. Numerous reviews and specialist texts exist and hundreds of patents appear yearly. The account [1] of the theory and practice of pyrotechnics contains much useful information on the performance and potential hazards of a great variety of oxidant-fuel combinations which burn very rapidly or explosively. Safety measures are found in [2], Other reviews written from a functional viewpoint are found in [3] and [4], Some hazardously incompatible pyrotechnic mixes are reported [5], Detonability of pyrotechnic compositions has... 

Kubota, N., and Kuwahara, T., Energetic Solid Fuels for Ducted Rockets (1), Propellants, Explosives, Pyrotechnics, Vol. 16, pp. 51-54, 1991. 

Ringuette, S., Dubois, C., and Stowe, R., On the Optimization of GAP-Based Ducted Rocket Fuels from Gas Generator Exhaust Characterization, Propellants, Explosives, Pyrotechnics, Vol. 25, 2001,... 

---