SEARCH Articles Figures Tables Aldehydes with metal alkyls Alkali Metal Salts of O-Alkyl Alkylphosphonic Acids IIA-IIE Alkali metal alkyls Alkali metal fluorides alkyl halides Alkali metals alkyl halides Alkali metals alkyl migration Alkenes insertions into metal-alkyl bonds Alkyl Derivatives of the Group II Metals Alkyl Derivatives of the Group II Metals B. J. Wakefield Alkyl Hydroperoxides, Peroxyl Acids, and Metal Peroxides Alkyl and Aryl Derivatives of Transition Metals Alkyl and Metal Halide Compounds Alkyl and aryl metal amide Alkyl and aryl metal compound Alkyl block metal Alkyl bromides transition-metal-catalyzed Alkyl complexes metal hydroxides Alkyl fluorides dissolving metals Alkyl fluorides metal-ammonia Alkyl halides 1.1- allyl metals Alkyl halides 1.1- propargyl metals Alkyl halides metal enolates Alkyl halides sodium metal Alkyl halides with alkali metals Alkyl halides with metal cations Alkyl halides with metal hydrides Alkyl halides with transition metal reagents Alkyl homolytic-transition metal bond Alkyl hydroperoxide-metal catalyst systems Alkyl hydroperoxides reaction with transition metals Alkyl metal halides Alkyl metal hydroxide Alkyl metal nitrosyls Alkyl metals, 1-silyl-1-selenoreactions with carbonyl compounds Alkyl metals, a-selenocarbonyl compound homologation Alkyl metals, a-selenocarbonyl compound homologation functionalized Alkyl metals, a-selenocarbonyl compound homologation reactions Alkyl metals, a-selenocarbonyl compound homologation reactions with carbonyl compounds Alkyl metals, a-selenocarbonyl compound homologation reactions with enals Alkyl metals, a-selenocarbonyl compound homologation reactions with enones Alkyl metals, a-selenocarbonyl compound homologation regiochemistry Alkyl metals, a-selenocarbonyl compound homologation synthesis Alkyl metals, a-selenocarbonyl compound homologation via metallation of selenides Alkyl metals, a-selenoxyreactions with carbonyl compounds Alkyl metals, vinyl halide cross-coupling Alkyl phosphites, transition metal Alkyl phosphites, transition metal complexes Alkyl rare-earth metal complexes Alkyl-metal compounds Alkyl-metal porphyrin anion Alkyl/amido alkali-metal magnesiates Alkylammonium metal alkyl Alkylation 1,3-diketone metal complexes Alkylation acetylacetone metal complexes Alkylation catalysts sulfated metal oxides Alkylation catalysts supported metal halides Alkylation complexes with metals Alkylation metal-free Alkylation of Nitro Compounds Using Transition Metal Catalysis Alkylation with transition metal catalysts Alkylations of metal enolates Alkylations transition metal-catalyzed allylic Alkyls of B subgroup metals Allylic alkylation transition-metal catalyzed Anionic polymerization alkali metal alkyls Aryl and Metal-Alkyl Systems Atomic metal alkyl Bonding in metal alkyls Bonding transition-metal alkyls Borane complexes metal-alkyl Boron Alkyls and Metal Alkyl Initiators of Free-Radical Polymerizations Boron and metal alkyl initiators of free-radical polymerizations Bridged (Associated) Metal Alkyls Bridged species metal alkyls By Reaction with Metals and Alkylating Agents CO insertion into early transition metal alkyls CO insertion into late transition metal alkyls Carbon into metal alkyls Carbon monoxide insertions metal-alkyl complexes Carbon-metal bonds aryl, alkyl, and benzyl halides Cationic alkyl rare-earth metal complexes Cationic metal carbonyls alkylation Characterization and Properties of Metal Alkyls Charge Transfer alkyl metals Chiral metal complexes alkylation Chromates, metal alkyl Chromates, metal alkyl alcohols Chromates, metal alkyl catalytic oxidants Complex alkyl-metal anions Coupling, metal mediated, alkyl Coupling, metal mediated, alkyl halides Cyanides, metal, reaction with alkyl halides Dipole moments transition metal alkyls Dissolving metal conjugate reduction a-alkylated ketones D° metal-alkyl complex Elimination from metal alkyl complexes Friedel-Crafts alkylation metal catalysis From Metal Alkyls From alkyl halides and bismuth metal From metal cyanides alkylation Group Metal Alkyls HOMOGENEOUS DECOMPOSITION OF METAL ALKYLS AND ARYLS Halides, alkyl reaction with metals Halides, aryl, arylation metal catalyzed alkylation Heterogeneous Polymerization Catalysts Derived from Transition Metal Alkyl Compounds Homogeneous catalysts metal alkyl-free Hydride transfer from transition metal alkyls Initiators) metal alkyl Insertion reactions metal alkyl Intermediate metal alkyl Ketones with metal alkyls Lappert, Wilkinson and the Isolation of Stable Metal Alkyls und Aryls Lithium, alkyl-: addn. to 1-alkenyl silanes halogen-metal exchange with Magnetic properties transition metal alkyls Main group-transition metal cluster alkylation Merging Asymmetric Metal and Organocatalysis in Friedel-Crafts Alkylations Metal Alkyls Aryls, and Hydrides Metal alkyl bond dissociation energies Metal alkyl clusters Metal alkyl hydrides Metal alkyl solutions Metal alkyl, transition states leading Metal alkyls Metal alkyls Friedel-Crafts reaction Metal alkyls Wurtz reaction and Metal alkyls alkylcobalt complexes Metal alkyls and aryls Metal alkyls bond energies Metal alkyls bridged Metal alkyls carbonation Metal alkyls catalysts Metal alkyls diethyl zinc Metal alkyls dimethylmercury Metal alkyls elimination Metal alkyls protonation Metal alkyls storage Metal alkyls tetraethyllead Metal alkyls thermal dissociation Metal alkyls thermolysis Metal alkyls toxicity Metal alkyls triethylaluminum Metal alkyls triethylsilane Metal alkyls triisobutylaluminum Metal alkyls trimethylaluminum Metal alkyls, nucleophilic reactivity Metal alkyls, stable homoleptic Metal aryloxides mixed alkyl Metal atoms alkyl halides Metal diastereoselective alkylation Metal dienolates alkylation Metal enolate alkylation Metal enolates alkylation Metal enolates alkylations Metal enolates competition with C-alkylation Metal groups alkyl halides Metal halide, nucleophilic alkylation Metal hydrides alkyl halides Metal hydrides and alkyls Metal phosphites reaction with alkyl halides Metal-alkyl Lewis base interaction Metal-alkyl Subject Metal-alkyl bonds Metal-alkyl bridge structures Metal-alkyl complexes Metal-alkyl complexes Agostic Metal-alkyl complexes Bridging Metal-alkyl complexes Electrophilic abstraction Metal-alkyl complexes Metallacycles Metal-alkyl complexes Preparation Metal-alkyl complexes Stability Metal-alkyl halide complexes Metal-alkyl mechanism Metal-alkyl polymer bonds, number Metal-alkyl radical combination reactions Metal-alkyl-free catalysts Metal-free Alkylations by Acyl Halides on Polymeric Supports Metal-mediated Schmidt Reactions of Alkyl Azides with Alkenes and Alkynes Metalation 9-alkylated calix arenes Metalation alkyl halides Metallated chiral asymmetric alkylation Metallation of -Dichloroethene and Subsequent Alkylation with Bromohexane Metallation of Alkylarenes and Alkyl-hetarenes Metallic alkyl compounds Metals, activated reactivity with alkyl halides Metals, activated with alkyl halides Metals, forming associated alkyls Migratory CO Insertion Reactions of Metal Alkyls Miscellaneous Metal Alkyls Nucleophilic allylation, alkali-metal alkyl Olefins elimination from transition metal alkyls Olefins metal alkyls Organometallic compounds metal alkyls Organometallic compounds, 1,4-addition with alkyl-metal bonds Other Metal Compounds with Bridging Alkyl Groups Other Metal-alkyl Complexes in the Environment Oxidative addition, zinc metal alkyl bromides Phosphines, alkylation from metal catalyzed Phosphines, alkylation metal catalyzed addition Phosphines, alkylation metal catalyzed arylation Polymerization styrene, alkali-metal alkyl Radical metal alkyl decomposition Reaction of Alkyl, Alkenyl, and Aryl Halides with Metals Reactions diamagnetic metal alkyl complexes with Reactions of Transition Metal Compounds with Alkylating or Arylating Reagents Reactions of metal alkyls Rearrangement, 1,2-alkyl alkenes, metal catalyzed Reducing agent metal alkyls Reductive alkylation with other metals Reductive alkylations metal-ammonia reduction Regioselectivity transition-metal catalyzed allylic alkylations Replacement in Transition Metal Alkyl Compounds and Polymerization Activity Safety and handling of metal alkyl Selected Reactions of Metal-Alkyl Complexes Selenides reactions with alkyl metals Sodium alkyl thiolates, reaction with halogen substituted metal complexes Stability metal alkyls Stability of transition metal alkyls Stereoregular Polymerization with Transition Metal Alkyls Stoichiometric reactions of isocyanides with metal alkyls Structural Aspects of Alkyl and Aryl Metal Amides Structural aspects of the metal alkyls Structural studies transition metal alkyls Structure and Bonding in Metal Alkyls Synthesis from metal alkyls/hydrides Synthesis of Metal-Alkyl Complexes The Metal Alkyl — Lewis Base Interaction The Metal-alkyl The Preparation of Metal Alkyls The Stability of Transition Metal Alkyls and Aryls The properties of perfluoro-alkyl and -aryl transition metal complexes Transfer with metal-alkyl Transition Metal Alkyl and Alkenyl Complexes Transition Metal-Catalyzed Alkylative Ring-Opening Transition metal alkyl chemistry Transition metal alkyl compounds Transition metal alkyl compounds activity Transition metal alkyl compounds heterogeneous polymerization catalysts Transition metal alkyl compounds stereoregular polymerizations with Transition metal alkyl compounds synthesis Transition metal alkyls Transition metal alkyls and aryls Transition metal alkyls hydride transfer Transition metal complexes alkyl Transition metal complexes alkylation Transition metal complexes, alkylations Transition metal-alkyl bonds Transition metal-catalyzed reactions allylic alkylations Transition metals catalytic allylic alkylations Transition metals, alkyl halide complexes Transition-metal Alkyl and Related Catalysts Transition-metal alkyl ions Transition-metal organic compounds, alkyl Transition-metal organic compounds, alkyl groups Types of Metal Alkyls Investigated Water alkyl halide-metal reaction Ziegler-Natta catalysts metal alkyls Zinc alkyls metal hydrides Zwitterionic metal alkyl species