3-Phenyl propyl acetate

CIC The powerful odour is dominated by 2-isobutyl thiazole and 3-pentanethiol. The green notes are lipid degradation products like (E)-2-hexenal, hexanal and higher unsaturated aldehydes, the pineapple-pear like fruity notes are derived from methyl hexanoate, ethyl-2-hexenoate and hexyl acetate. The spicy cinnamon notes are represented by 3-phenyl propyl acetate, cinnamyl acetate, methyl cinnamate, ethyl cinna-mate and ciimamaldehyde. Gamma-decalactone and 2,5-dimethyl-4-hydroxy-furan-3(2H)-one and 3-hydroxy-2-butanone add the sweet, creamy body. Beta-famesene, citronellol, 2-phenylethanol, beta-ionone add the sweet, floral, quincelike part and methyl benzoate and ethyl benzoate impart a characteristic medicinal, exotic topnote. 

Addition of nitrosyl chloride also does not give single products.30 However, it seems to be of practical use for esters of unsaturated alcohols for instance, Pfleger and Landauer31 obtained 65% of 3-chloro-2-(hydroxyimino)-3-phenyl-propyl acetate in this way from cinnamyl acetate ... 

Phenyl propyl acetate Benzenepropanol, acet at e iiHQO 122-72-6 178.228 col 11 q -40 i ... 

Synonyms Hydrocinnamic acetate 3-Phenyl-1-propanol acetate Phenylpropyl acetate 3-Phenyl propyl acetate Empirical C11H14O2 Formula C6H5CH2CH2CH2OOCCH3 Properties Colorless liq., spicy floral odor sol. in alcohol insol. in water m.w. 178.25 dens. 1.012 flash pt. > 212 F ref. index 1.494 Toxicology LD50 (oral, rat) 4700 mg/kg mildly toxic by ing. TSCA listed Precaution Combustible liq. 

The log (rate) vs. log (time) curves for the McLafferty rearrangement in the molecular ions of n-butyl acetate, 2-phenylethyl acetate, 2-phenyl-propyl acetate and 2-dimethylaminoethyl acetate have been found to be approximately parallel to each other and the rates at any time decreased significantly on going from n-butyl acetate to 2-phenylethyl acetate to... 

CAS 10402-52-5 EINECS/ELINCS 233-871-2 Synonyms Hydrotropic acetate 1-Methyl phenethyl acetate P-Methylphenethyl acetate Phenethyl alcohol, P-methyl-, acetate 2-Phenyl propyl acetate Empirical C11H14O2... 

Phenyl propyl acetate 2116-84-9 Abil AV 20 Abil AV 20 HS Abil AV1000 Abil AV 8853 Baysilone Fluid PD 5 Baysilone Fluid PK 20 Dow Corning 556 Fluid... 

Phenyl-propyl alcohol, CgH. CHj. CH.2. CHj. OH, is the next highest homologue of phenyl-ethyl alcohol, and is also known as hydro-cinnamyl alcohol. Like the last described bodies it has been known for many years, its first preparation being described in the Aivnalen (188, 202). It occurs as a cinnamic acid ester in storax, and as an acetic ester in cassia oil. It is prepared synthetically by the reduction of cinnamyl alcohol with sodium amalgam and water, or by the reduction of cinnamic or benzyl acetic esters with sodium and absolute alcohol. It has the following characters —... 

The acid-catalyzed cyclization of properly substituted aminoacetaldehyde dialkyl acetals was shown to be a suitable method in the construction of a homo-isopavine (Scheme 39) (132a,172). Treatment of 7V-[l,3-bis(3,4-dimethoxy-phenyl)propyl]aminoacetaldehyde dimethyl acetal (175) with concentrated hydrochloric acid afforded the 7V-norhomoisopavine 176 in 39% yield. This cyclization was also accompanied by some O-demethylation. Product 176 could be readily N-methylated using formaldehyde and sodium borohydride to afford the homoisopavine ( )-177 (772). 

Pentanone Petroleum distillates Phenyl ether vapor Phenyl glycidyl ether n-Propyl acetate Propyl alcohol n-Propyl nitrate Propylene dichloride Propylene oxide Pyridine... 

H-1 -Benzazepine-1 -acetic acid, [5 -(R, R )]-3-[[l -(ethoxycarbonyl)-3-phenyl-propyl]amino]-2,3,4,5-tetrahydro-2-oxo-, monohydrochloride. 

Bromadiolone [3-(3-(4 -bromobiphenyl-4-yl)-3-hydroxy-1-phenyl propyl)-4-hydroxycoumarin] was synthesized and marketed by the French company Lipha SA during the mid-1970s. It is used widely for control of commensal and field rodents in many countries. Technical grade bromadiolone is 97% pure. It is a yellowish powder and stable up to 200°C (Chalermchaikit et al, 1993). It is very soluble in dime-thylformamide (730 g/1), but less soluble in ethyl acetate... 

Adamantyliden)-methyl- -EI4b, 1422 (aus CI/NO-Acetal) Dimethyl-(3-phenyl-propyl)- V/lb, 239 Anilin... 

SYNS FEMANo. 2890 3-PHENYL-l-PROPANOL ACETATE PHENYLPROPYL ACETATE 3-PHENYLPROPYL ACETATE (FCQ 3-PHENYL-1-PROPYL ACETATE... 

Diphenyl-l,3,5-pentanetrione (45) was successfully used for the preparation of pyridone 48. 5-Benzoyl-2-phenyl-4(lH)pyridone (48) was prepared from l,5-diphenyl-l,3,5-pentanetrione (45) with 1 equivalent of DMFDMA in propyl acetate at room temperature followed by NH4CI. The product precipitated from the mixture. But the synthesis of N-substituted pyridones was not successful (Scheme 18). 

A solution of 3.0 g 2-hydroxy-3-(y-phenyl)propyl-6-bromo-l,4-naphthoquinone in the required amount of benzene was stirred in 600 mL hot 1% NaOH solution, and the red solution was cooled to 0°C and treated with 189 mL 1% KMn04 also at 0°C. The solution becoming practically colorless (spot test) and then reaching a maximum intensity of red in 1 to 2 h. The yield of precipitated, nearly pure material was 36%. Crystallization from alcohol containing acetic acid afforded 3-hydroxy-2-(y3-phenyl)ethyl-6-bromo-1,4-naphthoquinone as golden yellow needles, m.p. 173-175°C. 

Cinnamic acid, 3-phenyl propyl ester. See 3-Phenylpropyl cinnamate Cinnamic alcohol. SeeCinnamyl alcohol, Cinnamic aldehyde. See Cinnamal Cinnamic aldehyde ethylene glycol acetal. See Cinnamaldehyde ethylene glycol acetal Cinnamic chloride. See Cinnamoyl chloride Cinnamol. See Styrene Cinnamomum camphora. See Camphor Cinnamomum camphora oil. See Camphor (Cinnamomum camphora) oii Cinnamomum cassia. See Cinnamon (Cinnamomum cassia) extract Cinnamon (Cinnamomum cassia) Cinnamon (Cinnamomum cassia) oii... 

Synonyms Benzyl dimethyl carbinyl acetate Benzyl propyl acetate Dimethyl benzyl carbinoacetate a,a-Dimethylphenethyl acetate a,a-Dimethylphenethyl alcohol acetate 1,1-Dimethyl-2-phenyl acetate DMBCA Definition Obtained by acetylation of dimethylbenzyl carbinol Empirical C12H16O2 Formula C6HgCH2C(CH3)200CCH3... 

Propenoic acid, 3-phenyl-, 3-methylbutyl ester. See Isoamyl cinnamate 2-Propenoic acid, 3-phenyl-, 1-methylethyl ester. See Isopropyl cinnamate 2-Propenoic acid, 3-phenyl-, 3-phenyl-2-propenyl ester. See Cinnamyl cinnamate 2-Propenoic acid, 3-phenyl-, 3-phenylpropyl ester. See 3-Phenyl propyl cinnamate Propenoic acid polymer. See Polyacrylic acid 2-Propenoic acid, polymer with ethene. See Ethylene/acrylic acid copolymer 2-Propenoic acid, polymer with ethene, calcium salt. See Ethylene/calcium acrylate copolymer 2-Propenoic acid, polymer with ethene and ethenyl acetate. See Ethylene/acrylic acid/vinyl acetate copolymer 2-Propenoic acid, polymer with ethene, magnesium salt. See Ethylene/magnesium acrylate copolymer... 

Troysan 186] Troysan 192. See 2-[(-Hydroxymethyl) amino]-2-methylpropanol Troysan Anti-Miidew O. See N-Trichloromethylthio phthalimide Troysan CMP Acetate. See Chloromethoxy propyl mercuric acetate Troysan Copper 8. See Copper naphthenate Troysan PMA-10-SEP, Troysan PMA-30] Troysan PMA-100. See Phenyl mercuric acetate... 

Phenylpropyl) tetrahydrofuran Phenyl salicylate a-Pinene p-Pinene Piperidine Pi peri ne d-Piperitone Piperonyl acetate Piperonyl isobutyrate Potassium acetate Propenylguaethol Propionaldehyde Propyl acetate Propyl alcohol p-Propyl anisole Propyl benzoate Propyl butyrate Propyl cinnamate Propyl disulfide Propyl formate Propyl 2-furanacrylate Propyl heptanoate Propyl hexanoate 3-Propylidenephthalide Propyl isobutyrate... 

Propyl acetate Propylene glycol methyl ether acetate Propylene glycol phenyl ether Propyl propionate Tripropylene glycol ethyl ether Turpentine y-Valerolactone Xylene solvent, lacquers nail polishes Ammonium xylenesulfonate solvent, lactic acid mfg. 

Methoxyethanol acetate 2-Methoxy-1-propanol acetate Methyl acetate Methylcyclohexanol Methyl isobutyl ketone N-Methyl-2-pyrrolidone Morpholine Nitroethane 2-Nitropropane Paraldehyde Pentachloroethane Phenoxyethanol p-Picoline y-Picoline PPG-2 methyl ether PPG-3 methyl ether Propyl acetate Propyl alcohol Propylene dichloride Propylene glycol phenyl ether Quinoline... 

Phenethyl methyl ethyl carbinyl acetate 3-Phenyl propyl isovalerate C14H20O3 Heptyl paraben C14H20O4... 

Montelukast sodium (1, 2-[l-[[(lR)-l-[3-[2-(7-chloroquinolin-2-yl)ethenyl]phenyl]-3-[2-(2-hydroxypropan-2-yl)phenyl]propyl]sulphanyhnethyl] cyclopropyl]acetic acid, sodium salt, Singulair , originator Merck Co.), a once-a-day oral antagonist of leukotriene D4 (LTD4) was selected for chnical development in 1991, and introduced in 1997 for the treatment of both adult and pediatric chronic asthma. This compound is recognized as one of the most significant advances in asthma therapy in the last 25 years [1] and is commonly used for the treatment of nocturnal asthma. 

The main constituent to which the odour of this oil, and of oil of dnnamon, is chiefly due, is cinnamic aldehyde. Small quantities of cinnamic add, its oxidation product, are naturally found in the oil, the amount varying according to its age. A terpene, and the acetic esters of cinnamyl and phenyl-propyl alcohols, also exist in very small quantities. A stearoptene was also found in this oil in 1850 by Eochleder. Acoordi to this chemist its formula is Cj HmO. But a recent investigation by Bertram and Eursten shows that it is ortko-methyl-ooumaric aldehyde C,H.(OCHj)(CH CH. COH). 

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