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The Physical Processes

The signal 1(E) detected at some energy loss E by a spectrometer collecting electrons scattered through angles up to j3 is given by  [Pg.187]


Section 10.1 will consider the physical processes which oil and gas (and unwanted fluids) from the wellhead must go through to reach product specifications. These processes will include gas-liquid separation, liquid-liquid separation, drying of gas. [Pg.235]

The starting point of imaging is the modelisation of the physical process implied when using the sensor once known the exci-tator geometry and the conductivity in any point of the tube, one must be able to compute the magnetic field at any point in the measurement area ... [Pg.357]

The physical process of Hquid—Hquid extraction separates a dissolved component from its solvent by transfer to a second solvent, immiscible with the first but having a higher affinity for the transferred component. The latter is sometimes called the consolute component. Liquid—Hquid extraction can purify a consolute component with respect to dissolved components which are not soluble in the second solvent, and often the extract solution contains a higher concentration of the consolute component than the initial solution. In the process of fractional extraction, two or more consolute components can be extracted and also separated if these have different distribution ratios between the two solvents. [Pg.60]

Third, design constraints are imposed by the requirement for controlled cooling rates for NO reduction. The 1.5—2 s residence time required increases furnace volume and surface area. The physical processes involved in NO control, including the kinetics of NO chemistry, radiative heat transfer and gas cooling rates, fluid dynamics and boundary layer effects in the boiler, and final combustion of fuel-rich MHD generator exhaust gases, must be considered. [Pg.435]

The most convenient mathematical method of describing pervaporation is to divide the overall separation processes into two steps, as shown in Figure 40. The first is evaporation of the feed Hquid to form a (hypothetical) saturated vapor phase on the feed side of the membrane. The second is permeation of this vapor through the membrane to the low pressure permeate side of the membrane. Although no evaporation actually takes place on the feed side of the membrane during pervaporation, this approach is mathematically simple and is thermodynamically completely equivalent to the physical process. The evaporation step from the feed hquid to the saturated vapor phase produces a separation, which can be defined (eq. 13) as the ratio of... [Pg.86]

Exceptions to the simple definition of an essential oil are, for example, gadic oil, onion oil, mustard oil, or sweet birch oils, each of which requires enzymatic release of the volatile components before steam distillation. In addition, the physical process of expression, appHed mostly to citms fmits such as orange, lemon, and lime, yields oils that contain from 2—15% nonvolatile material. Some flowers or resinoids obtained by solvent extraction often contain only a small portion of volatile oil, but nevertheless are called essential oils. Several oils are dry-distiUed and also contain a limited amount of volatiles nonetheless they also are labeled essential oils, eg, labdanum oil and balsam oil Pern. The yield of essential oils from plants varies widely. Eor example, nutmegs yield 10—12 wt % of oil, whereas onions yield less than 0.1% after enzymatic development. [Pg.296]

Corrosion also occurs as a result of the conjoint action of physical processes and chemical or electrochemical reactions (1 3). The specific manifestation of corrosion is deterrnined by the physical processes involved. Environmentally induced cracking (EIC) is the failure of a metal in a corrosive environment and under a mechanical stress. The observed cracking and subsequent failure would not occur from either the mechanical stress or the corrosive environment alone. Specific chemical agents cause particular metals to undergo EIC, and mechanical failure occurs below the normal strength (5aeld stress) of the metal. Examples are the failure of brasses in ammonia environments and stainless steels in chloride or caustic environments. [Pg.274]

The goal of any statistical analysis is inference concerning whether on the basis of available data, some hypothesis about the natural world is true. The hypothesis may consist of the value of some parameter or parameters, such as a physical constant or the exact proportion of an allelic variant in a human population, or the hypothesis may be a qualitative statement, such as This protein adopts an a/p barrel fold or I am currently in Philadelphia. The parameters or hypothesis can be unobservable or as yet unobserved. How the data arise from the parameters is called the model for the system under study and may include estimates of experimental error as well as our best understanding of the physical process of the system. [Pg.314]

A Level 1 PSA is a core-melt analysis that may or may not include external events a Level 2 PSA encompasses Level 1 and extends to the physical processes of the accident and their effect on containment a Level 3 PSA encompasses Levels 1 and 2 and extends to public risk. [Pg.230]

Given the damage states, the analysis flows much as shown in Figure 6.3-1, depending on the process. For a nuclear power plant, thermal-hydraulic analyses determine the spatial temperature of the damaged core, and consequently the ability of the core to retain radioactive materials. Analysis of the physical processes reveals the amounts of hazardous materials that may be released. [Pg.237]

TT-theorem) or from the governing equations of the flow. The latter is to be preferred because this method will give a sufficient amount of dimensionless numbers. Furthermore, it will connect the numbers to the physical process via the equations and give important information in cases where it is necessary to make approximations. [Pg.1177]

Given the complications of strongly nonlinear mechanical and electrical behaviors in a strongly coupled mode along with electrical conduction effects, it is not difficult to appreciate why the physical processes are poorly understood. [Pg.114]

The piezoelectric polymer investigations give new physical insight into the nature of the physical process in this class of ferroelectric polymers. The strong nonlinearities in polarization with stress are apparently more a representation of nonlinear compressibility than nonlinear electrical effects. Piezoelectric polarization appears to be linear with stress to volume compressions of tens of percent. The combination of past work on PVDF and future work on copolymers, that have quite different physical features promises to provide an unusually detailed study of such polymers under very large compression. [Pg.137]

It is important to note that the mental model representation elicited by this technique is not a process engineering model, but instead represents the process workers understanding of the various causes and consequences of the disturbance. This may or may not be in accordance with the actual chemistry or dynamics of the physical process. [Pg.186]

S. Chandrasekar (Chicago) theoretical studies of the physical processes of importance to the structure and evolution of the stars. [Pg.1303]

In this section experimental results are described, which are obtained by applying the conventional pump-probe technique to m-LPPP films kept in vacuum at the temperature of liquid nitrogen [25], These results allow the identification of the primary excitations of m-LPPP and the main relaxation channels. In particular, the low and high excitation density regimes are investigated in order to get an insight into the physical processes associated with the emission line-narrowing phenomenon. [Pg.448]

Equation (3.43) only determines the ratio AjB and does not specify the absolute values of the rate constants, hence some choice must be made based on the physical processes involved. This problem is referred to as apportioning and has often... [Pg.260]

Particle Formation, Electron microscopy and optical microscopy are the diagnostic tools most often used to study particle formation and growth in precipitation polymerizations (7 8). However, in typical polymerizations of this type, the particle formation is normally completed in a few seconds or tens of seconds after the start of the reaction (9 ), and the physical processes which are involved are difficult to measure in a real time manner. As a result, the actual particle formation mechanism is open to a variety of interpretations and the results could fit more than one theoretical model. Barrett and Thomas (10) have presented an excellent review of the four physical processes involved in the particle formation oligomer growth in the diluent oligomer precipitation to form particle nuclei capture of oligomers by particle nuclei, and coalescence or agglomeration of primary particles. [Pg.268]

Abstract This tutorial shows how fundamental is the role plaid by interferences in many of the physical processes involved in astrophysical signal formating and consequently instmmentation. It is obvious in interferometry. Grating spectroscopy is explained within the same framework as Young experiment, and Fabry-Perot filters are explained as Michelson interferometers.Polarization interferences, used in Lyot filters, are discussed, emphasizing the analogy with echelle gratings. [Pg.11]

The composition of the Earth was determined both by the chemical composition of the solar nebula, from which the sun and planets formed, and by the nature of the physical processes that concentrated materials to form planets. The bulk elemental and isotopic composition of the nebula is believed, or usually assumed to be identical to that of the sun. The few exceptions to this include elements and isotopes such as lithium and deuterium that are destroyed in the bulk of the sun s interior by nuclear reactions. The composition of the sun as determined by optical spectroscopy is similar to the majority of stars in our galaxy, and accordingly the relative abundances of the elements in the sun are referred to as "cosmic abundances." Although the cosmic abundance pattern is commonly seen in other stars there are dramatic exceptions, such as stars composed of iron or solid nuclear matter, as in the case with neutron stars. The... [Pg.14]

The condensed phases also are important to the physical processes of the atmosphere however, their role in climate poses an almost entirely open set of scientific questions. The highest sensitivity of physical processes to atmospheric composition lies within the process of cloud nucleation. In turn, the albedo (or reflectivity for solar light) of clouds is sensitive to the number population and properties of CCN (Twomey, 1977). At this time, it appears impossible to predict how much the temperature of the Earth might be expected to increase (or decrease in some places) due to known changes in the concentrations of gases because aerosol and cloud effects cannot yet be predicted. In addition, since secular trends in the appropriate aerosol properties are not monitored very extensively there is no way to know... [Pg.155]

While these calculations provide information about the ultimate equilibrium conditions, redox reactions are often slow on human time scales, and sometimes even on geological time scales. Furthermore, the reactions in natural systems are complex and may be catalyzed or inhibited by the solids or trace constituents present. There is a dearth of information on the kinetics of redox reactions in such systems, but it is clear that many chemical species commonly found in environmental samples would not be present if equilibrium were attained. Furthermore, the conditions at equilibrium depend on the concentration of other species in the system, many of which are difficult or impossible to determine analytically. Morgan and Stone (1985) reviewed the kinetics of many environmentally important reactions and pointed out that determination of whether an equilibrium model is appropriate in a given situation depends on the relative time constants of the chemical reactions of interest and the physical processes governing the movement of material through the system. This point is discussed in some detail in Section 15.3.8. In the absence of detailed information with which to evaluate these time constants, chemical analysis for metals in each of their oxidation states, rather than equilibrium calculations, must be conducted to evaluate the current state of a system and the biological or geochemical importance of the metals it contains. [Pg.383]

The physical processes that occur during indentation are schematically illustrated in Fig. 31. As the indenter is driven into the material, both elastic and plastic deformation occurs, which results in the formation of a hardness impression conforming to the shape of the indenter to some contact depth, h. During indenter withdrawal, only the elastic portion of the displacement is recovered, which facilitates the use of elastic solutions in modeling the contact process. [Pg.23]


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