Phenyl propyl

A). 2 -Hydroxy-5 -([N-(2-methyl-1-phenyl-2-propyl) glycyl]methane-sulfonanilide hydrobromide ... 

OH1402 2-methyl-1-phenyl-2-propyl hydroperoxide 1944-83-8 514.35 45.264 2 20220 C10H15N 2-(1-ethylpropyl)pyridine 7399-50-0 468.55 40.871 1.2... 

When the cyclic component is benzene or naphthalene, the -ic acid or -oic acid of the acid corresponding to the acyl group is changed to -ophenone or -onaphthone, respectively. For example, C5H5—CO—CH2CH2CH3 can be named either butyrophenone (or butanophenone) or phenyl propyl ketone. 

Phenyl-propyl alcohol, CgH. CHj. CH.2. CHj. OH, is the next highest homologue of phenyl-ethyl alcohol, and is also known as hydro-cinnamyl alcohol. Like the last described bodies it has been known for many years, its first preparation being described in the Aivnalen (188, 202). It occurs as a cinnamic acid ester in storax, and as an acetic ester in cassia oil. It is prepared synthetically by the reduction of cinnamyl alcohol with sodium amalgam and water, or by the reduction of cinnamic or benzyl acetic esters with sodium and absolute alcohol. It has the following characters —... 

There exist three isomers of phenyl-propyl alcohol, all of which have been prepared and described, and, although not yet introduced into commerce, may eventually be so. These are as follows Benzyl-methyl-carbinol, CgHj. CHj. CH(OH)CHg, boiling at 215° phenyl-ethyl-carbinol, CgHg. CH(OH)CH2. CHg, boiling at 221° and benzyl-dimethyl-carbinol, C Hg. C(OH)(CHg)2, melting at 21° and boiling at 225°. 

Phenyl-propyl CinTiamate.—This ester occurs in storax, and has a perfume res mbling that balsamic substance. It has the formula... 

Chemical Name 4-[3-[4-(phenoxymethyl)phenyl] propyl] morpholine Common Name —... 

Valethamate bromide dl-1 -Benzyl-4-(1,3-dicyano-1 -phenyl-propyl)piperidine HCI Dexetimide Benzylethanolamine Phenmetrazine... 

Piperacillin sodium Diethyl-d -phenyl propyl) malonate Phenprocoumon Diethylpropyl malonate Apazone... 

R1 = C(CH3)3 R2 = CN (2,2-Dimethyl-l-phenyl-propyl)-malons(iure-dinitrilb —80% d.Th. R1 = ChH, R2 = COOC2H5 Diphenylmethyl-malonsdure-dthylester-nitril6 —80% d.Th. 

Dcmgegeniiber bleibt die Konfiguration bei der Reduktion des optisch aktiven 2-(l-Hydroxy-l-phenyl-propyl)-pyridins zum 2-(l-Phenyl-propyl)-pyridin (-1,36 V 62% d.Th.) erhalten2. 

Diaceioxy-1,1,2,2-tetrakis-[2-methyl-2-phenyl-propyl]-dizinn3... 

Methoxy- -oxim 379 4-Methoxy-phenyl- 631 -O-methyl-oxim 378 2-Nitro- 311 4-Nitro- 285, 765 -oxim 374, 502. 613 -phenylimin 609 -2-phenyl-propyl-(2)-imin 609 4-Phenylthio- 673 2-Thiocyanat- 635 m,ft),o)-Trifluor- 543... 

Athylazo-cyclohexyl)- 571 (1-Alkylazo-alkyl)- 571 tert.-Butyl- 570 (l-tert.-Butylazo-butyl)- 571 ( l-tert.-Butylazo-cyclopentyl)- 571 (l-tert.-ButyIazo-2-methyI-propyI)- 571 Dekalyl-(l)- 570 2-Phenyl-propyl-(2)- 570, 680 Tetralyl-(l)- 570... 

Dimethyl-1-phenyl-propyl)- -dinitril 581 (2,2-Dimethyl-1-phenyl-propyliden)- -dinitril 581 -dinitril 112... 

Pcnten-(2)-yl-(4)- -diathylester 204 Pentyliden-(2)- -dinitril 666 1-Phenyl-athyliden- -dinitril 643 4-Phenylazo-benzoyl- -diathylester 195 (1-Phenyl-propyl)- -dinitril 559 (1-PhenyI-propyliden)- -dinitril 559 PropyI-(2-methyl-aIlyl)- -diathylester 202... 

Dichlor-bis-f2-methyl-2-phenyl-propyl]- 702 Dichlor-diphenyl- 702 Diphenyl- 702... 

Hydroxy-2-phenyl-athyl)-benzyI- 633 (2-Hydroxy-2-phenyl-athyl)-phenyI- 667 [1-Hydroxy-l -phenyl-propyl-(2)J-phenyl- 633 Methyl-(2-tert.-butyl-phenyl)- 632 Methyl-(2-methyl-phenyl)- 632 Methyl-naphthyl- 663 Naphthyl-benzyl- 633 fi-Oxo- 634... 

Phenyl- -1-oxid 567 2-(1-Phenyl-propyl)- 628 2- (bzw. 4)-(2-Phenyl-vinyl)- 645 2-(Succinimido-methylamino)- 453... 

Percec, V. et al. Synthesis and retrostructural analysis of hbraries of AB3 and constitutional isomeric AB2 phenyl propyl ether-based supramolecular dendrimers, J. Am. Chem. Soc., 128, 3324, 2005. 

The common denominator of all these CP-channel blockers (Fig. 2) is their acidic function (usually carboxylate), the secondary amine with a certain spacing to the acidic group, a nitro substitution at a certain distance from the carboxylate group, and the apolar groups such as the phenyl-propyl-residue. We have suggested that the interaction with the CP-channel requires all of these interaction sites, and that even the apolar moiety of the blocker molecule reacts with the channel protein rather than with the membrane lipid [70]. 

The NMR spectrum of the threo + erythro mixture of methylphenyl(2-phenyl-propyl)tin hydride (51), another compound with two asymmetric atoms, shows two CH3Sn signals (Av = 6.6 Hz in benzene at 270 MHz) which remain aniso-chronous even in the presence of HMPA 22>. The analogous erythro + threo tri-organotin deuteride (52) shows two CH3Sn signals too (Av = 1.5 Hz at 60 MHz... 

Phenyl-2-propenoic acid, e279 3-Phenyl-2-propen-l-ol, c282 3-Phenyl-2-propenoyl chloride, c280 3-Phenylpropyl alcohol, pi46 Phenyl propyl ketone, b619... 

Although similar efforts have been devoted to related polymer systems (Overberger and Cho, 1968 Overberger and Dixon, 1977 Okamoto, 1978), large enantioselectivity has not been observed. Goldberg et al. (1978) conducted borohydride reduction of phenyl ketones in micelles of the chiral surfactant [44]. The result was disappointing, since the maximal enantioselectivity was only 1.66% for phenyl propyl ketone. A much better optical yield was reported when this reaction was carried out under phase-transfer conditions (Masse and Parayre, 1976). The cholic acid micelle and bovine serum albumin exhibited the relatively high enantioselectivity in the reduction of trifluoroacetophenone (Baba ef al., 1978). 

Even more educational is the case of the Cu(II) and Cu(III) complexes of N,N -bis[2-(l -hydroxyimino-2-methyl-1 -phenyl)propyl]dimethylma-londiamide (H4mal). Figure 125 shows the molecular structure and the voltammetric behaviour of the Cu(II) form [Cu(Hmal)]-.182... 

Divalent sulfur is a poison for most noble metal catalysts so that catalytic hydrogenation of sulfur-containing compounds poses serious problems (p. 10). However, allyl phenyl sulfide was hydrogenated over tris trisphenyl-phosphine)rhodium chloride in benzene to give 93% yield of phenyl propyl sulfide [674. ... 

The acid-catalyzed cyclization of properly substituted aminoacetaldehyde dialkyl acetals was shown to be a suitable method in the construction of a homo-isopavine (Scheme 39) (132a,172). Treatment of 7V-[l,3-bis(3,4-dimethoxy-phenyl)propyl]aminoacetaldehyde dimethyl acetal (175) with concentrated hydrochloric acid afforded the 7V-norhomoisopavine 176 in 39% yield. This cyclization was also accompanied by some O-demethylation. Product 176 could be readily N-methylated using formaldehyde and sodium borohydride to afford the homoisopavine ( )-177 (772). 

Methyl-2-nitro-l-phenyl-propyl)-malonsaure-diiiiettiylester (R = QH,)1 ... 

---