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Alkyl Hydroperoxides, Peroxyl Acids, and Metal Peroxides

Alkyl Hydroperoxides, Peroxyl Acids, and Metal Peroxides [Pg.69]

The mechanisms of the reactions of hydrogen peroxide and hydroperoxide with iron(III) porphyrins have been investigated. The reactions with t-butyl hydroperoxide and pentafluoroiodosylbenzene in CH2Cl2(Me0H/H20), shown in equations (8) and (9), yield the iron- oxene center, which in turn may act as an [Pg.69]

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Alkyl hydroperoxide

Alkyl hydroperoxides

Alkyl hydroperoxides Alkylation

Alkyl hydroperoxides hydroperoxide

Alkyl peroxides

Alkylated metals

Alkylations peroxide

And peroxides

Hydroperoxide peroxide

Metals acids and

Peroxides metal

Peroxyl