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Reactions of Transition Metal Compounds with Alkylating or Arylating Reagents

This is the most commonly utilized method for synthesis of transition metal complexes with M —C a bonds. The following substrates are utilized halides, acetylacetonates, acetates, /-electron element alcoholates, as well as organometallic compounds of lithium, magnesium, aluminum, sodium, zinc, mercury, elements of group 14, etc. Ethers and hydrocarbons are used as solvents. In general, the synthesis should be carried out at lower temperatures and under inert atmosphere. [Pg.219]

CrCls 3THF + 3MgBrPh — CrPh3 3THF + 3MgBrCl [Pg.219]


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Alkyl compounds reactions

Alkyl reaction with

Alkyl reagents

Alkyl-metal compounds

Alkylated metals

Alkylating compounds

Alkylating reagents

Alkylation compounds

Alkylation reactions compounds

Aryl metallation

Arylating reagents

Arylation compounds

Arylation reagents

Aryls, transition metal

Compounds of transition metals

Compounds with Transition Metals

Metal aryls

Metals compounds, reactions

Metals reagents

Of alkylation reactions

Reaction with aryl compounds

Reactions alkylating reagents

Reactions of metal alkyls

Reactions of transition metals

Reactions with metal compounds

Reactions with transition metal reagents

Reagents alkylation

Transition alkyl compounds

Transition arylations

Transition compounds

Transition metal alkyl compounds

Transition metal alkyls

Transition metal reactions

Transition reactions with

Transition-metal compounds

With Metal Compounds

With Transition Metals

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