Carbon, fossil fuel

The equilibrium between CO2 in the air and organically bound carbon (having remained static for hundreds of thousands or even millions of years) has been disturbed noticeably since the second half of the last century by man s progressing civilization. Fixed forms of carbon, fossil fuel (coal, petroleum) and inorganic carbonates, have been mobilized to a considerable extent and have been allowed to enter the carbon cycle. ... 

Burning of any hydrocarbon (fossil fuel) or, for that matter, any organic material converts its carbon content to carbon dioxide and its hydrogen to water. Because power plants and other industries emit large amounts of carbon dioxide, they contribute to the so-called greenhouse warming effect on our planet, which causes significant en-... 

The control of carbon dioxide emission from burning fossil fuels in power plants or other industries has been suggested as being possible with different methods, of which sequestration (i.e., collecting CO2 and injecting it to the depth of the seas) has been much talked about recently. Besides of the obvious cost and technical difficulties, this would only store, not dispose of, CO2 (although natural processes in the seas eventually can form carbonates, albeit only over very long periods of time). 

In photosynthesis, nature recycles carbon dioxide and water, using the energy of sunlight, into carbohydrates and thus new plant life. The subsequent formation of fossil fuels from the biomass, however, takes... 

Rayon is unique among the mass produced man-made fibers because it is the only one to use a natural polymer (cellulose) directly. Polyesters, nylons, polyolefins, and acryflcs all come indirectly from vegetation they come from the polymerization of monomers obtained from reserves of fossil fuels, which in turn were formed by the incomplete biodegradation of vegetation that grew millions of years ago. The extraction of these nonrenewable reserves and the resulting return to the atmosphere of the carbon dioxide from which they were made is one of the most important environmental issues of current times. CeUulosic fibers therefore have much to recommend them provided that the processes used to make them have minimal environmental impact. 

The percentage of energy demand that could be satisfied by particular nonfossil energy resources can be estimated by examination of the potential amounts of energy and biofuels that can be produced from renewable carbon resources and comparison of these amounts with fossil fuel demands. 

X 10 Btu/short ton), the solar energy trapped in 17.9 x 10 t of biomass, or about 8 x 10 t of biomass carbon, would be equivalent to the world s fossil fuel consumption in 1990 of 286 x 10 J. It is estimated that 77 x 10 t of carbon, or 171 x 10 t of biomass equivalent, most of it wild and not controlled, is fixed on the earth each year. Biomass should therefore be considered as a raw material for conversion to large suppHes of renewable substitute fossil fuels. Under controlled conditions dedicated biomass crops could be grown specifically for energy appHcations. 

Another factor is the potential economic benefit that may be realized due to possible future environmental regulations from utilizing both waste and virgin biomass as energy resources. Carbon taxes imposed on the use of fossil fuels in the United States to help reduce undesirable automobile and power plant emissions to the atmosphere would provide additional economic incentives to stimulate development of new biomass energy systems. Certain tax credits and subsidies are already available for commercial use of specific types of biomass energy systems (93). 

Natural gas is attractive as a fuel ia many appHcatioas because of its relatively clean burning characteristics and low air pollution (qv) potential compared to other fossil fuels. Combustion of natural gas iavolves mixing with air or oxygen and igniting the mixture. The overall combustion process does not iavolve particulate combustion or the vaporization of Hquid droplets. With proper burner design and operation, the combustion of natural gas is essentially complete. No unbumed hydrocarbon or carbon monoxide is present ia the products of combustioa. 

Vinyl compares favorably to other packaging materials. In 1992, a lifecycle assessment comparison of specific packages made from glass, paperboard, paper, and selected plastics concluded that vinyl was the material that has the lowest production energy and carbon dioxide emissions, as well as the lowest fossil fuel and raw material requirements of the plastics studied (169). Vinyl saves more than 34 million Btu per 1000 pounds manufactured compared to the highest energy-consuming plastic (170). 

Furthermore, it is not tme that other plastics are more environmentally friendly than vinyl. A more recent study compared vinyl to a number of other packaging materials and found that vinyl consumed the least amount of energy, used the lowest level of fossil fuels, consumed the least amount of raw materials, and produced the lowest levels of carbon dioxide of any of the plastics studied (184). In fact, the Norwegian environmental group BeUona has concluded that a generally reduced use of vinyl plastics can lead to a worsening of the environmental situation (185). 

Carbon. Most of the Earth s supply of carbon is stored in carbonate rocks in the Hthosphere. Normally the circulation rate for Hthospheric carbon is slow compared with that of carbon between the atmosphere and biosphere. The carbon cycle has received much attention in recent years as a result of research into the possible relation between increased atmospheric carbon dioxide concentration, most of which is produced by combustion of fossil fuel, and the "greenhouse effect," or global warming. Extensive research has been done on the rate at which carbon dioxide might be converted to cellulose and other photosyntheticaHy produced organic compounds by various forms of natural and cultivated plants. Estimates also have been made of the rate at which carbon dioxide is released to soil under optimum conditions by various kinds of plant cover, such as temperature-zone deciduous forests, cultivated farm crops, prairie grassland, and desert vegetation. 

The balance between animal and plant life cycles as affected by the solubiHty of carbon dioxide ia the earth s water results ia the carbon dioxide content ia the atmosphere of about 0.03 vol %. However, carbon dioxide content of the atmosphere seems to be increa sing as iacreased amounts of fossil fuels are burned. There is some evidence that the rate of release of carbon dioxide to the atmosphere may be greater than the earth s abiHty to assimilate it. Measurements from the U.S. Water Bureau show an iacrease of 1.36% ia the CO2 content of the atmosphere ia a five-year period and predictions iadicate that by the year 2000 the content may have iacreased by 25% (see Airpollution). 

The increasing number of atomic reactors used for power generation has been questioned from several environmental points of view. A modern atomic plant, as shown in Fig. 28-3, appears to be relatively pollution free compared to the more familiar fossil fuel-fired plant, which emits carbon monoxide and carbon dioxide, oxides of nitrogen and sulfur, hydrocarbons, and fly ash. However, waste and spent-fuel disposal problems may offset the apparent advantages. These problems (along with steam generator leaks) caused the plant shown in Fig. 28-3 to close permanently in 199T. 

Unburnt hydrocarbon (UHC) and carbon monoxide (CO) are only produced in incomplete combustion typical of idle conditions. It appears probable that idling efficiency can be improved by detailed design to provide better atomization and higher local temperatures. CO2 production is a direct function of the fuel burnt (3.14 times the fuel burnt) it is not possible to control the production of CO2 in fossil fuel combustion, the best control is the increasing of the turbine efficiency, thus requiring less fuel to be burnt for the same power produced. 

Combustion processes are the most important source of air pollutants. Normal products of complete combustion of fossil fuel, e.g. coal, oil or natural gas, are carbon dioxide, water vapour and nitrogen. However, traces of sulphur and incomplete combustion result in emissions of carbon monoxide, sulphur oxides, oxides of nitrogen, unburned hydrocarbons and particulates. These are primary pollutants . Some may take part in reactions in the atmosphere producing secondary pollutants , e.g. photochemical smogs and acid mists. Escaping gas, or vapour, may... 

---