Acrylic adhesives acrylate synthesis

Uses Copolymerized with methyl acrylate, methyl methacrylate, vinyl acetate, vinyl chloride, or 1,1-dichloroethylene to produce acrylic and modacrylic fibers and high-strength fibers ABS (acrylonitrile-butadiene-styrene) and acrylonitrile-styrene copolymers nitrile rubber cyano-ethylation of cotton synthetic soil block (acrylonitrile polymerized in wood pulp) manufacture of adhesives organic synthesis grain fumigant pesticide monomer for a semi-conductive polymer that can be used similar to inorganic oxide catalysts in dehydrogenation of tert-butyl alcohol to isobutylene and water pharmaceuticals antioxidants dyes and surfactants. 

Uses Solvent in nitrocellulose coatings, vinyl films and Glyptal resins paint removers cements and adhesives organic synthesis manufacture of smokeless powders and colorless synthetic resins preparation of 2-butanol, butane, and amines cleaning fluids printing catalyst carrier acrylic coatings. 

Use Solvent in nitrocellulose coatings and vinyl films, Glyptal resins, paint removers, cements and adhesives, organic synthesis, manufacture of smokeless powder, cleaning fluids, printing, catalyst carrier, acrylic coatings. 

Kakoulides EP, Smart JD, Tsibouklis J. Azocross-linked poly(acrylic acid) for colonic delivery and adhesion specificity synthesis and characterization. J Control Release 1998 52 291-300. 

A long-standing goal in polyolefins is the synthesis of polymers bearing polar functional groups such as acrylate, esters, or vinyl ethers, etc [24,40]. These copolymers might endow polyolefins with useful properties such as adhesiveness, dyeability, paintability, and print-ibility. Advances have recently been made in polymerizing polar monomers with cationic metallocene catalysts... 

China. See also People s Republic of China acrylic fiber production in, 11.T89, 220 adhesive joint ventures, 1 526 advanced materials research, 1 696 aquaculture history, 3 183 aquaculture production, 3 189t ascorbic acid synthesis in, 25 754 demand for oil in, 23 530 nanocomposite development, 1 717 natural graphite in, 12 780 oil recovery program in, 23 534 olefin fiber production in, 11 243 production and consumption of regenerated cellulose fibers in,... 

The major emulsion processes include the copolymerization of styrene and butadiene to form SBR rubber, polymerization of chloroprene (Fig. t -4) to produce neoprene rubbers, and the synthesis of latex paints and adhesives based mainly on vinyl acetate and acrylic copolymers. The product is either used directly in emulsion form as a paint or else the surfactants used in the polymerization are left in the final, coagulated rubber product. 

The high pressure polymerization of ethylene can be slightly modified for the copolymerization of ethylene with vinyl- and acrylic-type monomers such as vinyl acetate, vinyl chloride, acrylonitrile, or acrylic esters. Some of these copolymers of ethylene and vinyl acetate or maleic anhydride are already available and have found various applications in plastics, coatings, and adhesives. Copolymers of ethylene and vinyl chloride and of ethylene and acrylonitrile appear particularly interesting because of the low cost of monomers and the properties of the copolymers. Although their synthesis has been disclosed in a number of patents their larger scale production is still in a state of development. 

Acrylonitrile is used in the manufacture of acrylic fibers and in the plastic surface coatings and adhesive industries. It is also used as a pesticide/fumigant. It is a chemical intermediate in the synthesis of antioxidants, pharmaceutical dyes, surface-active agents, and in reactions requiring the cyanoethyl group. 

Beilstein Handbook Reference) Acrylic acid butyl ester Acrylic acid n-butyl ester AI3-15739 BRN 1749970 Butyl 2-propenoate Butyl acrylate Butylester kyseliny akrylove CCRIS 3401 EINECS 205-480-7 HSDB 305 NSC 5163 UN2348. Intermediate in organic synthesis, polymers and copolymers for solvent coatings, adhesives, paints, binders, emulsifiers. Liquid mp = -54.6° bp = 145° d = 0.8898 Am n 242 nm (isooctane) insoluble in H2O, slightly soluble in CCU, soluble in EtOH, Et20, Me2CO LDso (rat orl) = 3,73 g/kg. BASF Corp. 

We are particularly interested in the Wacker oxidation of cyclohexene as the product, cyclohexanone, is a starting material in the synthesis of caprolactam, which is an intermediate in nylon production. Furthermore, we have strong interest in oxidation of acrolein in particular and acryhc compounds in general. Acrolein oxidation leads to a convenient route to 1,3-propanediol, while methyl acrylate oxidation leads to a starting material for adhesives. 

Dimethoxy methyl propionate is a versatile multifunctional synthetic building block, as illustrated by its use as starting material in our route to methyl cyanoac-etate [10] as precursor for cyanomethyl methacrylate [10], which finds wide application in the adhesive industry [11]. We envisaged the synthesis of 3,3-dimethoxy methyl propionate by Wacker-type oxidation of cheap methyl acrylate in methanol as the solvent (Figure 11.5). 

Chem. Descrip. 2-Ethylhexyl acrylate CAS 103-11-7 EINECS/ELINCS 203-080-7 Uses Copolymer intermediate for resins and dispersions forfabrics, inks, glues, and adhesives cleaning and waxing prods. org. synthesis aq. disp. for nonwoven fabrics, textiles, and paper additives for fuel oils and lubricants syn. rubber and latexes plastics and syn. resins Properties APFIA10 max. clear liq. m.w. 184 sp.gr. 0.880 vise. 1.52 mPa s vapor pressure < 1 mbar (20 C) f.p. - 90 C b.p. 213.5 C ( 1013 mbar) flash pt. (OC) 92 C ref. index 1.433 Precautiorr Flamm. 

Hazardous Decomp. Prods. CO, CO2, NO, hydrogen cyanide NFPA Flealth 4, Flammability 3, Reactivity 2 Uses Monomer for acrylic and modacrylic fibers, paints in prod, of ABS and SAN copolymers, nitrile rubber, surfactants, adhesives, polyols, barrier resins, carbon fibers organic synthesis formerly as pesticide fumigant... 

Uses Inlermediale in organic synthesis monomer in mfg. of homopolymers and copolymers for solvent coatings, adhesives, paints, binders, emulsifiers, varnishes, inks, glues, adhesives, cleaning and waxing prods., nonwoven fabrics, textiles, paper, leather acrylic toughener acrylic resin comonomer modifier for oils/alkyds in food-contact coatings... 

Uses Reactive comonomer for acrylic, vinyl acetate, S/B, nitrile resins reactive diluent for radiation-cured coatings crosslinkable paint resin binder for textiles and paper adhesion promoter Manuf/Distrib. ABCR Aldrich Alfa Aesar Lancaster Synthesis Pfaltz Bauer TCI Am. 

Uses Monomer for creating and modifying polymers, acrylic resins, urethane methacryiates marine antifouling paint resin comonomer reactive comonomer for acryiic and S/B resins rubber modifier binder for textiies/paper adhesives, nonwoven fabrics, enamels, adhesives grafting of textiie fibers scaie inhibitors adhesion promoter for polymers hydrophilic polymers It.-curing polymer systems reactive thinner for radiation curing food-pkg. adhesives, polymers Manuf./Distrib. Acros Org. Aldrich Allchem Ind. Ashland BP Amoco Electron Microscopy Sciences Fluka ICN Biomed. Research Prods. Kessler Lancaster Synthesis Laporte Perf. Chems. Monomer-Polymer Dajac Labs Pfaltz Bauer Rohm Haas Rohm Tech San Esters Scientific Polymer Prods. Sigma TCI Am. Ubichem pic Whyte Chems. Ltd... 

Uses Monomer for large-volume resins and polymers, organic synthesis comonomer for thermosetting acrylic resins carboxylated comonomer for S/B-nItrlle latex engineering adhesives thickener for hair care prods. paints Ion-exchange membrane processing agent, binder for paper and textiles leather treatment adhesion promoter pharmaceutical ophthalmics... 

Empirical C7H13NO4S Formula H2C=CHCONHC(CH3)2CH2S03H Properties M.w. 207.25 m.p. 195 C Toxicology Cancer suspect agent Precaution Corrosive Uses Comonomer (anionic flocculants/dispersants) protective colloid and/or copolymerizable surfactant in acrylic/modified acrylic latexes for use in paints, inks, adhesives, and sealants in food-contact paper/paperboard Manuf./Distrib. ABCR UK http //www.abcr.de] Aldrich http //www.sigma-aidrich.com] CBC Europe Fisher Scientific UK http //www.fisher.co.uk, Fluka http //www.sigma-aidrich. com Lancaster Synthesis UK http //www.iancastersynthesis.com] Lubrizol... 

Uses Engineering adhesives monomer for hydrophilic polymer synthesis reactive comonomer for acrylic and S/B resins Manuf./Distrib. ABCR http //www.abcr.de-, Acros Org. http //www.acros.be Trade Name Synonyms Blemmer P [NOF http //WWW. nof. co.jp]... 

---