Temperature-compensated

The temperature compensator on a pH meter varies the instrument definition of a pH unit from 54.20 mV at 0°C to perhaps 66.10 mV at 60°C. This permits one to measure the pH of the sample (and reference buffer standard) at its actual temperature and thus avoid error due to dissociation equilibria and to junction potentials which have significant temperature coefficients. 

A pH electrode is normally standardized using two buffers one near a pH of 7 and one that is more acidic or basic depending on the sample s expected pH. The pH electrode is immersed in the first buffer, and the standardize or calibrate control is adjusted until the meter reads the correct pH. The electrode is placed in the second buffer, and the slope or temperature control is adjusted to the-buffer s pH. Some pH meters are equipped with a temperature compensation feature, allowing the pH meter to correct the measured pH for any change in temperature. In this case a thermistor is placed in the sample and connected to the pH meter. The temperature control is set to the solution s temperature, and the pH meter is calibrated using the calibrate and slope controls. If a change in the sample s temperature is indicated by the thermistor, the pH meter adjusts the slope of the calibration based on an assumed Nerstian response of 2.303RT/F. 

A number of meter designs have been developed based on this principle. Some are shown in Eigure 17. Certain advantages ate claimed for each, but all share a number of characteristics. Perhaps the most important property is a full-scale deflection on the order of 0.001 mm. The sensors for these meters are extremely sensitive, stable, and capable of being temperature compensated. 

In addition, most devices provide operator control of settings for temperature and/or response slope, isopotential point, zero or standardization, and function (pH, mV, or monovalent—bivalent cation—anion). Microprocessors are incorporated in advanced-design meters to faciHtate caHbration, calculation of measurement parameters, and automatic temperature compensation. Furthermore, pH meters are provided with output connectors for continuous readout via a strip-chart recorder and often with binary-coded decimal output for computer interconnections or connection to a printer. Although the accuracy of the measurement is not increased by the use of a recorder, the readabiHty of the displayed pH (on analogue models) can be expanded, and recording provides a permanent record and also information on response and equiHbrium times during measurement (5). 

In many appHcations temperature compensation is added to calculate level (or volume) to an industry standard value, usually the American Petroleum Institute (API). 

Ni alloys of 30—32 wt % are used as temperature-compensator alloys and are characterized by a steep decrease ia magnetic permeabiUty with temperature. These alloys are ideally suited ia electrical circuits as shunts which maintain constant magnetic strength ia devices such as electric meters, voltage regulators, and speedometers. 

Figure 1.3.2 gives another perspective for scale-down to recycle reactor studies. In this actual case, after preliminary studies in a recycle reactor, a 5-stage adiabatic reactor was envisioned (Betty 1979.) Scaling down the proposed commercial reactor, a 3 diameter tube was designed with elaborate temperature compensation (heating and insulation) for pilot-plant studies (Betty 1968, 1969.) Small squares in the proposed reactor represent side views of cylindrical catalyst cutouts for the recycle reactor... 

For various reasons, this type of anemometer is not a suitable instrument for practical measurements in the industrial environment. The thin wire probe is fragile and sensitive to contamination and is unsuited to rough industrial environments. The wire temperature is often too high for low-velocity measurements because a strong natural convection from the wire causes errors. Temperature compensation, to correct for ambient air temperature fluctuations may not be available or may not cover the desired operating range. 

A calibration facility must produce the desired velocity range for the meter to be calibrated. The air temperature should be kept constant over the test to ensure constant density. For thermal anemometers, velocity calibration only is not sufficient. They should also be checked for temperature compensation. In the case of omnidirectional probes, sensitivity to flow direction should be tested. In the case of low-speed (thermal) anemometers, their self-convection error should be measured, and, for instruments measuring flow fluctuation (turbulence), dynamic characteristics testing should be carried out as well. ... 

The Nernst equation shows that the glass electrode potential for a given pH value will be dependent upon the temperature of the solution. A pH meter, therefore, includes a biasing control so that the scale of the meter can be adjusted to correspond to the temperature of the solution under test. This may take the form of a manual control, calibrated in 0 C, and which is set to the temperature of the solution as determined with an ordinary mercury thermometer. In some instruments, arrangements are made for automatic temperature compensation by inserting a temperature probe (a resistance thermometer) into the solution, and the output from this is fed into the pH meter circuit. 

Check whether the instrument supplied is equipped for automatic temperature compensation, and, if so, that the temperature probe (resistance thermometer) is available. If it is not so equipped, then the temperature of the solutions to be used must be measured, and the appropriate setting made on the manual temperature control of the instrument. 

Improved carburetion and choke altitude and temperature compensation... 

W.C. Eller F J. Valenta, Temperature Compensate d Pyrotechnic Delays , USP 3851586... 

The pH (or pI) term of the Nemst equation contains the electrode slope factor as a linear temperature relationship. This means that a pH determination requires the instantaneous input, either manual or automatic, of the prevailing temperature value into the potentiometer. In the manual procedure the temperature compensation knob is previously set on the actual value. In the automatic procedure the adjustment is permanently achieved in direct connection with a temperature probe immersed in the solution close to the indicator electrode the probe usually consists of a Pt or Ni resistance thermometer or a thermistor normally based on an NTC resistor. An interesting development in 1980 was the Orion Model 611 pH meter, in which the pH electrode itself is used to sense the solution temperature (see below). 

For conductimetric incremental titrations, large rugged analogue conductivity meters have also become available, e.g., the Metrohm 518 conductometer (in connection with the Model 536 potentiograph its yields a rapid recording of the curve together with end-point indication) and the Philips PW 9505 analogue conductivity meter (in addition to a recorder output and an output for electrode re-platinization, there is a choice of manual or, by use of a Pt 100 resistance thermometer, automatic temperature compensation). 

It is clear from the Nemst equation that the temperature of the solution affects the response slope (2.303A7//0 of the calibration curve. The electrode voltage changes linearly in relationship to changes in temperature at a given pH therefore, the pH of any solution is a function of its temperature. For example, the electrode response slope increases from 59.2mV/pH at 25°C to 61.5 mV/pH at a body temperature of 37°C. For modem pH sensing systems, a temperature probe is normally combined with the pH electrode. The pH meter with an automatic temperature compensation (ATC) function automatically corrects the pH value based on the temperature of the solution detected with the temperature probe. 

Construction of an EIL temperature compensated oxygen electrode (from EIL advertising material). 

Conductivity was measured as described (10) using a conductivity meter (Radiometer, Copenhagen, Denmark) type CDM3 equipped with a CDC 304 immersion electrode with manual temperature compensator type CDA 100. The instrument was calibrated as specified by the manufacturer. The determination of the (NH4)2S04 concentration from the conductivity measurements was done at constant temperature (4°C) using a calibration curve, in the range of 0.016 mM to 120 mM AS in glucose or sucrose (total... 

Temperature Temperature changes can result in dimensional changes, which inevitably cause problems if not addressed, for optomechanical assemblies within an instrument. Temperature compensation is usually required, and careful attention to the expansion characteristics of the materials of construction used for critical components is essential. This includes screws and bonding materials. If correctly designed, the optical system should function at minimum over typical operating range of 0 to 40 °C. Rapid thermal transients can be more problematic, because they may result in thermal shock of critical optical components. Many electronic components can fail or become unreliable at elevated temperatures, including certain detectors, and so attention must be paid to the quality and specification of the components used. 

This analyser is a computer-controlled automated batch analyser, using a stop-flow principle to analyse for pH, conductivity, turbidity and colour. TTie principle of analysis for each module is based on the recommended methods as detailed in the Examination of Waters and Associated Materials issued by the Standing Committee of Analysts of the Department of the Environment. The temperature of the sample hquid flow is measured in order that temperature-compensated results of pH and conductivity can be quoted. 

Loros Have you looked at temperature compensation of this 6 h rhythm ... 

Loros We do have a period length mutant in White Collar (WC) 2, the ER24 allele that is both long-period and not temperature compensated. We haven t looked at ER24 in terms of the amplitude of the molecular rhythms of either FRQ or WC-1. 

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